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The effect of hydrodynamic conditions on the rate of copper cathodic reduction from aqueous ethanol environments

  • Physicochemical Processes at the Interfaces
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Abstract

The effect of hydrodynamic conditions on copper electroplating from aqueous ethanol CuSO4 solutions is studied. Adding ethanol is found to result in a decrease in the ionic mass transfer rate in the solution. Experimental data are analyzed on the basis of the convective diffusion equation for a rotating disc electrode. Diffusivities of copper cations and kinetic current densities are estimated.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    A. V. Noskov, S. A. Chulovskaya & V. I. Parfenyuk

  2. Ivanovo State University of Chemistry and Technology, pr. Fridrikha Engelsa 7, Ivanovo, 153000, Russia

    A. V. Balmasov & V. I. Parfenyuk

Authors
  1. A. V. Noskov
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  2. S. A. Chulovskaya
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  3. A. V. Balmasov
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  4. V. I. Parfenyuk
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Corresponding author

Correspondence to V. I. Parfenyuk.

Additional information

Original Russian Text © A.V. Noskov, S.A. Chulovskaya, A.V. Balmasov, V.I. Parfenyuk, 2012, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2012, Vol. 48, No. 5, pp. 435–439.

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Noskov, A.V., Chulovskaya, S.A., Balmasov, A.V. et al. The effect of hydrodynamic conditions on the rate of copper cathodic reduction from aqueous ethanol environments. Prot Met Phys Chem Surf 48, 520–523 (2012). https://doi.org/10.1134/S2070205112050073

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  • DOI: https://doi.org/10.1134/S2070205112050073

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