Abstract
The phase diagram of the Ni-Mo-O system and the potential-pH diagram of the Ni-Mo-H2O system at 25°C are composed. The electrochemical equilibrium diagram of a NiCr15Mo15 alloy (70%Ni + 15%Mo + 15%Cr) at the standard temperature is refined. The beneficial effect of molybdenum on the stability of the alloys’ passive state is discussed in terms of thermodynamics.
Similar content being viewed by others
References
H. Ulig, Corrosion and Corrosion Control, New York: Wiley, 1971.
Ul’yanin, E.A., Svistunova, T.V., and Levin, F.P., Korozionno-stoikie splavy na osnove zheleza i nikelya (Iron- and Nickel-based Corrosion-resistant Alloys), Moscow: Metallurgiya, 1986.
Plaskeev, A.V., Knyazheva, V.M., and Kuchubaev, Kh.G., Zashch. Met., 1998, vol. 34, no. 5, pp. 497–502.
Agladze, T.R. and Dzhakibakhchieva, L.E., Zashch. Met., 1991, vol. 27, no. 4, pp. 561–574.
Novakovskii, V.M., Zashch. Met., 1991, vol. 27, no. 4, pp. 532–545.
Kolotyrkin, Ya.M., Freiman, L.I., Reformatskaya, I.I., and Pan’shin, E.A., Zashch. Met., 1994, vol. 30, no. 5, pp. 453–462.
Plaskeev, A.V., Zashch. Met., 1995, vol. 31, no. 1, pp. 42–46.
Tyurin, A.G., Zashch. Met., 2003, vol. 39, no. 6, pp. 633–639.
Tyurin, A.G., Zashch. Met., 2003, vol. 39, no. 4, pp. 410–416.
Diagrammy sostoyaniya dvoinykh metallicheskikh sistem: Spravochnik v 3 tomakh. T. 3. kn.1 / Pod obshch red. N.P. Lyakusheva (Phase Diagrams of Binary Metal Systems: a Reference Book, in Three Volumes. Vol. 3, issue 1) N.P, Lyakishev, Ed., Moscow: Mashinostroenie, 1997, pp. 856–858.
Brewer, L. and Lsmoreaux, R.H., Atomic Energy Review, Special Issue π 7. Molybdenum: Physico-Chemical Properties of Its Compounds and Alloys, Vienna: International Atomic Energy, 1980, pp. 195–356.
Tyurin, A.G., Termodinamika khimicheskoi ustoichivosti splavov. V dvukh chastyakh. Ch.1. Obshchie printsipy. Vysokotemperaturnoe okislenie, in Chelyab. Gos. Univ. (Thermodynamics of Chemical Stability of Alloys, in Two Parts. Pt. 1. General Principles. High-temperature Oxidation), Chelyabinsk, 2004.
Tyurin, A.G., Termodinamika khimicheskoi ustoichivosti splavov. V dvukh chastyakh. Ch. 2. Nizkotemperaturnoe okislenie, Chelyab. Gos. Univ. (Thermodynamics of Chemical Stability of Alloys, in Two Parts. Pt. 2. Low-temperature Oxidation), Chelyabinsk, 2004.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.G. Tyurin, N.V. Markina, 2009, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2009, Vol. 45, No. 3, pp. 326–333.
Rights and permissions
About this article
Cite this article
Tyurin, A.G., Markina, N.V. Diagrams of chemical and electrochemical equilibriums of nickel-molybdenum and nickel-chromium-molybdenum alloys. Prot Met Phys Chem Surf 45, 361–368 (2009). https://doi.org/10.1134/S2070205109030149
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070205109030149