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A comparative study of corrosion inhibition of steel and stainless steel in hydrochloric acid by N,N,N′,N′-tetramethyl-p-phenylenediamine

  • Physicochemical Problems of Materials Protection
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Abstract

The corrosion of mild steel (MS) and AISI type 321 stainless steel (AISI 321) in 1 M HCl solution and the inhibitive mechanism of N,N,N′,N′-Tetramethyl-p-phenylenediamine (TMPPD) were investigated using open circuit potential measurements (OCP), potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. Potential-time measurements showed that the addition of TMPPD to HCl solutions shifts the potential of MS and AISI 321 to more positive values. Polarization curves measurements indicated that TMPPD act as a mixed type inhibitor for the corrosion of MS and AISI 321 in HCl solutions. EIS measurements showed that the dissolution process occurs under activation control. The applied techniques explained that TMPPD is more efficient as a corrosion inhibitor for mild steel than stainless steel in acidic solutions. Theoretical fitting of different isotherms, Langmuir, Kinetic-thermodynamic, Flory–Huggins, and Temkin isotherms were tested to explain the nature of TMPPD adsorption. The associated activation parameters were also calculated and discussed.

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References

  1. Zaafarany, I.A., Int. J. Electrochem. Sci., 2013, vol. 8, p. 9531.

    Google Scholar 

  2. Yaro Aprael S, Anees A. Khadom, Rafal K. Wael, Alexandria Eng. J., 2013, vol. 52, p. 129.

    Article  Google Scholar 

  3. Herle Ramadev, Prakash Shetty S, Divakara Shetty, and Achutha Kini U., Indian J. Chem. Technol., 2013, vol. 20, p. 317.

    Google Scholar 

  4. Shukla, S.K., Singh, A.K., and Ebenso, E.E, Int. J. Electrochem. Sci., 2011, vol. 6, p. 4276.

    Google Scholar 

  5. Al-Nowaiser, F.M., J. King Abdulaziz Univ, Sci., 2010, vol. 22, p. 89.

    Article  Google Scholar 

  6. Nada F., Atta Fekry, A.M., and Hamdi M. Hassaneem, Int. J. Hydrogen Energy 2011, vol. 36, p. 6462.

    Article  Google Scholar 

  7. Geethamani, P. and Kasthuri, P.K, Cogent Chem., 2015, vol. 1, p. 1091558.

    Article  Google Scholar 

  8. Hmimou, J., Rochdi, A., Touir, R., et al, J. Mater. Environ. Sci., 2012, vol. 3, p. 43.

    Google Scholar 

  9. Khaled Rola, Y, Abdel-Gaber, A.M., and Holail, H.M., Int. J. Electrochem. Sci., 2016, vol. 11, p. 2790.

    Article  Google Scholar 

  10. Rahal, H.T., Abdel-Gaber, A.M., and Younes, G.O, Chem. Eng. Commun., 2016, vol. 203, p. 435.

    Article  Google Scholar 

  11. Din, E.L., Shams, A.M., Mohammed, R.A., and Haggag, H.H, Desalination, 1997, vol. 114, p. 85.

    Article  Google Scholar 

  12. Abdel-Gaber, A.M., Int. J. Appl. Chem., 2007, vol. 3, p. 161.

    Google Scholar 

  13. Abdel-Gaber, A.M., Masoud, M.S., Khalil, E.A., and Shehata, E.E, Corros. Sci., 2009, vol. 51, p. 3021.

    Article  Google Scholar 

  14. Abdel-Gaber, A.M., Khamis, E., Abo-ElDahab, H., and Adeel, Sh, Mater. Chem. Phys., 2008, vol. 109, p. 297.

    Article  Google Scholar 

  15. Goudarzi, N., Peikari, M., Zahir, M., and Mousavi, H, Arch. Metall. Mater., 2012, vol. 57, p. 845.

    Article  Google Scholar 

  16. Abd-El-Nabey, B.A., Abdel-Gaber, A.M, El Said Ali, M., et al., Int. J. Electrochem. Sci., 2013, vol. 8, p. 7124.

    Google Scholar 

  17. Abd-El-Nabey, B., Khamis, E., Ramadan, M., and El-Gindy, A, Corrosion, 1996, vol. 52, p. 671.

    Article  Google Scholar 

  18. Eddy, N.O. and Ebenso, E.E, Afr. J. Pure Appl. Chem., 2008, vol. 2, p. 46.

    Google Scholar 

  19. Abd-El-Nabey, B.A., Abdel-Gaber, A.M., Elawady, G.Y., and El-Houssein, S, Int. J. Electrochem. Sci., 2012, vol. 7, p. 7823.

    Google Scholar 

  20. Khalifa Omyma R. and Shadia M. Abdallah, Port. Electrochim. Acta, 2011, vol. 29, p. 47.

    Article  Google Scholar 

  21. Fouda, A.S. and Ellithy, A.S, Corros. Sci., 2009, vol. 51, p. 868.

    Article  Google Scholar 

  22. Lukovits, I., Kálmán, E., and Zucchi, F, Corrosion, 2001, vol. 57, p. 3.

    Article  Google Scholar 

  23. Ahamad, I., Prasad, R., Ebenso, E.E., et al, Int. J. Electrochem. Sci., 2012, vol. 7, p. 3436.

    Google Scholar 

  24. Satpati, A.K., Palrecha, M.M., and Sundaresan, R.I, Indian J. Chem. Technol., 2008, vol. 15, p. 163.

    Google Scholar 

  25. Lagrenee, M., Mernari, B., Bouanis, M., et al, Corros. Sci., 2002, vol. 44, p. 573.

    Article  Google Scholar 

  26. Scendo, M. and Trela, J, Int. J. Electrochem. Sci., 2013, vol. 8, p. 9201.

    Google Scholar 

  27. Cuevas Arteaga, C, Porcayo Calderón, J., Campos Sedano, C.F., and Rodríguez, J.A., Int. J. Electrochem. Sci., 2012, vol. 7, p. 445.

    Google Scholar 

  28. Cuevas-Arteaga, C. and Dominguez-Crescencio, F, Corrosion, 2009, vol. 65, p. 748.

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Beirut Arab University, Beirut, Lebanon

    Rola Y. Khaled & A. M. Abdel-Gaber

  2. Department of Chemistry, Faculty of Science, Alexandria University, Ibrahimia, Alexandria, 21321, Egypt

    A. M. Abdel-Gaber

Authors
  1. Rola Y. Khaled
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  2. A. M. Abdel-Gaber
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Correspondence to Rola Y. Khaled.

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Khaled, R.Y., Abdel-Gaber, A.M. A comparative study of corrosion inhibition of steel and stainless steel in hydrochloric acid by N,N,N′,N′-tetramethyl-p-phenylenediamine. Prot Met Phys Chem Surf 53, 956–960 (2017). https://doi.org/10.1134/S2070205117050082

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  • DOI: https://doi.org/10.1134/S2070205117050082

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