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On conditions of change of sign of the Rehbinder effect in the case of single-component adsorption according to the Frumkin isotherm

  • Physicochemical Processes at the Interfaces
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Abstract

Thermodynamic criteria of the “positive” (a decrease in surface hardness) and “negative” (an increase in surface hardness) Rehbinder effect are studied in terms of an earlier-proposed theory of adsorption on a solid surface that takes into account its deformation. Single-component adsorption according to Frumkin isotherm is considered. The conditions for transition from surface stretching in the presence of a “positive” Rehbinder effect to its compression and appearance of the “negative” effect is considered numerically and analytically.

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Authors and Affiliations

  1. Institute of Applied Mechanics, Russian Academy of Sciences, Leninskii pr. 32A, Moscow, 119991, Russia

    E. M. Podgaetskii

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  1. E. M. Podgaetskii
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Correspondence to E. M. Podgaetskii.

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Original Russian Text © E.M. Podgaetskii, 2015, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2015, Vol. 51, No. 5, pp. 451–455.

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Podgaetskii, E.M. On conditions of change of sign of the Rehbinder effect in the case of single-component adsorption according to the Frumkin isotherm. Prot Met Phys Chem Surf 51, 725–729 (2015). https://doi.org/10.1134/S2070205115050196

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  • DOI: https://doi.org/10.1134/S2070205115050196

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