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Cluster type molecule as novel corrosion inhibitor for steel in HCl solution

  • Physicochemical Problems of Materials Protection
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Abstract

The MOF [Ag (qox) (4-hb)] 1, was obtained at room temperature by the reaction of AgNO3, quinoxaline (qox) and 4-hydroxy benzoate (4-hb). A cluster molecule containing two silver atoms, two qox and two 4-hb ligands is considered the basic building block of the structure of 1. 3D-network structure is created via H-bonds and π-π stacking. The MOF 1 was tested as corrosion inhibitor for carbon steel in 1 M HCl solution using potentiodynamic polarization and electrochemical impedance techniques (EIS). The polarization measurements indicated that the MOF 1 is of mixed type. The adsorption of MOF 1 obeyed Langmuir adsorption isotherm. The inhibition efficiency increased with increase in MOF 1 concentration but decreased with increase in temperature. The activation and thermodynamic parameters were calculated and discussed. Mechanism of inhibition is explained on the basis of molecular structure of the inhibitor.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt

    Safaa El-din H. Etaiw & Mohamed M. El-bendary

  2. Department of Chemistry, Faculty of Science, El-Mansoura University, El-Mansoura, 35516, Egypt

    Abd El-Aziz S. Fouda

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  1. Safaa El-din H. Etaiw
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  2. Abd El-Aziz S. Fouda
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  3. Mohamed M. El-bendary
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Correspondence to Safaa El-din H. Etaiw.

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Etaiw, S.Ed.H., Fouda, A.EA.S. & El-bendary, M.M. Cluster type molecule as novel corrosion inhibitor for steel in HCl solution. Prot Met Phys Chem Surf 49, 113–123 (2013). https://doi.org/10.1134/S2070205113010061

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