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The relation between individual properties of alloy components and anodic behavior of multicomponent alloys in acidic environments. III. The effect of halide ions on active dissolution and passivation of Fe-Cr, Ni-Cr, and Fe-Cr-Ni alloys

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Abstract

The anodic behavior of alloy components in the presence of ions added to the solution is considered on the basis of concepts about the operation and blockade of active dissolution sites. Halide ions selectively change the anodic behavior of only nickel and iron components. The ions suppress reactions in which OH-ions are involved and promote new anodic processes, which is especially pronounced in the case of a nickel component in the presence of Cl−.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    V. P. Razygraev & M. V. Lebedeva

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  1. V. P. Razygraev
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  2. M. V. Lebedeva
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Correspondence to V. P. Razygraev.

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Original Russian Text © V.P. Razygraev, M.V. Lebedeva, 2012, published in Korroziya: Materialy, Zashchita, 2012, No. 4, pp. 1–8.

This work continues investigations [1, 2].

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Razygraev, V.P., Lebedeva, M.V. The relation between individual properties of alloy components and anodic behavior of multicomponent alloys in acidic environments. III. The effect of halide ions on active dissolution and passivation of Fe-Cr, Ni-Cr, and Fe-Cr-Ni alloys. Prot Met Phys Chem Surf 49, 811–817 (2013). https://doi.org/10.1134/S2070205113070137

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  • DOI: https://doi.org/10.1134/S2070205113070137

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