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Thermal Analysis of Oxidation of TiB2 Powders for Wettable Composite Protective Coatings for Aluminum Electrolyzer Cathodes

  • INVESTIGATION METHODS FOR PHYSICOCHEMICAL SYSTEMS
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Abstract

The resistance of different TiB2 powders to oxidative degradation is studied by synchronous thermal analysis. The temperature dependence of oxidation rate of the powders is determined by the size and morphology of their constituting particles. Our findings can be used to establish the structural and morphological properties of powdered titanium diboride that are optimal for its use in wettable protective composite coatings for the floor of an aluminum electrolyzer.

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REFERENCES

  1. Sorlie, M. and Øye, H.A., Cathodes in Aluminium Electrolysis, Dusseldorf: Aluminium-Verlag Marketing and Kommunikation GmbH, 2010.

    Google Scholar 

  2. Sizyakov, V.M., Vlasov, A.A., and Bazhin, V.Yu., Tsvetn. Met. (Moscow, Russ. Fed.), 2016, no. 1, pp. 32–38.

  3. Yurkov, A.L., Ross. Khim. Zh., 2006, vol. 50, no. 1, pp. 35–42.

    CAS  Google Scholar 

  4. Rafiei, P., Hiltmann, F., Hyland, M., et al., in Light Metals 2001, Warrendale, PA: Minerals, Metals, and Materials Society, 2001, pp. 747–752.

    Google Scholar 

  5. Øye, H.A. and Welch, B.J., JOM, 1998, vol. 50, pp. 18–23.

    Article  Google Scholar 

  6. Li, T., Jonasen, S.T., and Solheim, A., in Light Metals 2015, Minerals, Metals, and Materials Society, 2015, pp. 831–836.

    Google Scholar 

  7. Hou, J., LÜ, X., Zhang, Y.H., et al., in Light Metals 2011, Minerals, Metals, and Materials Society, 2011, pp. 1017–1021.

    Google Scholar 

  8. Novak, B., Tschope, K., Ratvik, A.P., and Grande, T., Light Metals 2012, Minerals, Metals, and Materials Society, 2012, pp. 1343–1348.

    Google Scholar 

  9. Ivanov, V.V., Blokhina, I.A., and Kirik, S.D., Ogneupory Tekh. Keram., 2013, nos. 4–5, pp. 10–15.

  10. Ivanov, V.V., Blokhina, I.A., and Kirik, S.D., Oxid. Met., 2014, vol. 81, nos. 3–4, pp. 71–84.

    Google Scholar 

  11. Blokhina, I.A. and Ivanov, V.V., J. Therm. Anal. Calorim., 2015, vol. 119, no. 1, pp. 123–130.

    CAS  Google Scholar 

  12. Chun, C.M., Bangaru, N.-R.V., Thirumalai, N., et al., Int. J. Appl. Ceram. Technol., 2008, vol. 5, no. 6, pp. 597–609.

    Article  CAS  Google Scholar 

  13. Murthy, T.S.R.Ch., Sonber, J.K., Subramanian, C., et al., Int. J. Refract. Met. Hard Mater., 2009, vol. 27, pp. 976–984.

    Article  CAS  Google Scholar 

  14. Serebryakova, T.I., Neronov, V.A., and Peshev, P.D., Vysokotemperaturnye boridy (High-Temperature Borides), Moscow: Metallurgiya, 1991.

  15. Derry, D.J., Lees, D.G., and Calvert, J.M., J. Phys. Chem. Solids, 1981, vol. 42, no. 1, pp. 57–64.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Siberian Federal University, Krasnoyarsk, Russia

    I. A. Kirillova, E. N. Fedorova & G. E. Nagibin

  2. OOO Rusal, Krasnoyarsk, Russia

    A. O. Gusev & D. A. Simakov

  3. Institute of Computational Technologies, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia

    E. N. Fedorova

  4. Krasnoyarsk Science Center, Siberian Branch, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia

    L. S. Tarasova

Authors
  1. I. A. Kirillova
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  2. L. S. Tarasova
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  3. E. N. Fedorova
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  4. A. O. Gusev
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  5. D. A. Simakov
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  6. G. E. Nagibin
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Corresponding authors

Correspondence to I. A. Kirillova, L. S. Tarasova, E. N. Fedorova or D. A. Simakov.

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Translated by A. Kukharuk

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Kirillova, I.A., Tarasova, L.S., Fedorova, E.N. et al. Thermal Analysis of Oxidation of TiB2 Powders for Wettable Composite Protective Coatings for Aluminum Electrolyzer Cathodes. Prot Met Phys Chem Surf 56, 849–856 (2020). https://doi.org/10.1134/S2070205120040140

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  • DOI: https://doi.org/10.1134/S2070205120040140

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