Abstract
Adapting domestic commercial catalysts for use in such important technological processes as the environmentally friendly production of hydrogen accompanied by СОх and NОх emissions is in demand under import substitution conditions. Ammonia seems to be the most promising Н2 accumulator, due to its high hydrogen density and simple storage and transportation. This work considers the possibility of using the domestic NIAP-03-01, NIAP-07-01, NIAP-06-06 catalysts and Со-Al2O3/SiO2 developed by the authors in the ammonia dissociation reaction. The conversion and hydrogen production capacity grow in the order NIAP-06-06<NIAP-03-01<NIAP-07-01<Со-Al2O3/SiO2. The conversion of ammonia on Со-Al2O3/SiO2 is close to 100% at 550°C and a gas hourly space velocity (GHSV) of 3000 h−1. The effective activation energies of all the catalysts are comparable to the available literature data for the ammonia decomposition reaction to potentially enable their application at moderate temperatures.
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This work was performed as a part of the Strategic Project “Scientific Innovative Cluster and Contract R&D Center” of the program for the development of Platov South Russian State Polytechnic University as a part of the Strategic Academic Leadership Program “Priority-2023”.
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Yakovenko, R.E., Krasnyakova, T.V., Dul’nev, A.V. et al. Estimating the Efficiency of Commercial Domestic Catalysts in the Reaction of Ammonia Decomposition. Catal. Ind. 16, 58–68 (2024). https://doi.org/10.1134/S2070050424010100
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DOI: https://doi.org/10.1134/S2070050424010100