Abstract
Kinetics of formation of phosphate coatings (PCs) on St3 carbon steel in zinc nitrate–phosphate solution (0.65 М Zn2+ + 0.3 М \({\text{PO}}_{{\text{4}}}^{{{\text{3}} - }}\) + 1.0 М \({\text{NO}}_{{\text{3}}}^{ - },\) рН 1.95) with various additives has been studied at 25°С. It has been shown that introduction of effective silicon-containing additive to phosphatizing solution and further treatment of phosphate films in aqueous solution containing silicon compounds has provided corrosion-stable PCs on St3. Using mathematical planning of Box–Wilson extreme experiment, preparation of PCs with increased protective ability has been optimized under these conditions.
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REFERENCES
Lapatukhin, V.S., Fosfatirovanie metallov (Phosphatizing of Metals), Moscow: Mashgiz, 1958.
Grilikhes, S.Ya., Oksidnye i fosfatnye pokrytiya metallov (Oxide and Phosphate Metal Coatings), Moscow: Mashgiz, 1958, pp. 83–95.
Khain, I.I., Teoriya i praktika fosfatirovaniya metallov (Theory and Practice for Phosphatizing of Metals), Leningrad: Khimiya, 1978.
Babakina, N.A. and Machevskaya, R.A., in Issledovaniya v oblasti tekhniki i tekhnologii lakokrasochnykh pokrytii. Sbornik nauchnykh trudov (Researches in the Field of Technique and Technology of Lacquer and Paint Coatings. Collection of Scientific Works), Moscow, 1975, issue 4, pp. 13–19.
Il’ina, L.K., Lyamina, L.A., Kuchinskaya, M.M., et al., Zashch. Met., 1991, vol. 27, no. 3, pp. 500–502.
Kozlova, L.A. and Okulov, V.V., Gal’vanotekh. Obrab. Poverkhn., 2000, vol. 8, no. 3, pp. 40–48.
Vagramyan, T.A., Grigoryan, N.S., Mazurova, D.V., et al., Korroz.: Mater., Zashch., 2011, no. 2, pp. 20–27.
GOST (State Standard) no. 9.402-2004: Unified System of Corrosion and Ageing Protection. Paint Coatings. Metal Surface Preparation for Painting, Moscow: Standartinform, 2004.
GOST (State Standard) no. 9.302-88: Unified System of Corrosion and Ageing Protection. Metal and Non-Metal Inorganic Coatings. Control Methods, Moscow: Izd. Standartov, 1990.
Il’ina, L.K., Fortunatov, A.V., and Dubrovskii, A.P., Zashch. Met., 1968, vol. 4, no. 2, pp. 171–174.
Il’ina, L.K., Trepak, N.M., Dvorkina, R.M., et al., Rasshirennye tezisy dokladov kongressa “Zashchita-92" (Proc. Congress “Protection-92”), Moscow, 1992, pp. 94–95.
Trepak, N.M., Isaicheva, L.A., Il’ina, L.K., et al., Tezisy dokladov 3-ego mezhdunarodnogo kongressa “Zashchita-98” (Proc. 3rd Int. Congress “Protection-98”), Moscow, 1998, p. 67.
Isaicheva, L.A., Trepak, N.M., Il’ina, L.K., et al., Prot. Met. Phys. Chem. Surf., 2006, vol. 42, no. 4, pp. 389–393.
JCPDC–International Centre for Diffraction Data, 1987.
Adler, Yu.P., Markova, E.V., and Granovskii, Yu.P., Planirovanie eksperimenta pri poiske optimal’nykh uslovii (Design of an Experiment under Searching for Optimal Conditions), Moscow: Nauka, 1976.
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Kazarinov, I.A., Isaicheva, L.A., Makhmmod, A.A. et al. Chemical Phosphatizing of Carbon Steel. Prot Met Phys Chem Surf 55, 700–705 (2019). https://doi.org/10.1134/S2070205119040075
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DOI: https://doi.org/10.1134/S2070205119040075