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Effect of atomic hydrogen on the anodic dissolution of iron in a weakly acidic sulfate electrolyte

  • Physicochemical Processes at the Interfaces
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Abstract

Using a membrane electrode, atomic hydrogen is shown to decelerate the dissolution of iron in sulfate and sulfate-citrate electrolytes (pH 5.5) in a potential range of the active metal dissolution and accelerates the process at the prepassivation potentials. Impedance spectra of iron at a controlled degree of surface coverage with hydrogen atoms are recorded. Rate constants of elementary stages of the anodic process are calculated and the reaction scheme of the iron dissolution in sulfate environments is made more accurate.

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References

  1. Khaldeev, V.G. and Borisova, T.V., Itogi Nauki Tekhn., Ser. Elektrokhimiya., 1989, vol. 30, p. 3.

    Google Scholar 

  2. Podobaev, N.I. and Klimov, G.G., Zashch. Met., 1980, vol. 16, no. 5, p. 611.

    CAS  Google Scholar 

  3. Podobaev, A.N., Reformatskaya, I.I., and Krivokhvostova, O.V., Zashch. Met., 2000, vol. 36, no. 4, p. 352.

    Google Scholar 

  4. Marshakov, A.I., Rybkina, A.A., and Nenasheva, T.A., Korroz.: Mater., Zashch., 2006, no. 5, p. 2.

  5. Maleeva, M.A., Rybkina, A.A., Elkin, V.V., and Marshakov, A.I., Fizikokhim. Poverkhn. Zashch. Mater., 2008, vol. 44, no. 6, p. 587.

    Google Scholar 

  6. Pyun, Su-I. and Oriani, R.A., Corros. Sci., 1989, vol. 29, no. 5, p. 485.

    Article  CAS  Google Scholar 

  7. Yang, Q. and Luo, J.L., J. Electrochem. Soc., vol. 148, no. 1, p. B29.

  8. Yu, J.G., Zhang C.S., Luo J.L., and Norton, P.R., J. Electrochem. Soc., 2003, vol. 150, no. 2, p. B68.

    Article  CAS  Google Scholar 

  9. Zeng, Y.M., Luo, J.L., and Norton, P.R., Electrochim. Acta, 2004, vol. 49, p. 703.

    Article  CAS  Google Scholar 

  10. Nenasheva, T.A. and Marshakov, A.I., Korroz.: Mater., Zashch., 2008, no. 4, p. 10.

  11. Keddam, M., Mattos, O.R., and Takenouti, H., J. Electrochem. Soc., 1981, vol. 128, no. 2, p. 257.

    Article  CAS  Google Scholar 

  12. Marshakov, A.I. and Nenasheva, T.A., Zashch. Met., 2002, vol. 38, no. 6, p. 624.

    Google Scholar 

  13. Marshakov, A.I., Rybkina, A.A., and Skuratnik, Ya.B., Elektrokhimiya, 2000, vol. 36, no. 10, p. 1244.

    Google Scholar 

  14. Marshakov, A.I. and Nenasheva, T.A., Zashch. Met., 2001, vol. 37, no. 6, p. 603.

    Google Scholar 

  15. Marshakov, A.I. and Nenasheva, T.A., Zashch. Met., 2006, vol. 42, no. 2, p. 138.

    Google Scholar 

  16. Marshakov, A.I., Nenasheva, T.A., Rybkina, A.A., and Maleeva, M.A., Zashch. Met., 2007, vol. 43, no. 1, p. 1.

    Google Scholar 

  17. Iyer, R.N., Pickering, H.W., and Zamanzadeh, M., J. Electrochem. Soc., 1989, vol. 136, no. 9, p. 2463.

    Article  CAS  Google Scholar 

  18. Kaesche, H., Die Korrosion der Metalle, Berlin: Springer, 1979.

    Google Scholar 

  19. Maleeva, E.A., Cand. Sci. (Chem.) Dissertation, Moscow: IFKh RAN, 1993.

    Google Scholar 

  20. Keddam, M., Mattos, O.R., and Takenouti, H., J. Electrochem. Soc., 1981, vol. 128, no. 2, p. 266.

    Article  CAS  Google Scholar 

  21. Kim, C.D. and Wilde, B.E., J. Electrochem. Soc., 1961, vol. 118, no. 2, p. 202.

    Article  Google Scholar 

  22. Kabanov, B.N., Burstein, R., and Frumkin, A., Disc. Faraday Soc., 1947, vol. 1, no. 1, p. 259.

    Google Scholar 

  23. Kolotyrkin, Ya.M., Usp. Khim., 1962, vol. 31, no. 3, p. 322.

    CAS  Google Scholar 

  24. Florianovich, G.M., Itogi Nauki Tekhn., Ser. Korroz. Zashch. Korroz., 1978, vol. 6, p. 136.

    CAS  Google Scholar 

  25. Elkin, V.V., Maleeva, M.A., and Marshakov, A.I., Korroz.: Mater., Zashch., 2007, no. 7, p. 42.

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Authors and Affiliations

  1. Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. I. Marshakov, M. A. Maleeva, A. A. Rybkina & V. V. Elkin

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  1. A. I. Marshakov
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  2. M. A. Maleeva
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  3. A. A. Rybkina
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  4. V. V. Elkin
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Corresponding author

Correspondence to A. I. Marshakov.

Additional information

Original Russian Text © A.I. Marshakov, M.A. Maleeva, A.A. Rybkina, V.V. Elkin, 2010, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2010, Vol. 46, No. 1, pp. 36–46.

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Marshakov, A.I., Maleeva, M.A., Rybkina, A.A. et al. Effect of atomic hydrogen on the anodic dissolution of iron in a weakly acidic sulfate electrolyte. Prot Met Phys Chem Surf 46, 40–49 (2010). https://doi.org/10.1134/S2070205110010053

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  • DOI: https://doi.org/10.1134/S2070205110010053

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