Abstract
Mixtures of cyanuric acid with different polymers are subjected to plastic deformation under pressure of 1 GPa, and the DSC method is used to establish that endothermal processes with enthalpies that can reach 50 J g-1 occur in deformed mixtures under heating in the range of 50–250°C. The occurrence of endothermal processes is related to the destruction of intermolecular bonds formed at the acid–polymer interface and due to formation of double electric layers and appearance of interphase electrostatic attraction.
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Original Russian Text © V.A. Zhorin, M.R. Kiselev, V.A. Kotenev, 2016, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2016, Vol. 52, No. 5, pp. 533–537.
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Zhorin, V.A., Kiselev, M.R. & Kotenev, V.A. Heat processes in mixtures of polymers with cyanuric acid after plastic deformation under high pressure according to calorimetric data. Prot Met Phys Chem Surf 52, 876–880 (2016). https://doi.org/10.1134/S2070205116050270
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DOI: https://doi.org/10.1134/S2070205116050270