Abstract
Published data on the influence of the effective nanoparticle size and the atomicity of clusters on the physicochemical properties of substances are considered. An interpretation is suggested for the analytical relations of the first and second laws of thermodynamics considered with conversion of the substance and the dependence of the chemical potential of reagents on the effective nanoparticle size taken into account.
Similar content being viewed by others
References
Gerasimov, Ya.I., Dreving, V.M., Eremin, E.N., et al., Kurs fizicheskoi khimii (The Course of Physical Chemistry), Moscow: Goskhimizdat, 1963, vol. 1, p. 624.
Prigozhin, I. and Kondepudi, D., Sovremennaya termodinamika (ot teplovykh dvigatelei do dissipativnykh struktur) (Modern Thermodynamics: from Heat Engines to Dissipative Structures, Moscow: Mir, 2009.
Shcherbakov, L.M., Dokl. Akad. Nauk SSSR, 1966, vol. 168, no. 2, p. 388.
Vigdorovich, V.I., Abstracts of Papers, Sb. nauchn. dokl. XVI Mezhdunarodnoi nauchno-prakticheskoi konf. “Povyshenie effektivnosti ispol’zovaniya resursov pri proizvodstve sel’skokhozyaistvennoi produktsii — novye tekhnologii i tekhnika novogo pokoleniya dlya rastenievodstva i zhivotnovodstva” (Proc. 16th Int. Research and Practice Conf. “Enhancement of the Efficiency of the Use of Resources in the Production of Agricultural Products: New Technologies and New-Generation Equipment for Plant Growing and Animal Husbandry”), Tambov, 2011, p. 347.
Vigdorovich, V.I., Tsygankova, L.E., and Osetrov, A.Yu., Prot. Met. Phys. Chem. Surf., 2011, vol. 47, no. 3, p. 410.
Shcherbakov, L.M., Kolloidn. Zh., 1961, vol. 23, no. 2, p. 215.
Shcherbakov, L.M. and Rykov, V.I., Kolloidn. Zh., 1961, vol. 23, no. 2, p. 221.
Sredzievskii, B., Zh. Russk. Fiz-Khim. Obshch., Fiz., 1883, vol. 15, no. 1, p. 39.
Helmholtz, R., Ann. Phys. (New York), 1886, vol. 27, no. 5, p. 508.
Strebeiko, P.E. O vliyanii izmel’cheniya na temperaturu perekhoda (On the Effect of Grinding on the Transition Temperature, Moscow: Inst. Obshch. i Neorg. Khim. Acad. Nauk SSSR, 1939.
Hill, T.L., J. Chem. Phys., 1962, vol. 36, p. 3182.
Landau, L.D. and Lifshits, E.M., Statisticheskaya fizika (Statistical Physics), Moscow: Fizmatgiz, 1964.
Rusanov, A.I., Termodinamika poverkhnostnykh yavlenii (Thermodynamics of Surface Phenomena), Leningrad: Khimiya, 1960.
Shcherbakov, L.M., Samsonov, V.M., and Novoselov, A.R., Zh. Fiz. Khim., 1991, vol. 65, no. 2, p. 459.
Rusanov, A.I., Fazovye ravnovesiya i poverkhnostnye yavleniya (Phase Equilibriums and Surface Phenomena), Leningrad: Khimiya, 1967.
Shi, F., J. Mater. Res., 1994, vol. 9, no. 10, p. 1307.
Sergeev, G.B., Nanokhimiya (Nanochemistry), Moscow: Izd. Mosk. Univ., 2007.
Kreibig, U. and Volmer, M., Optical Properties of Metal Clusters, Berlin: Springer-Verlag, 1995.
Lidorenko, N.S., Chizhik, S.P., Gladkikh, N.P., et al., Dokl. Akad. Nauk SSSR, 1981, vol. 257, no. 5, p. 1114.
Vashkyalis, A.Yu., Elektrokhimiya, 1978, vol. 14, no. 12, p. 1770.
Kravchenko, T.A., Polyanskii, L.N., Elanichev, A.I., and Konev, D.V., Nanokompozity metall-ionoobmennik (Metal-Ion Exchanger Nanocomposites), Moscow: Nauka, 2009.
Sidnin, A.I. and Sheberstov, V.I., Zh. Nauchn. Prikl. Fotogr. Kinematogr., 1983, vol. 28, no. 1, p. 7.
Tur’yan, Ya.I., Okislitel’no-vosstanovitel’nye reaktsii i potentsialy v analiticheskoi khimii (Redox Reactions), Moscow: Khimiya, 1989.
Spravochnik khimika (Chemist’s Handbook), Nikol’skii, B.P., Ed., Leningrad: Khimiya, 1965, vol. 3, ed. 2.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.I. Vigdorovich, L.E. Tsygankova, 2012, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2012, Vol. 48, No. 5, pp. 415–421.
Rights and permissions
About this article
Cite this article
Vigdorovich, V.I., Tsygankova, L.E. Thermodynamics of nanostructured materials. Prot Met Phys Chem Surf 48, 501–507 (2012). https://doi.org/10.1134/S2070205112050152
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070205112050152