Abstract
Changes in the morphology and composition of a metal-oxide iron nanoparticle obtained by reactive pulse sputtering of iron in an oxygen atmosphere (10−4 mmHg) on glass followed by low-temperature annealing in air atmosphere in a temperature range from 20 to 100°C were studied with the use of atomic-force microscopy with digital processing of images and infrared spectroscopy. During annealing of a particle, accelerated sintering (up to 50% of the volume) is found to take place due to the compaction and possible spreading over the glass surface. Judging from data of infrared spectroscopy, annealing is accompanied by oxidation of the nanoparticle and the accumulation of hematite phase formed as a result of magnetite oxidation. The activation energy of the deformation of a nanoparticle seemingly determined by the viscous flow at low-temperature annealing was estimated from the kinetic curves of volume degradation based on AFM data.
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Suzdalev, I.P., Nanotekhnologiya: fizikokhimiya nanoklasterov, nanostruktur i nanomate-rialov (Nanotechnology: The Physical Chemistry of Nanoclusters, Nanostructures, and Nanomaterials), Moscow: KomKniga, 2006.
Vayssieres, L., Hagfeldt, A., and Lindquist, S.E., Pure Appl. Chem., 2000, vol. 72, p. 47.
Xia, Y. and Halas, N.J., MRS Bull., 2005, vol. 30, p. 356.
Fan, H.J., Gosele, U., and Zacharias, M., Small, 2007, vol. 3, p. 1660.
Smigelskas, A.D. and Kirkendall, E.O., Trans. Metall. Soc. AIME, 1947, vol. 171, p. 130.
Handbook of Thin Film Technology, Maissel, L.J. and Glang, R., New York: McGraw Hill Hook, 1970.
Palatnik, L.S., Cheremskoi, P.G., and Fuks, M.Ya., Pory v plenkakh (Pores in Films), Moscow: Energoizdat, 1982.
Kotenev, V.A., Petrunin, M.A., Maksaeva, L.B., et al., Prot. Met. Phys. Chem. Surf., 2013, vol. 49, no. 4, p. 479.
Kotenev, V.A., Petrunin, M.A., Maksaeva, L.B., et al., Prot. Met. Phys. Chem. Surf., 2013, vol. 49, no. 5, p. 597.
Cheremskoi, P.G., Slezov, V.V., and Betekhtin, V.I., Pory v tverdom tele (Pores in Solids), Moscow: Energoatomizdat, 1990.
Tochitskii, E.I., Kristallizatsiya i termoobrabotka tonkikh plenok (Crystallization and Thermal Processing of Thin Films), Minsk: Nauka i Tekhnika, 1976.
Tu, K.N. and Gosele, U., Appl. Phys. Lett., 2005, vol. 86, p. 093111.
Gusak, A.M., Zaporozhets, T.V., Tu, K.N., and Gosele, U., Phil. Mag., 2005, vol. 85, p. 4445.
Evteev, A.V., Levchenko, E.V., Belova, I.V., and Murch, G.E., Phil. Mag., 2007, vol. 87, p. 3787.
Fischer, F.D. and Svoboda, J.J., Nanoparticle Res., 2008, vol. 10, p. 255.
Nakamura, R., Tokozakura, D., Lee, J.G., et al., Acta Mater., 2008, vol. 56, p. 5276.
Ivensen, V.A., Fenomenologiya spekaniya i nekotorye voprosy teorii (Phenomenology of Sintering and Particular Theoretical Aspects), Moscow: Metallurgiya, 1985.
Kotenev, V.A., Tyurin, D.N., Tsivadze, A.Yu., et al., Prot. Met. Phys. Chem. Surf., 2009, vol. 45, no. 6, p. 704.
Nakamura, R., Matsubayashi, G., Tsuchiya, H., et al., Acta Mater., 2009, vol. 57, p. 4261.
Kotenev, V.A., Vysotskii, V.V., Kiselev, M.R., et al., Prot. Met. Phys. Chem. Surf., 2011, vol. 47, no. 6, p. 785.
Greenler, R., J. Chem. Phys., 1966, vol. 4, p. 310.
Poling, G.W., J. Electrochem. Soc., 1969, vol. 116, p. 958.
Yurchenko, E.N., Kustova, G.N., and Batsanov, S.S., Kolebatel’nye spektry neorganicheskikh soedinenii (Vibrational Spectra of Inorganic Compounds), Novosibirsk: Nauka, 1981.
Dvoraic, V. and Feitknechtw, W., Helv. Chim. Acta, 1969, vol. 52, p. 575.
Mertens, P.P.N., Corrosion, 1978, vol. 34, p. 359.
Ottsen, D.R., Solid State Sci. Technol., 1985, vol. 132, p. 2250.
Lyakishev, N.P. and Al’mov, M.I., Poluchenie i fizikokhimicheskie svoistva ob”emnykh nanokristallicheskikh materialov (Production and Physicochemical Properties of Bulk Nanocrystalline Materials), Moscow: EKLIZ, 2007.
Cornell, R.M. and Schwertmann, U., The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses, Weinheim: Wiley, 2003, p. 403.
Andrievskii, R.A., Prot. Met. Phys. Chem. Surf., 2013, vol. 49, no. 5, p. 528.
Lu, J., Yang, S., Ng, K. M., et al., Nanotechnol., 2006, vol. 17, p. 5812.
Kotenev, V.A., Tyurin, D.N., Petrunin, M.A., et al., Prot. Met. Phys. Chem. Surf., 2008, vol. 44, no. 6, p. 589.
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Original Russian Text © V.A. Kotenev, M.R. Kiselev, V.I. Zolotarevskii, A.Yu. Tsivadze, 2014, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2014, Vol. 50, No. 4, pp. 399–404.
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Kotenev, V.A., Kiselev, M.R., Zolotarevskii, V.I. et al. Cold sintering of iron nanoparticles. Prot Met Phys Chem Surf 50, 488–492 (2014). https://doi.org/10.1134/S207020511404008X
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DOI: https://doi.org/10.1134/S207020511404008X