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Corrosion resistance of nanostructured films of titanium diboride in mineral acid solutions

  • Nanoscale and Nanostructured Materials and Coatings
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Abstract

The reactions of nanostructured TiB2 films (mean grain size is 3.3 ± 1.1 nm) with mineral acids (HCl, H2SO4, H3PO4, and HNO3) of different concentrations have been studied. It is found that the dissolution of the films is a congruent process showing linear kinetics for the time periods in the range from 300 to 1500 min. The corrosion depth parameters of nanostructured TiB2 films in mineral acids are determined, and their corrosion resistance is graded on a ten-point scale. The studied films show the lowest corrosion resistance in their reaction with nitric acid solutions, and the highest resistance is observed in phosphoric acid solutions.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    I. I. Korobov, G. V. Kalinnikov, A. V. Ivanov, N. N. Dremova, R. A. Andrievski & S. P. Shilkin

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  1. I. I. Korobov
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  2. G. V. Kalinnikov
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  3. A. V. Ivanov
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  4. N. N. Dremova
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  5. R. A. Andrievski
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  6. S. P. Shilkin
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Correspondence to I. I. Korobov.

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Original Russian Text © I.I. Korobov, G.V. Kalinnikov, A.V. Ivanov, N.N. Dremova, R.A. Andrievski, S.P. Shilkin, 2016, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2016, Vol. 52, No. 4, pp. 382–385.

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Korobov, I.I., Kalinnikov, G.V., Ivanov, A.V. et al. Corrosion resistance of nanostructured films of titanium diboride in mineral acid solutions. Prot Met Phys Chem Surf 52, 618–621 (2016). https://doi.org/10.1134/S2070205116040171

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  • DOI: https://doi.org/10.1134/S2070205116040171

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