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Comparative analysis of the adsorption of the stereoisomers of hydroxy- and dihydroxyproline at graphitized thermal soot

  • Molecular and Supramolecular Structures at the Interfaces
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Abstract

The thermodynamic characteristics of the adsorption of proline and its derivatives at graphitized thermal soot (GTS) were determined. It was found that the arrangement of the hydroxy groups in the amino acid molecule influences its adsorption at GTS. The thermodynamic characteristics of the adsorption of the stereoisomers of hydroxy- and dihydroxyproline at GTS were calculated. The influence of the internal rotation angles in the molecules of proline and its derivatives on their adsorption at GTS was studied.

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References

  1. Avgul’, N.N., Kiselev, A.V., and Poshkus, D.P., Adsorbtsiya gasov i parov na odnorodnykh poverkhnostyakh (The Adsorption of Gases and Vapors at Homogeneous Surfaces), Moscow: Khimiya, 1975, p. 384.

    Google Scholar 

  2. Buryak, A.K., Usp. Khim., 2002, vol. 64, no. 5, p. 788.

    Google Scholar 

  3. Sunozova, E.V., Trubnikov, V.I., and Sakodynskii, K.I., Gazovaya khromatografiya aminokislot (Gas Chromatography of Amino Acids), Moscow: Nauka, 1976, p. 83.

    Google Scholar 

  4. Gavrilova, T.B., Kiselev, A.V., Kulikov, N.S., and Vlasenko, E.V., Chromatographia, 1986, vol. 22, p. 59.

    Article  CAS  Google Scholar 

  5. Topalova, I., Petsev, N., Dimitrov, Chr., et al., Chromatographia, 1986, vol. 364, p. 431.

    Article  CAS  Google Scholar 

  6. Kiselev, A.V., Poshkus, D.P., and Yashin, Ya.I., Molekulyarnye osnovy adsorbtsionnoi khromatografii (Molecular Foundations of Adsorption Chromatography), Moscow: Khimiya, 1986, p. 272.

    Google Scholar 

  7. Ioffe, B.V., Refraktometricheskie metody khimii (Refractometric Techniques in Chemistry), Leningrad: Khimiya, 1974, p. 400.

    Google Scholar 

  8. Kratkii spravochnik fiziko-khimicheskikh velichin (A Concise Handbook of Physicochemical Quantities), Ravdel’, A.A. and Ponomareva, A.M., Eds., St. Petersburg: Spetsial’naya Literatura, 1999, p. 232.

    Google Scholar 

  9. Yashkin, S.N., Kurbatova, S.V., Petrova, E.I., and Buryak, A.K., Izv. Akad. Nauk, Ser. Khim., 2001, no. 5, p. 787.

  10. Kiselev, A.V. and Markosyan, D.L., Arm. Khim. Zh., 1985, vol. 38, p. 29.

    CAS  Google Scholar 

  11. Yashkin, S.N., Grigor’eva, O.B., and Buryak, A.K., Izv. Akad. Nauk, Ser. Khim., 2001, no. 6, p. 938.

  12. Kuznetsova, E.S., Ul’yanov, A.V., and Buryak, A.K., Zashch. Met., 2008, vol. 44, no. 3, p. 260.

    Google Scholar 

  13. Zefirov, Yu.V. and Zorkii, P.M., Usp. Khim., 1995, vol. 64, no. 5, p. 446.

    CAS  Google Scholar 

  14. Eksperimental’nye metody v adsorbtsii i molekulyarnoi khromatografii (Experimental Techniques in Adsorption and Molecular Chromatography), Kiselev, A.V. and Dreving, V.P., Eds., Moscow: Mosk. Univ., 1995, p. 447.

    Google Scholar 

  15. Gurskaya, G.V., Struktura aminokislot (Amino Acid Structures), Moscow: Nauka, 1966, p. 158.

    Google Scholar 

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Correspondence to E. S. Kuznetsova.

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Original Russian Text © E.S. Kuznetsova, A.V. Ul’yanov, A.K. Buryak, 2009, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2009, Vol. 45, No. 3, pp. 271–276.

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Kuznetsova, E.S., Ul’yanov, A.V. & Buryak, A.K. Comparative analysis of the adsorption of the stereoisomers of hydroxy- and dihydroxyproline at graphitized thermal soot. Prot Met Phys Chem Surf 45, 289–294 (2009). https://doi.org/10.1134/S2070205109030046

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  • DOI: https://doi.org/10.1134/S2070205109030046

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