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Regulation of sorption processes in natural nanoporous aluminosilicates. 3. Impact of electromagnetic fields on adsorption and desorption of formaldehyde by clinoptilolite

  • Physicochemical Processes at the Interfaces
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Abstract

The effect of electromagnetic fields on the adsorption–desorption properties of natural zeolites is a new direction in the theory of physical and chemical processes associated with the surface characteristics of aluminosilicates. The influence of two types of fields, an ultrahigh-frequency electromagnetic field (UHF EMF) and a weak pulsed magnetic field (WPMF) is considered. Modes for treatment of natural zeolite (clinoptilolite) and its activated forms for the most effective sorption of formaldehyde, water, and a mixture thereof were found. It was shown that the preadsorption activation of zeolite in a UHF EMF enhances the selectivity of water vapor sorption, whereas treatment of the sorbent in a WPMF largely affects the selectivity of the absorption of formaldehyde vapors. The decreased desorption of formaldehyde as a result of activation of the mineral in a UHF EMF, as well as complete absence of formaldehyde desorption when a WPMF was used as an activator, was detected.

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Authors and Affiliations

  1. Morozov Voronezh State University of Forestry and Technologies, Voronezh, 394087, Russia

    L. I. Bel’chinskaya, N. A. Khodosova, L. A. Novikova & M. V. Anisimov

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    G. A. Petukhova

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  1. L. I. Bel’chinskaya
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  2. N. A. Khodosova
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  3. L. A. Novikova
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  4. M. V. Anisimov
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  5. G. A. Petukhova
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Correspondence to L. I. Bel’chinskaya.

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Original Russian Text © L.I. Bel’chinskaya, N.A. Khodosova, L.A. Novikova, M.V. Anisimov, G.A. Petukhova, 2017, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2017, Vol. 53, No. 5, pp. 472–479.

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Bel’chinskaya, L.I., Khodosova, N.A., Novikova, L.A. et al. Regulation of sorption processes in natural nanoporous aluminosilicates. 3. Impact of electromagnetic fields on adsorption and desorption of formaldehyde by clinoptilolite. Prot Met Phys Chem Surf 53, 793–800 (2017). https://doi.org/10.1134/S2070205117040025

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  • DOI: https://doi.org/10.1134/S2070205117040025

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