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Application of Mossbauer spectroscopy of conversion and Auger electrons for the study of transformations on Fe electrode under conditions of passive-transpassive transition

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Abstract

Using Mossbauer spectroscopy of conversion and Auger electrons and X-ray photoelectron spectroscopy peculiarities and regularities in formation of composition and structure of the products of oxidation of 57Fe samples in solutions of 0.1 N NaOH, a mixture of 1 N NaOH and 6 N NaNO3, 1 N H2SO4, 0.1 N H3BO3, and 0.5 mol/L Na2B4O7 in relation to the nature of corrosion medium and charge densities of anode polarization (10…12000 mA/cm2) corresponding to the region of passive-transpassive transition has been studied.

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References

  1. Chemodanov, A.N. and Kolotyrkin, Ya.M., Itogi nauki i tekhniki. Ser. Korroziya i zashchita metallov (Results in Science and Technology. Ser. Corrosion and Protection of Metals), Moscow: 1981, vol. 8, p. 102

    Google Scholar 

  2. Graham, M.S., Mitchell, D.S., and Canning, D.A., Oxid. Met., 1978, vol. 3, p. 247.

    Article  Google Scholar 

  3. Kolotyrkin, Ya.M., Losev, V.V., and Chemodanov, A.N., Itogi nauki i tekhniki. Ser. Korroziya i zashchita metallov (Results in Science and Technology. Ser. Corrosion and Protection of Metals), Moscow: 1986, vol. 12, p. 3.

    Google Scholar 

  4. Sukhotin, A.M., Fizicheskaya Khimiya passiviruyushchikh plenok na zheleze (Physical Chemistry of Passivating Films on Iron), Leningrad: Khimiya, 1989.

    Google Scholar 

  5. Sukhotin, A.M. and Lisovaya, E.V., Itogi nauki i tekhniki. Ser. Korroziya i zashchita metallov (Results in Science and Technology. Ser. Corrosion and Protection of Metals), Moscow: 1986, vol. 12, p. 61.

    Google Scholar 

  6. Baldokhin, I.P. Suzdalev, V.E., Prusakov, et al, Russian J. of Phys. Chem. B, 2012, vol. 6, no. 1, p. 81.

    Article  Google Scholar 

  7. Datta, M., Mathieu, H.J., and Landolt, D., J. Electrochem. Soc, 1984, vol. 131, no. 11, p. 2484.

    Article  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119334, Russia

    Yu. V. Baldokhin

  2. Ministry of Education and Science of the Russian Federation, MISIS National University of Science and Technology, Leninskii pr. 4, Moscow, 119049, Russia

    Yu. A. Pustov

Authors
  1. Yu. V. Baldokhin
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  2. Yu. A. Pustov
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Correspondence to Yu. V. Baldokhin.

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Original Russian Text © Yu.V. Baldokhin, Yu.A. Pustov, 2014, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2014, Vol. 50, No. 5, pp. 547–552.

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Baldokhin, Y.V., Pustov, Y.A. Application of Mossbauer spectroscopy of conversion and Auger electrons for the study of transformations on Fe electrode under conditions of passive-transpassive transition. Prot Met Phys Chem Surf 50, 667–671 (2014). https://doi.org/10.1134/S2070205114050050

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  • DOI: https://doi.org/10.1134/S2070205114050050

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