Abstract
Some peculiarities of the time and temperature dependences of the high-temperature oxidation of a low-alloyed low-carbon steel covered with a glass coating are studied. The dependences characterizing the oxidation of steel without coating and that covered with it are found to have a similar character. Based on the data obtained, it is supposed that, at low temperatures, the prevailing mechanism involves the penetration of oxygen toward the metal surface through macro- and micropores of the coating, while, at high temperatures, the oxidation, which seems to be related to the electrochemical corrosion of the surface under a glass melt, becomes predominant. The article is published in the original.
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References
Popov, N.N., In Zharostoikie i teplostoikie pokrytiya (Heat-Proof and Heat-Resistant Coatings), Leningrad: Nauka, 1969, p. 219.
Akimenko, A.D., Kuzelev, M.Ya., and Skvortsov, A.A., Kuznechno-Shtamp. Proizv., 1964, no. 4, p. 37.
Solntsev, S.S. and Tumanov, A.T., Zashchitnye pokrytiya metallov pri nagreve (Protective Metal Coatings under Heating), Moscow: Mashinostoroenie, 1976.
Manegin, Yu.V. and Anisimova, I.V., Steklosmazki i zashchitnye pokrytiya dlya goryachei obrabotki metallov (Glass Lubricants and Protective Coatings for Heat Treatment of Metals), Moscow: Metallurgiya, 1978.
Popov, N.N., Appen, A.A., and Antonova, E.A., In Temperaturoustoichivye zashchitnye pokrytiya (Heat-Resistant Protective Coatings), Leningrad: Nauka, 1968, p. 257.
Appen, A.A., Zharostoikie neorganicheskie pokrytiya na stali (Heat-Resistant Inorganic Coatings on Steels), Leningrad: LDNTP, 1961.
Vargin, V.V. and Pevzner, B.Z., Novoe v emalirovanii metallov (The New in Enameling Metals), Moscow: NIIMASh, 1965.
Primenenie steklyannykh zashchitnykh pokrytii pri shtampovke lopatok iz zharoprochnykh splavov (Using Glass Protective Coatings When Punching Blades of Heat-Resistant Alloys), Korneev, N.I., Skugarev, I.G., and Kuleshov, M.Ya., Eds., Moscow: Mashinostroenie, 1966.
Svirskii, L.D., Sobol’, N.P., and Neelova, G.V., In Zharostoikie i teplostoikie pokrytiya (Heat-Proof and Heat-Resistant Coatings), Leningrad: Nauka, 1969.
Svirskii, L.D. and Sobol’, N.P., In Temperaturoustoichivye zashchitnye pokrytiya (Heat-Resistant Protective Coatings), Leningrad: Nauka, 1968, p. 246.
Borisenko, A.I. and Nikolaeva, A.V., Tonkosloinye stekloemalevye i steklokeramicheskie pokrytiya (Thin-Wall Glass-Enamel and Glass-Ceramic Coatings), Leningrad: Nauka, 1970.
Appen, A.A., In Zashchitnye vysokotemperaturnye pokrytiya (Protective High-Temperature Coatings), Leningrad: Nauka, 1972.
Svirskii, L.D., Bragina, L.L., and Frolenkov, K.Yu., In Novye vidy emalirovannoi posudy i tekhnologicheskie protsessy ee izgotovleniya (Novel Kinds of Enamel Ware and Technological Processes of Its Production), Sverdlovsk: UNIIChM, 1983, p. 19.
Frolenkov, K.Yu., Izv. VUZov. Mashinostroenie, 1997, nos. 7–9, p. 128.
Emalirovanie metallicheskikh izdelii (Enameling Metallic Manufacture), Vargin, V.V., Ed., Leningrad: Mashinostroenie, 1972.
Gushchina, I.I., Kuznechno-Shtamp. Proizv., 1965, no. 4, p. 39.
Fogel’, V.N., In Stekloobraznoe sostoyanie (Glassy State), Moscow: Nauka, 1960, p.24.
Appen, A.A., Khimiya stekla (Chemistry of Glasses), Leningrad: Khimiya, 1970.
Pavlushkin, N.M., Osnovy tekhnologii sitallov (Basic Principles of Glass-Ceramic Technology), Moscow: Stroiizdat, 1979.
Evstrop’ev, K.K., Diffuzionnye protsessy v stekle (Diffusion Processes in Glass), Leningrad: Stroiizdat, 1970.
Myuller, R.L., In Stekloobraznoe sostoyanie (Glassy State), Moscow: Nauka, 1960, p. 60.
Sanditov, D.S. and Bartenev, G.M., Fizicheskie svoistva neuporyadochennykh struktur (Physical Properties of Unordered Structures), Novosibirsk: Nauka, 1982.
Appen, A.A., Temperaturoustoichivye neorganicheskie pokrytiya (Temperature-Resistant Inorganic Coatings), Leningrad: Khimiya, 1967.
Steklo. Spravochnik (Glass. Handbook), Pavlushkin, N.M., Ed., Moscow: Stroiizdat, 1973.
Pavlushkin, N.M. and Sentyurin, G.G., Praktikum po tekhnologii stekla. (Practicum in Glass Technology), Moscow: Promstroiizdat, 1957.
Instruktsiya opredeleniya plavkosti emalei (Directions of Determining Fusibility of Enamels), Novocherkassk: NPI, 1977.
Spravochnik metallista (Handbook of a Metalworker), Malov, A.N., Ed., Moscow: Mashinostroenie, 1976, vol. 2.
L’vovskii, E.N, Statisticheskie metody postroeniya empiricheskikh formul. Uchebnoe posobie dlya vtuzov (Statistical Methods of Deriving Empirical Formulas. Higher School Tutorial), Moscow: Vysshaya shkola, 1988.
Tomashov, N.D. and Chernova, G.P., Teoriya korrozii i korrozionnostoikie konstruktsionnye splavy (Theory of Corrosion and Corrosion-Resistant Structural Alloys), Moscow: Metallurgiya, 1993.
Kofstad, P., High Temperature Oxidation of Metals, New York: Wiley, 1966.
Arkharov, V.I., Okislenie metallov (Metal Oxidation), Moscow: Metallurgizdat, 1945.
Umanskii, Ya.S., Finkel’shtein, B.N., and Blanter, M.E., Fizicheskie osnovy metallovedeniya (Physical Bases of Physical Metallurgy), Moscow: Metallurgizdat, 1949.
Hauffe, K., Reactions in and on Solids, New York: US Atomic Energy Commission, 1962.
Shelest, A.E., Mikrokal’kulyatory v fizike (Microcalculators in Physics), Moscow: Nauka, 1988.
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Frolenkov, K.Y., Frolenkova, L.Y. & Shadrin, I.F. High-temperature oxidation of low-alloyed steel under glass coatings. Prot Met Phys Chem Surf 46, 103–109 (2010). https://doi.org/10.1134/S2070205110010156
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DOI: https://doi.org/10.1134/S2070205110010156