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Melting of high- and low-density polyethylene in mixtures with aluminum after plastic deformation under high pressure

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Abstract

Mixtures of low- and high-density polyethylene with aluminum were subjected to plastic deformation at a pressure of 0.5–4.0 GPa. DSC analysis showed that heating of samples at 110 and 140°C results in addition to the melting of polymers in the melting of ultrafine polymer crystallites at 40°C and also in chemical interaction at 80°C at the polymer–metal phase interface; crystallization of the polymer phase in deformed mixtures occurs at 14–18° higher than that of the initial polymers. Enthalpies of thermal processes in baric dependences reached extremum values at the pressures at which restructuring of the electron subsystem occurs in the deformed mixtures.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    V. A. Zhorin

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    M. R. Kiselev & V. A. Kotenev

Authors
  1. V. A. Zhorin
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  2. M. R. Kiselev
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  3. V. A. Kotenev
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Correspondence to V. A. Zhorin or M. R. Kiselev.

Additional information

Original Russian Text © V.A. Zhorin, M.R. Kiselev, V.A. Kotenev, 2017, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2017, Vol. 53, No. 4, pp. 418–425.

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Zhorin, V.A., Kiselev, M.R. & Kotenev, V.A. Melting of high- and low-density polyethylene in mixtures with aluminum after plastic deformation under high pressure. Prot Met Phys Chem Surf 53, 703–710 (2017). https://doi.org/10.1134/S2070205117040256

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  • DOI: https://doi.org/10.1134/S2070205117040256

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