Skip to main content
Log in

Investigation of Electrochemical Behavior of Zirconia -Benzotriazole Hybrid Nanostructured Coating Applied on Al 2024 by Sol-Gel Method

  • NANOSCALE AND NANOSTRUCTURED MATERIALS AND COATINGS
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

Nowadays, zirconia based ceramic coatings are extensively used in various industries thanks to their favorable corrosion and wear resistance behavior. In this study, zirconia and zirconia-Benzotriazole nanostructured coatings were deposited on the surface of Al2024 to improve corrosion protection properties by using sol-gel method. Phases and morphology analyses were performed, and chemical bonds were investigated, using GIXRD, FTIR, AFM, FESEM and ellipsometry. In addition, corrosion properties were evaluated by electrochemical methods including polarization and electrochemical impedance techniques using a 3.5% NaCl solution. Results indicated a homogeneous and crack-free zirconia-Benzotriazole hybrid nanostructured coating which exhibited a good corrosion resistance at a corrosion current density reduced by a factor of 47683.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 7.
Fig. 8.

Similar content being viewed by others

REFERENCES

  1. Yasakau, K.A., Tedim, J., Zheludkevich, M.L., and Ferreira, M.G.S., Handbook of Smart Coatings for Materials Protection, Woodhead Publ., 2014.

    Google Scholar 

  2. Shchukin, D.G. and Mçhwald, H., Small, 2007, vol. 6, p. 926.

    Article  Google Scholar 

  3. Khramov, A.N., Voevodin, N.N., Balbyshev, V.N., and Mantz, R.A., Thin Solid Films, 2005, vol. 483, p. 191.

    Article  Google Scholar 

  4. Raps, D., Hack, T., Wehr, J., et al., Corros. Sci., 2009, vol. 51, p. 1012.

    Article  Google Scholar 

  5. Giolli, C., Borgioli, F., Credi, A., et al., Surf. Coat. Technol., 2007, vol. 202, p. 13.

    Article  Google Scholar 

  6. Brunet, M., MafhozKot, H., Bouscayrol, L., et al., Thin Solid Films, 2011, vol. 519, p. 5638.

    Article  Google Scholar 

  7. Lopez, A.J., Rams, J., and Urena, A., Surf. Coat. Technol., 2011, vol. 205, p. 4183.

    Article  Google Scholar 

  8. Wang, D. and Bierwagen, G.P., Prog. Org. Coat., 2009, vol. 64, p. 327.

    Article  Google Scholar 

  9. Andreatta, F., Aldighieri, P., Paussa, L., et al., Electrochim. Acta, 2007, vol. 52, p. 7545.

    Article  Google Scholar 

  10. Saridag, S., Tak, O., and Alniacik, G., World J. Stomatol., 2013, vol. 2, p. 40.

    Google Scholar 

  11. Sakka, S., Handbook of Advanced Ceramics, Academic Press, 2013.

    Google Scholar 

  12. Ganbavle, V.V., Bangi, U.K.H., Latthe, S.S., et al., Surf. Coat. Technol., 2011, vol. 205, p. 5338.

    Article  Google Scholar 

  13. Kawaguti, C.A., Chivacci, L.A., Pulcinelli, S.H., et al., J. Sol-Gel Sci. Technol., 2004, vol. 32, p. 91.

    Article  Google Scholar 

  14. Tiwari, S.K., Adhikary, J., Singh, T.B., and Singh, R., Thin Solid Films, 2009, vol. 517, p. 4502.

    Article  Google Scholar 

  15. Catauro, M., Bollino, F., Veronesi, P., and Lamanna, G., Mater. Sci. Eng., 2014, vol. 39, p. 344.

    Article  Google Scholar 

  16. Paussa, L. and Rosero, N.C., Prog. Org. Coat., 2012, vol. 74, p. 311.

    Article  Google Scholar 

  17. Aljourani, J., Golozar, M., and Raeissi, K., Mater. Chem. Phys., 2010, vol. 121, p. 320.

    Article  Google Scholar 

  18. Aljourani, J., Raeissi, K., and Golozar, M., Corros. Sci., 2009, vol. 51, p. 1836.

    Article  Google Scholar 

  19. Setare, E., Raeissi, K., Golozar, M.A., and Fathi, M.H., Corros. Sci., 2009, vol. 51, p. 1802.

    Article  Google Scholar 

  20. Shanaghi, A. and Kadkhodaei, M., Corros. Eng., Sci. Technol., 2017, vol. 52, p. 332.

    Article  Google Scholar 

  21. Shanaghi, A., Chu, P.K., and Moradi, H., Surf. Rev. Lett., 2017, vol. 24, p. 1 750 055.

    Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors would like to express their thanks to Iranian Nanotechnology Initiative Council.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ali Shanaghi.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Saeid Mersagh Dezfuli, Shanaghi, A. & Baghshahi, S. Investigation of Electrochemical Behavior of Zirconia -Benzotriazole Hybrid Nanostructured Coating Applied on Al 2024 by Sol-Gel Method. Prot Met Phys Chem Surf 54, 1050–1058 (2018). https://doi.org/10.1134/S2070205118060096

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205118060096

Keywords:

Navigation