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Corrosion of environmentally friendly lanthanum conversion coating on AA2024-T3 aluminum alloy

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Abstract

In this work, lanthanum conversion coating applied on AA2024-T3 aluminum alloy. The coatings were analyzed by optical and scanning electron microscope. The composition and phase structure of the coating were evaluated by EDS and XRD, respectively. Corrosion properties of the coating were investigated by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. To explain the corrosion behavior of the coating, equivalent circuit was developed from the measurements. Results showed that the coating has a nanocrystaline structure with crystal size less than 50 nm which is composed of La2O3. Additionally, EIS measurements showed that the lanthanum conversion coating was monolayer. Measurements taken by polarization tests showed that the coating increased corrosion potential and decreased corrosion current density approximately one order of magnitude.

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References

  1. Kaufman, J.G., Materials Park, OH, ASM International, November, 2000.

    Google Scholar 

  2. Ghali, E., Corrosion Resistance of Aluminum and Magnesium Alloys: Understanding, Performance and Testing, Hoboken, New Jersey: John Wiley and Sons, Inc., 2010.

    Book  Google Scholar 

  3. Blanc, C., Gastaud, S., and Mankowski, G., J. Electrochem. Soc., 2003, vol. 150, no. 8, p. B396.

    Article  Google Scholar 

  4. Buchheit, R.G. et al., J. Electrochem. Soc., 1997, vol. 144, no. 8, p. 2621.

    Article  Google Scholar 

  5. Buchheit, R.G. et al., J. Electrochem. Soc., 1999, vol. 146, no. 12, p. 4424.

    Article  Google Scholar 

  6. Ramezanzadeh, B., Attar, M.M., and Farzam, M., Surface and Coatings Technology, 2010, vol. 205, p. 874.

    Article  Google Scholar 

  7. ASM Handbook, vol. 5: Materials Park, OH, ASM International, 1998.

  8. Bierwagen, G. et al., Progress in Organic Coatings, 2010, vol. 68, p. 48.

    Article  Google Scholar 

  9. Hinton, B.R.W., J. Alloys and Compounds, 1992, vol. 180, p. 15.

    Article  Google Scholar 

  10. de Frutos, A. et al., Surface and Coatings Technology, 2008, vol. 202, p. 3797.

    Article  Google Scholar 

  11. Fahrenholtz, W.G. et al., Surface and Coatings Technology, vol. 155, p. 208.

  12. Dabala, M. et al., Appl. Surf. Sci., 2001, vol. 172, p. 312.

    Article  Google Scholar 

  13. Mishra, A.K. and Balasubramaniam, R., Mater. Chem. and Phys., 2007, vol. 103, p. 385.

    Article  Google Scholar 

  14. Peng, T. and Man, R., Journal of Rare Earths, 2009, vol. 27, p. 159.

    Article  Google Scholar 

  15. Ferreira, M.G.S. et al., Electrochim. Acta, 2004, Vol. 49, p. 2927.

    Article  Google Scholar 

  16. Kong, G. et al., Journal of Rare Earths, 2010, vol. 28, p. 461.

    Article  Google Scholar 

  17. Kong, G. et al., Corrosion Sci., 2011, vol. 53, p. 1621.

    Article  Google Scholar 

  18. Yang, L. et al., Appl. Surf. Sci., 2008, vol. 255, p. 2338.

    Article  Google Scholar 

  19. Song, D. et al., Corrosion Sci., 2011, vol. 53, p. 3651.

    Article  Google Scholar 

  20. Fan, H. et al., Corrosion Sci., 2011, vol. 53, p. 3821.

    Article  Google Scholar 

  21. Aziz, I. and Zhang, Q., Materials and Corrosion, 2010, vol. 61, p. 568.

    Article  Google Scholar 

  22. Pardo, A. et al., Appl. Surf. Sci., 2006, vol. 252, p. 2794.

    Article  Google Scholar 

  23. Pinc, W. et al., Appl. Surf. Sci., 2009, vol. 255, no. 7, p. 4061.

    Article  Google Scholar 

  24. Joshi, S., Fahrenholtz, W.G., and O’Keefe, M.J., Appl. Surf. Sci., 2011, vol. 257, no. 6, p. 1859.

    Article  Google Scholar 

  25. Joshi, S., Fahrenholtz, W.G., and O’Keefe, M.J., Surface and Coatings Technology, 2011, vol. 205, nos. 17–18, p. 4312.

    Article  Google Scholar 

  26. Zhang, H. and Zuo, Y., Appl. Surf. Sci., 2008, vol. 254, no. 16, p. 4930.

    Article  Google Scholar 

  27. Heller, D.K., Fahrenholtz, W.G., and O’Keefe, M.J., ECS Transactions, 2009, vol. 16, no. 43, p. 47.

    Google Scholar 

  28. Xingwen, Y. et al., Corrosion Sci., 2001, vol. 43, no. 7, p. 1283.

    Article  Google Scholar 

  29. Zhang, W. et al., Surface Engineering, 2002, vol. 18, no. 3, p. 224.

    Article  Google Scholar 

  30. Hasannejad, H. et al., Thin Solid Films, 2009, vol. 517, p. 4792.

    Article  Google Scholar 

  31. Heller, D.K., Fahrenholtz, W.G., and O’Keefe, M.J., Corrosion Sci., 2010, vol. 52, no. 2, p. 360.

    Article  Google Scholar 

  32. Campestrini, P., van Westing, E.P.M., and de Wit, J.H.W., Electrochim. Acta, 2001, vol. 46, no. 17, p. 2631.

    Article  Google Scholar 

  33. Qiao, Y.X. et al., Corrosion Sci., 2009, vol. 51, no. 5, p. 979.

    Article  Google Scholar 

  34. Orazem, M.E., Pebere, N., and Tribollet, B., J. Electrochem. Soc., 2006, vol. 153, no. 4, p. B129.

    Article  Google Scholar 

  35. Carnot, A. et al., Corrosion Sci., 2003, vol. 45, no. 11, p. 2513.

    Article  Google Scholar 

  36. Gu, C. et al., Surface and Coatings Technology, 2006, vol. 200, nos. 18–19, p. 5413.

    Article  Google Scholar 

  37. Hasannejad, H. et al., Appl. Surf. Sci., 2008, vol. 254, no. 18, p. 5683.

    Article  Google Scholar 

  38. Palomino, L.E.M. et al., Electrochim. Acta, 2007, vol. 52, no. 27, p. 7496.

    Article  Google Scholar 

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Correspondence to A. Sabour Rouhaghdam.

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Shoja Gharabagh, R., Sabour Rouhaghdam, A. Corrosion of environmentally friendly lanthanum conversion coating on AA2024-T3 aluminum alloy. Prot Met Phys Chem Surf 50, 88–93 (2014). https://doi.org/10.1134/S2070205114010183

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