Abstract
The thermodynamic characteristics of the adsorption of proline and its derivatives at graphitized thermal soot (GTS) were determined. It was found that the arrangement of the hydroxy groups in the amino acid molecule influences its adsorption at GTS. The thermodynamic characteristics of the adsorption of the stereoisomers of hydroxy- and dihydroxyproline at GTS were calculated. The influence of the internal rotation angles in the molecules of proline and its derivatives on their adsorption at GTS was studied.
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Avgul’, N.N., Kiselev, A.V., and Poshkus, D.P., Adsorbtsiya gasov i parov na odnorodnykh poverkhnostyakh (The Adsorption of Gases and Vapors at Homogeneous Surfaces), Moscow: Khimiya, 1975, p. 384.
Buryak, A.K., Usp. Khim., 2002, vol. 64, no. 5, p. 788.
Sunozova, E.V., Trubnikov, V.I., and Sakodynskii, K.I., Gazovaya khromatografiya aminokislot (Gas Chromatography of Amino Acids), Moscow: Nauka, 1976, p. 83.
Gavrilova, T.B., Kiselev, A.V., Kulikov, N.S., and Vlasenko, E.V., Chromatographia, 1986, vol. 22, p. 59.
Topalova, I., Petsev, N., Dimitrov, Chr., et al., Chromatographia, 1986, vol. 364, p. 431.
Kiselev, A.V., Poshkus, D.P., and Yashin, Ya.I., Molekulyarnye osnovy adsorbtsionnoi khromatografii (Molecular Foundations of Adsorption Chromatography), Moscow: Khimiya, 1986, p. 272.
Ioffe, B.V., Refraktometricheskie metody khimii (Refractometric Techniques in Chemistry), Leningrad: Khimiya, 1974, p. 400.
Kratkii spravochnik fiziko-khimicheskikh velichin (A Concise Handbook of Physicochemical Quantities), Ravdel’, A.A. and Ponomareva, A.M., Eds., St. Petersburg: Spetsial’naya Literatura, 1999, p. 232.
Yashkin, S.N., Kurbatova, S.V., Petrova, E.I., and Buryak, A.K., Izv. Akad. Nauk, Ser. Khim., 2001, no. 5, p. 787.
Kiselev, A.V. and Markosyan, D.L., Arm. Khim. Zh., 1985, vol. 38, p. 29.
Yashkin, S.N., Grigor’eva, O.B., and Buryak, A.K., Izv. Akad. Nauk, Ser. Khim., 2001, no. 6, p. 938.
Kuznetsova, E.S., Ul’yanov, A.V., and Buryak, A.K., Zashch. Met., 2008, vol. 44, no. 3, p. 260.
Zefirov, Yu.V. and Zorkii, P.M., Usp. Khim., 1995, vol. 64, no. 5, p. 446.
Eksperimental’nye metody v adsorbtsii i molekulyarnoi khromatografii (Experimental Techniques in Adsorption and Molecular Chromatography), Kiselev, A.V. and Dreving, V.P., Eds., Moscow: Mosk. Univ., 1995, p. 447.
Gurskaya, G.V., Struktura aminokislot (Amino Acid Structures), Moscow: Nauka, 1966, p. 158.
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Original Russian Text © E.S. Kuznetsova, A.V. Ul’yanov, A.K. Buryak, 2009, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2009, Vol. 45, No. 3, pp. 271–276.
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Kuznetsova, E.S., Ul’yanov, A.V. & Buryak, A.K. Comparative analysis of the adsorption of the stereoisomers of hydroxy- and dihydroxyproline at graphitized thermal soot. Prot Met Phys Chem Surf 45, 289–294 (2009). https://doi.org/10.1134/S2070205109030046
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DOI: https://doi.org/10.1134/S2070205109030046