Abstract
The formation kinetics of inhibitor nuclei during the origination of the primary layer at the metal interface is considered. A model of interactions that change the equilibrium state is presented. An equation of the process referred to as the evolution of nuclei is derived.
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Volmer, M., Kinetika obrazovaiya novoi fazy (Kinetics of New Phase Formation), Moscow: Nauka, 1986.
Popov, Yu.A. and Koval’chukov, N.A., Fizikokhimiya Poverkhn. Zashch. Mater., 2010, vol. 46, no. 1, p. 24 [Prot. Met. Phys. Chem. Surf., 2010, vol. 46, no. 1, p. 27].
Andreev, V.A. and Andreeva, N.P., Krat. Soobshch. Fiz., Moscow: FIAN, 2001, no. 11, p. 3.
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Original Russian Text © Yu.A. Popov, N.A. Koval’chukov, V.N. Chistokhvalov, 2010, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2010, Vol. 46, No. 2, pp. 170–173.
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Popov, Y.A., Koval’chukov, N.A. & Chistokhvalov, V.N. Fluctuation formation model and operation mechanism of inhibiting layers on metals: II. Interaction and evolution of inhibitor nuclei. Prot Met Phys Chem Surf 46, 202–205 (2010). https://doi.org/10.1134/S2070205110020061
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DOI: https://doi.org/10.1134/S2070205110020061