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Inhibitor Protection of Steels in Solutions of Sulfuric Acid under High-Temperature Corrosion (up to 200°C)

  • CORROSION INHIBITORS
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Abstract

This article analyzes corrosion of 08Kh18N10T chrome nickel steel in 2 M H2SO4 in wide temperature range t = 0–200°C. Under such conditions, corrosion of metal increases with increase in t and at 200°C reaches 9.7 kg/(m2 h). It is demonstrated that the composition of substituted triazole, IFKhAN-92 inhibitor and KI (mole ratio 1 : 1), makes it possible to protect this steel in 2 M H2SO4 at temperatures up to 140°C, inclusive. A three-component mixture of IFKhAN-92, KI, and hexamethylenetetramine (1 : 1 : 4), is more interesting in this regard, it efficiently inhibits corrosion at t up to 180°C, inclusive, maintaining protection for at least 8 h. The same composition reliably protects low carbon steel, grade 20, in 2 M H2SO4 at temperatures up to 180°C, inclusive; moreover, metal corrosion is decelerated in time.

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ACKNOWLEDGMENTS

This work was supported by the Russian Foundation for Basic Research and the government of Kaluga oblast, project no. 14-43-03037.

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Authors and Affiliations

  1. Tsiolkovsky State University, 248023, Kaluga, Russia

    Ya. G. Avdeev

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    D. S. Kuznetsov & S. V. Oleinik

Authors
  1. Ya. G. Avdeev
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  2. D. S. Kuznetsov
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  3. S. V. Oleinik
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Correspondence to Ya. G. Avdeev.

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Translated by I. Moshkin

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Avdeev, Y.G., Kuznetsov, D.S. & Oleinik, S.V. Inhibitor Protection of Steels in Solutions of Sulfuric Acid under High-Temperature Corrosion (up to 200°C). Prot Met Phys Chem Surf 54, 1305–1311 (2018). https://doi.org/10.1134/S2070205118070067

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  • DOI: https://doi.org/10.1134/S2070205118070067

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