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Effect of conditions of formation of composite pyrographite/Nafion-polyaniline-Pt anode upon electrooxidation of methanol

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Abstract

The effect of the conditions of formation (regime of formation and sequence of deposition of composite components, pH of the solution) of a multicomponent composite anode including polyaniline, Nafion, and platinum on the activity of such an anode in the course of electrocatalytic oxidation of methanol is studied. An explanation of the observed regularities of platinum and polyaniline codeposition is suggested on the basis of the data on the electrode surface topography obtained using the atomic force microscopy technique.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, bldg 4, Moscow, 119071, Russia

    V. N. Andreev, M. R. Ehrenburg & V. A. Bogdanovskaya

Authors
  1. V. N. Andreev
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  2. M. R. Ehrenburg
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  3. V. A. Bogdanovskaya
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Correspondence to V. N. Andreev.

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Original Russian Text © V.N. Andreev, M.R. Ehrenburg, V.A. Bogdanovskaya, 2014, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2014, Vol. 50, No. 5, pp. 528–534.

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Andreev, V.N., Ehrenburg, M.R. & Bogdanovskaya, V.A. Effect of conditions of formation of composite pyrographite/Nafion-polyaniline-Pt anode upon electrooxidation of methanol. Prot Met Phys Chem Surf 50, 632–638 (2014). https://doi.org/10.1134/S2070205114050037

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  • DOI: https://doi.org/10.1134/S2070205114050037

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