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Adsorption of 1,2,3-benzotriazole on zinc surface from phosphate solution

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Abstract

The electrochemical behavior of zinc in phosphate solutions (pH 8.9) containing benzotriazole (BTA) and NaCl is studied. Introduction of up to 15 mmol/L BTA into phosphate solution is found to nearly completely suppress the anodic current and increase the pitting potential. In accordance with XPS data, an oxide-hydroxide layer covered with (ZnBTA2) n protective complex is formed on zinc, phosphate being completely displaced from the surface layer by BTA.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    L. P. Kazanskii, E. M. Sokolova & Yu. E. Pronin

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  1. L. P. Kazanskii
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  2. E. M. Sokolova
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  3. Yu. E. Pronin
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Correspondence to L. P. Kazanskii.

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Original Russian Text © L.P. Kazanskii, E.M. Sokolova, Yu.E. Pronin, 2013, published in Korroziya: Materialy, Zashchita, 2013, No. 2, pp. 31–40.

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Kazanskii, L.P., Sokolova, E.M. & Pronin, Y.E. Adsorption of 1,2,3-benzotriazole on zinc surface from phosphate solution. Prot Met Phys Chem Surf 49, 844–853 (2013). https://doi.org/10.1134/S2070205113070101

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