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The surface tension of a solid in the presence of adsorption and electric charge on its surface taking account its finite strain

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Abstract

Studies of the thermodynamic theory of equilibrium single-component adsorption from a liquid on a charged solid surface taking into account its finite strain are continued. The adsorption isotherm equation and surface tension of a solid are derived in the special case of the surface-layer equation within the model of two parallel capacitors. The constraint equations are obtained for parameters of the theory with capacitive curves measured on an unstrained metallic surface.

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Correspondence to E. M. Podgaetskii.

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Original Russian Text © E.M. Podgaetskii, 2014, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2014, Vol. 50, No. 4, pp. 339–353.

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Podgaetskii, E.M. The surface tension of a solid in the presence of adsorption and electric charge on its surface taking account its finite strain. Prot Met Phys Chem Surf 50, 433–446 (2014). https://doi.org/10.1134/S2070205114040133

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  • DOI: https://doi.org/10.1134/S2070205114040133

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