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Study of inhibition effect of pyridinium salt derivative on corrosion of C1010 carbon steel in saline solution

  • Physicochemical Problems of Materials Protection
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Abstract

In this work, pyridinium dibromide (2) was synthesized and its structure was confirmed using spectroscopic techniques. Compound (2) was successfully applied as a corrosion inhibitor for C1010 carbon steel in 3.5% NaCl solution at 25°C. Different electrochemical measurements such as potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) were used to evaluate different concentrations of the suggested inhibitor (2). The results showed that inhibition efficiencies obtained from EIS curves are in consistence with the results of PDP at higher concentration 4.5 × 10–4 M. Semi-empirical calculations with PM3 method was used to find relationship between molecular structure and inhibiting effect of suggested inhibitor (2).

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References

  1. Sherif, E.M. and Park, S.M., Electrochim. Acta, 2006, vol. 51, p. 1313.

    Article  Google Scholar 

  2. Ebenso, E.E., Obot, I.B., and Murulana, L.C., Int. J. Electrochem. Sci., 2010, vol. 5, p. 1574.

    Google Scholar 

  3. Sanyal, B., Prog. Org. Coat., 1981, vol. 9, p. 165.

    Article  Google Scholar 

  4. Li, S., Chen, S., Lei, S., et al., Corros. Sci., 1999, vol. 41, p. 1273.

    Article  Google Scholar 

  5. Emregu, K.C. and Atakol, O., Mater. Chem. Phys., 2003, vol. 82, p. 188.

    Article  Google Scholar 

  6. Emregu, K.C. and Atakol, O., Mater. Chem. Phys., 2004, vol. 83, p. 373.

    Article  Google Scholar 

  7. Emregu, K.C., Kurtaran, R., and Atakol, O., Corros. Sci., 2003, vol. 45, p. 2803.

    Article  Google Scholar 

  8. Yurt, A., Ulutas, S., and Dal, H., Appl. Surf. Sci., 2006, vol. 253, p. 919.

    Article  Google Scholar 

  9. Kendig, M. and Jeanjaquet, S., J. Electrochem. Soc., 2002, vol. 149, p. B47.

    Article  Google Scholar 

  10. Ma, F., Li, W., Tian, H., Kong, Q., and Hou, B., Int. J. Electrochem. Sci., 2012, vol. 7, p. 10909.

    Google Scholar 

  11. Popova, A., Christov, M., Vasilev, A., and Zwetanova, A., Corros. Sci., 2011, vol. 53, p. 679.

    Article  Google Scholar 

  12. Atia, A.A. and Saleh, M.M., J. Appl. Electrochem., 2003, vol. 33, p. 171.

    Article  Google Scholar 

  13. Achouri, M.El., Bensouda, Y., Gouttaya, H.M., et al., Prog. Org. Coat., 2001, vol. 43, p. 267.

    Article  Google Scholar 

  14. Mohite, P.B. and Bhaskar, V.H., Orbital Elec. J. Chem. Campo Grande, 2011, vol. 3, p. 117.

    Google Scholar 

  15. Daeniker, H.U. and Grob, C.A., Org. Synth. Coll., 1973, vol. 5, p. 989.

    Google Scholar 

  16. Chauhan, L. and Gunasekaran, G., Corros. Sci., 2007, vol. 49, p. 1143.

    Article  Google Scholar 

  17. Hegazy, M.A., Corros. Sci., 2009, vol. 51, p. 2610.

    Article  Google Scholar 

  18. Jeyaprabha, C., Sathiyanarayanan, S., Muralidharan, S., and Venkatachari, G., J. Braz. Chem. Soc., 2006, vol. 17, p. 61.

    Article  Google Scholar 

  19. Growcock, F.B. and Jasinski, J.H., J. Electrochem. Soc., 1989, vol. 136, p. 2310.

    Article  Google Scholar 

  20. Ashassi-Sorkhabi, H., Seifzadeh, D., and Hosseini, M., Corros. Sci., 2008, vol. 50, p. 3363.

    Article  Google Scholar 

  21. Osman, M.M., Omar, A.M., and Al-Sabagh, A.M., Mater. Chem. Phys., 1997, vol. 50, p. 271.

    Article  Google Scholar 

  22. Goncalves, R.S., Azambuja, D.S., and Serpa Lucho, A.M., Corros. Sci., 2002, vol. 44, p. 467.

    Article  Google Scholar 

  23. Bommersbach, P., Alemany-Dumont, C., Millet, J., and Normand, B., Electrochim. Acta, 2005, vol. 51, p. 1076.

    Article  Google Scholar 

  24. Raspini, I.A., Werkst. Korros., 1985, vol. 36, p. 273.

    Article  Google Scholar 

  25. Malik, M.A., Hashim, M.A., Shaeel, F.N., et al., Int. J. Electrochem. Sci., 2011, vol. 6, p. 1927.

    Google Scholar 

  26. Noor, E.A. and Al-Moubaraki, A.H., Mater. Chem. Phys., 2008, vol. 110, p. 145.

    Article  Google Scholar 

  27. Shihab, M.S. and Al-Doori, H., J. Mol. Struct., 2014, vol. 1076, p. 658.

    Article  Google Scholar 

  28. HyperChem 2002, Version 7.5, Gainesville: Hypercube Inc., 2002.

  29. Tang, Y., Yang, X., Yang, W., et al., Corros. Sci., 2010, vol. 52, p. 1801.

    Article  Google Scholar 

  30. Gao, G. and Liang, C., Electrochim. Acta, 2007, vol. 52, p. 4554.

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Al-Nahrain University, College of Science, Department of Chemistry, Al-Jadrya, Baghdad, Iraq

    Mehdi Salih Shihab

  2. Department of Civil and Environmental Engineering, Washington State University, PO Box 642910, Pullman, WA, 99164-2910, USA

    Mehdi Honarvar Nazari

  3. Western Transportation Institute, Montana State University, P O Box 174250, Bozeman, MT, 59717, USA

    Laura Fay

Authors
  1. Mehdi Salih Shihab
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  2. Mehdi Honarvar Nazari
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  3. Laura Fay
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Correspondence to Mehdi Salih Shihab.

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Shihab, M.S., Nazari, M.H. & Fay, L. Study of inhibition effect of pyridinium salt derivative on corrosion of C1010 carbon steel in saline solution. Prot Met Phys Chem Surf 52, 714–720 (2016). https://doi.org/10.1134/S2070205116040213

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  • DOI: https://doi.org/10.1134/S2070205116040213

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