Abstract
Polymethylmethacrylate-based film composites containing small additives of fullerenes (up to 3 wt %) are obtained. The thermal behavior of the obtained materials is studied by DSC in the temperature range from 25 to 130°C. It is found that the character of the DSC curve depends on the composite composition. For films containing up to 0.1 wt % C60, one glass transition temperature (T g soft) is observed, while in the case of films with a higher concentration of the filler, two glass transition temperatures (T g soft and T g solid) are observed. It is found that the dependence of T g soft value on the content of fullerenes is nonmonotonic with a minimum at 0.5 wt % of C60.
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Badamshina, E.R. and Gafurova, M.P., Polym. Sci., Ser. B, 2008, vol. 50, nos. 7–8, pp. 215–226.
Alekseeva, O.V., Bagrovskaya, N.A., Kuz’min, S.M., et al., Russ. J. Phys. Chem. A, 2009, vol. 83, no. 7, pp. 1170–1175.
Alekseeva, O.V., Barannikov, V.P., Bagrovskaya, N.A., et al., J. Therm. Anal. Calorim., 2012, vol. 109, p. 1033.
Arshad, M., Masud, K., Arif, M., et al., J. Therm. Anal. Calorim., 2009, vol. 96, p. 873.
Harper, C.A., Modern Plastics Handbook, New York: McGraw-Hill, 2000.
Nemec, J.W., Jr. and Bauer, W., in Encyclopedia of Polymer Science and Engineering, Mark, H.F., Bikales, N.M., Overberger, C.G., and Marges, G.V., Eds., New York: Wiley Int., 1985, p. 211.
Andrade, C.K.Z., Matos, R.A.F., Oliveira, V.B., et al., J. Therm. Anal. Calorim., 2010, vol. 99, p. 539.
Thangamani, R., Chinnaswamy, T.V., Palanichamy, S., et al., J. Therm. Anal. Calorim., 2010, vol. 100, p. 651.
Tatro, S.R., Clayton, L.M., Muisener, P.A.O., et al., Polymer, 2004, vol. 45, p. 1971.
Kuljanin-Jakovljevic, J., Stojanovic, Z., and Nedeljkovic, J., J. Mater. Sci., 2006, vol. 41, p. 5014.
Zheng, J., Goh, S.H., and Lee, S.Y., Polym. Bull., 1997, vol. 39, p. 79.
Katiyar, R., Bag, D.S., and Nigam, I., Thermochim. Acta, 2013, vol. 557, p. 55.
Kropka, J.M., Putz, K.W., Pryamitsyn, V., et al., Macromolecules, 2007, vol. 40, p. 5424.
Zanotto, A., Spinella, A., Nasillo, G., et al., eXPRESS Polym. Lett., 2012, vol. 6, p. 410.
Abdullaev, Kh.M. and Shoimov, E., Dokl. Akad. Nauk Resp. Tadzh., 2010, vol. 53, no. 2, p. 117.
Abdullaev, Kh.M., Shoimov, E., and Tabarov, F., Dokl. Akad. Nauk Resp. Tadzh., 2011, vol. 54, no. 11, p. 901.
Hu, Y.-H., Chen, C.-Y., and Wang, C.-C., Polym. Degrad. Stab., 2004, vol. 84, p. 545.
Ash, B.J., Schadler, L.S., and Siegel, R.W., Mater. Lett., 2002, vol. 55, p. 83.
Abdullaev, Kh.M. and Shoimov, E., Dokl. Akad. Nauk Resp. Tadzh., 2009, vol. 52, p. 950.
Roldugin, V.I., Serenko, O.A., Getmanova, E.V., et al., Dokl. Phys. Chem., 2013, vol. 449, no. 2, pp. 83–87.
Lee, K.J., Lee, D.K., Kim, Y.W., et al., J. Polym. Sci., Part B: Polym. Phys., 2007, vol. 45, p. 2232.
Vinogradova, L.V., Melenevskaya, E.Yu., Kever, E.E., et al., Polym. Sci., Ser. A, 1997, vol. 39, no. 11, pp. 1149–1154.
Sabban, J.R., Xu-Wu, A., Chichos, J.S., et al., Thermochim. Acta, 1999, vol. 331, p. 93.
Tugov, I.I. and Kostrykina, G.I., Khimiya i fizika polimerov (Chemistry and Physics of Polymers), Moscow: Khimiya, 1989.
Tsagaropoulos, G. and Eisenberg, A., Macromolecules, 1995, vol. 28, p. 396.
Tsagaropoulos, G. and Eisenberg, A., Macromolecules, 1995, vol. 28, p. 6067.
Robertson, C.G. and Rackaitis, M., Macromolecules, 2011, vol. 44, p. 1177.
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Original Russian Text © O.V. Alekseeva, A.V. Noskov, S.S. Guseynov, 2016, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2016, Vol. 52, No. 6, pp. 628–632.
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Alekseeva, O.V., Noskov, A.V. & Guseynov, S.S. Features of the thermal behavior of PMMA/C60 film composites. Prot Met Phys Chem Surf 52, 1019–1023 (2016). https://doi.org/10.1134/S2070205116060034
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DOI: https://doi.org/10.1134/S2070205116060034