Abstract
The possibilities of diffuse and specular reflectance Fourier-transform infrared spectroscopy in long-term corrosion monitoring are studied. A 15-week period of interaction between carbon tetrachloride and a commercial aluminum sheet is followed. Analysis of the results obtained reveals a complex and multistage character of the interaction between CCl4 and aluminum surface. The final product of the reaction is shown to be chlorine-containing hydrocarbon, which is strongly bound to the metal surface.
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References
Techniques in Electrochemistry, Corrosion and Metal Finishing: A Handbook, Kuhn, A.T., Ed., New York: Wiley, 1987.
Roberge P. R. Corrosion inspection and monitoring. N.Y.: John Wiley and Sons, 2007. 383 p.
Electrochemical and Optical Techniques for the Study and Monitoring of Metallic Corrosion, Ferreira, M.G.S. and Melendres, C.A., Eds., Netherlands: Kluwer, 1991.
Kotenev, V.A. and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2009, vol. 45, no. 4, p. 472.
Applied Infrared Spectroscopy, Kendall, D.N., Ed., New York: Reinhold, 1966.
Socolova, N.P., Tsivadze, A.Yu., Bulgakova, R.A.// Prot. Met. Phys. Chem. Surf., 2010. vol. 46. no. 4. p. 414.
Tarasova, N.V., Saltykov, S.N., and Vedishchev, V.V., Prot. Met. Phys. Chem. Surf., 2010, vol. 46, no. 2, p. 271.
Shcherbakov, A.I., Oshe, E.K., Skvortsova, I.B., et al., Prot. Met. Phys. Chem. Surf., 2011, vol. 47, no. 2, p. 203.
Rhodes F. H., Carty J. T. // Ind. Eng. Chem. 1925. V. 17. no. 9. p. 909.
Stern, M. and Uhlig, H.H., J. Electrochem. Soc., 1952, vol. 99, no. 10, p. 381.
Hollingsworth E. H. and Hunsicker H. Y., in Corrosion and Corrosion Protection Handbook, P. A. Schweitze (Ed.), Marcel Dekker, New York, 1983. P. 111; Vargel C. Corrosion of aluminium.
Ellialtioglu, R.M., White, H.W., Godwin, L.M., and Wolfram, T., J. Chem. Phys., 1980, vol. 72, no. 10, p. 5291.
Little, L.H., Infrared Spectra of Adsorbed Species, New York: Academic, 1966.
Davydov, A.A., IK-spektroskopiya v khimii poverkhnosti okislov (Infrared Spectroscopy in the Chemistry of Oxide Surfaces), Novosibirsk: Nauka, 1984.
Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, 2009.
The Sadtler Standard Spectra. Inorganics and Related Compounds, Sadtler Research Laboratories, Philadelphia Inc., 1972.
Sverdlov, L.M., Kovner, M.A., and Krainov, E.P., Kolebatel’nye spektry mnogoatomnykh molekul (Vibrational Spectra of Polyatomic Molecules), Moscow: Nauka, 1970.
The Aldrich Library of Infrared Spectra, Pouchert, C.J., Ed., Aldrich Chemical, 1975.
Del Bene, J.E. and Shavitt, I., J. Mol. Str. (Theochem.), 1994, vol. 314, p. 9.
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Original Russian Text © I.A. Gagina, N.P. Sokolova, N. P. Platonova, V.A. Kotenev, A.Yu. Tsivadze, 2012, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2012, Vol. 48, No. 5, pp. 495–500.
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Gagina, I.A., Sokolova, N.P., Platonova, N.P. et al. Fourier transform infrared spectroscopy in long-term corrosion monitoring of the interaction between a commercial aluminum sheet and carbon tetrachloride at room temperature. Prot Met Phys Chem Surf 48, 591–595 (2012). https://doi.org/10.1134/S2070205112050036
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DOI: https://doi.org/10.1134/S2070205112050036