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Furan and Phenyl Substituted Triazolothiadiazine Derivatives as Copper Corrosion Inhibitors: Electrochemical and DFT Studies

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Abstract

This paper presents experimental aspects of two triazolodiathiazine derivatives 1 {1-(6,7-di(furan-2-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazin-3-yl)ethanol} and 2 {6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazin-3-yl)ethanol} as copper corrosion inhibitors in borate (pH 8.4 and 10.4) aggressive media. Electrochemical findings by CV, polarization and EIS experiments were found inconsistent. The η% values evaluated from all electrochemical methods were in good agreement and within the range of 93–97% at both pH. Compound 1 was found the most efficient corrosion inhibitor for Cu surface at pH 8.4 with inhibition efficiency upto 97%. Electrochemical responses and data interpretation confirmed that the process involved was charge transfer controlled and inhibitors were mixed type. Adsorption data was found best fit in Langmuir’s adsorption isotherm and indicated spontaneity and stability of the compounds on Cu surface via physiosorption. DFT computational studies further supported the experimental results.

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REFERENCES

  1. Fouda, A.S., Gouda, M.M., and Abd El-Rahman, S.I., Chem. Pharm. Bull., 2000, vol. 48, p. 636.

    Article  Google Scholar 

  2. Mojtaba, N., Mahmoud, Z., and J. Behroz, Prot. Met. Phys. Chem. Surf., 2015, vol. 51, p. 285.

    Article  Google Scholar 

  3. Mihajlović, M.B.P. and Antonijević, M.M., Int. J. Electrochem. Sci., 2015, vol. 10, p. 1027.

    Google Scholar 

  4. Ramesh, S. and Rajeswari, S., Corros. Sci., 2005, vol. 47, p. 151.

    Article  Google Scholar 

  5. Altaf, F., Qureshi, R., Ahmed, S., Khan, A.Y., and Naseer, A., J. Electroanal. Chem., 2010, vol. 642, p. 98.

    Article  Google Scholar 

  6. Ameh, P.O. and Eddy, N.O., Res. Chem. Intermed., 2014, vol. 40, p. 2641.

    Article  Google Scholar 

  7. Eddy, N.O., Ameh, P.O., Gimba, C.E., and Ebenso, E.E., J. Chem., 2013, vol. 2013, p. 10.

    Article  Google Scholar 

  8. Eddy, N.O., J. Adv. Res., 2011, vol. 2, p. 35.

    Article  Google Scholar 

  9. Elayyoubi, S.B., Hammouti, S., Kertit, H.O., and Maarouf, E.B., Rev. Met. Paris, 2004, vol. 2, p. 153.

    Article  Google Scholar 

  10. Okafor, P.C., Osabor, V., and Ebenso, E.E., Pigm. Resin Technol., 2007, vol. 36, p. 299.

    Article  Google Scholar 

  11. Bilgic, L. and Caliskan, N., J. Appl. Electrochem., 2001, vol. 52, p. 79.

    Article  Google Scholar 

  12. Duran, B., Bereket, G., and Duran, M., Prog. Org. Coat., 2012, vol. 73, p. 162.

    Article  Google Scholar 

  13. Sherif, S.M., Erasmus, R.M., and Comins J.D., J. Colloid Interface Sci., 2007, vol. 309, p. 470.

    Article  Google Scholar 

  14. Attia, A.A., Elmelegy, E.M., and Ahmed, M.A.B., Asian J. Chem., 2016, vol. 28, p.267.

    Article  Google Scholar 

  15. Altaf, F., Qureshi, R., and Ahmad, S., J. Electroanal. Chem., 2011, vol. 659, p. 134.

    Article  Google Scholar 

  16. Kim, Y.S., Kim, S.H., and Kim, J.G., Met. Mater. Int., 2015, vol. 21, p. 1013.

    Article  Google Scholar 

  17. Emergull, K.C., Kurtaran, R., and Atakol, O., J. Corros. Sci., 2003, vol. 45, p. 2803.

    Article  Google Scholar 

  18. Li, X., Deng, S., Fu, H., and Li, T., Electrochim. Acta, 2009, vol. 54, p. 4089.

    Article  Google Scholar 

  19. Arshad, N., Akram, A.R., Akram, M., and Rasheed, I., Prot. Met. Phys. Chem. Surf., 2017, vol. 53, p. 343.

    Article  Google Scholar 

  20. Hussin, M.H. and Kassim, M.J., J. Phys. Sci., 2010, vol. 21, p. 1.

    Google Scholar 

  21. Benali, O., Lerabi, I., Traisne, L.M., Gengembra, L., and Harek, Y., Appl. Surf. Sci., 2007, vol. 253, p. 6130.

    Article  Google Scholar 

  22. Yunus, U., Ahmed, S., Chahkandi, M., Bhatti, M.H., and Tahir, M.N., J. Mol. Struct., 2017, vol. 1130, p. 688.

    Article  Google Scholar 

  23. Bentiss, F., Lagrenée, M., Elmehdi, B., Mernari, B., Traisnel, M., and Vezin, H., Corrosion, 2002, vol. 58, p. 399.

    Article  Google Scholar 

  24. Hukovic, M.M., Babic, R., and Paic, I., J. Appl. Electrochem., 2000, vol. 30, p. 617.

    Article  Google Scholar 

  25. Solmaz, R., Corros. Sci., 2014, vol. 79, p. 169.

    Article  Google Scholar 

  26. Saji, V.S., Corros. Sci., 2010, vol. 2, p. 6.

    Google Scholar 

  27. Muhammad, T.A., Abdul Rahman, A.A., and Muhammad, S., Sustainability, 2015, vol. 7, p. 15302.

    Article  Google Scholar 

  28. Hukovic, M.M., Babic, R., and Grubac, Z., J. Appl. Electrochem., 2002, vol. 32, p. 35.

    Article  Google Scholar 

  29. Amin, M.A., J. Appl. Electrochem., 2006, vol. 36, p. 215.

    Article  Google Scholar 

  30. Bentiss, F., Lagrenee, M., Traisnel, M., and Hornes, J.C., Corros. Sci., 1999, vol. 41, p. 789.

    Article  Google Scholar 

  31. Bentiss, F., Lagrenee, M., Traisnel, M., and Hornes, J.C., Corros. Sci., 2005, vol. 47, p. 2915.

    Article  Google Scholar 

  32. Belkheir, A.H., Ali, D., Mohammed, B., Hassan, Z., Said, B., and Salem, A.D., J. Saudi Chem. Soc., 2014, vol. 5, p. 450.

    Google Scholar 

  33. Spirtovic-Halilovic, S., Salihovic, M., Veljovic, E., Osmanovi, C.A., Trifunovic, S., and Zavrsnik, D., Bull. Chem. Technol., 2014, vol. 42, p. 31.

    Google Scholar 

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ACKNOWLEDGMENTS

Authors are thankful to Dr. Uzma Yunus, Chemistry Department AIOU for donating compounds for corrosion studies.

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Authors and Affiliations

  1. Department of Chemistry, Allama Iqbal Open University, 44000, Islamabad, Pakistan

    Nasima Arshad, Muhammad Akram & Mehboob Ullah

  2. Pakistan Council of Research in Water Resources, Ministry of Science and Technology, 44000, Islamabad, Pakistan

    Fouzia Altaf

Authors
  1. Nasima Arshad
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  2. Fouzia Altaf
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  3. Muhammad Akram
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  4. Mehboob Ullah
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Correspondence to Nasima Arshad.

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The authors would like to declare that there is no any established conflict of interest.

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Figures S1, S2; as supporting information for this study.

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Arshad, N., Altaf, F., Akram, M. et al. Furan and Phenyl Substituted Triazolothiadiazine Derivatives as Copper Corrosion Inhibitors: Electrochemical and DFT Studies. Prot Met Phys Chem Surf 55, 770–780 (2019). https://doi.org/10.1134/S2070205119040038

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