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Methanol Decomposition to Synthesis Gas over Supported Platinum-Containing Catalysts

  • CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY
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Abstract

The properties of supported Pt-containing granular (Pt/Ce0.75Zr0.25O2 – δ) and structured catalysts (Pt/Ce0.75Zr0.25O2 – δ/η-Al2O3/FeCrAl) in methanol decomposition to synthesis gas for feeding solid oxide fuel cells have been studied. It has been shown that the use of a structured catalyst for the methanol decomposition reaction is promising. It has been found that the addition of a small amount of oxygen to the feed mixture hinders the formation of carbon and thereby increases the on-stream stability of the catalyst. At atmospheric pressure, a temperature of ≈400°C, a reaction mixture feed space velocity of 5.6 L/(gcat h), and a CH3OH : air volume ratio of 1, the proposed 0.15 wt % Pt/8 wt % Ce0.75Zr0.25O2 – δ/6 wt % η-Al2O3/FeCrAl structured catalyst can provide a complete methanol conversion to synthesis gas with a total content of H2 and CO of ≈64 vol % and a productivity with respect to synthesis gas of ≈6.7 L(H2 + CO)/(gcat h).

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REFERENCES

  1. Pinaeva, L.G. and Noskov, A.S., Catal. Ind., 2022, vol. 14, no. 1, pp. 66–85. https://doi.org/10.1134/S2070050422010081

    Article  Google Scholar 

  2. Shoynkhorova, T.B., Simonov, P.A., Potemkin, D.I., Snytnikov, P.V., Belyaev, V.D., Ishchenko, A.V., Svintsitskiy, D.A., and Sobyanin, V.A., Appl. Catal., B, 2018, vol. 237, pp. 237–244. https://doi.org/10.1016/j.apcatb.2018.06.003

    Article  CAS  Google Scholar 

  3. Zyryanova, M.M., Badmaev, S.D., Belyaev, V.D., Amosov, Yu.I., Snytnikov, P.V., Kirillov, V.A., and Sobyanin, Catal. Ind., 2013, vol. 5, no. 4, pp. 312–317. https://doi.org/10.1134/S2070050413040107

    Article  Google Scholar 

  4. Li, D., Li, X., and Gong, J., Chem. Rev., 2016, vol. 116, no. 19, pp. 11529–11653. https://doi.org/10.1021/acs.chemrev.6b00099

    Article  CAS  PubMed  Google Scholar 

  5. Pechenkin, A.A., Badmaev, S.D., Belyaev, V.D., Paukshtis, E.A., Stonkus, O.A., and Sobyanin, V.A., Kinet. Catal., 2017, vol. 58, no. 5, pp. 577–584. https://doi.org/10.1134/S0023158417050196

    Article  CAS  Google Scholar 

  6. Lytkina, A.A., Orekhova, N.V., Ermilova, M.M., Belenov, S.V., Guterman, V.E., Efimov, M.N., and Yaroslavtsev, A.B., Catal. Today, 2016, vol. 268, pp. 60–67. https://doi.org/10.1016/j.cattod.2016.01.003

    Article  CAS  Google Scholar 

  7. Gribovskiy, A.G., Makarshin, L.L., Andreev, D.V., Klenov, O.P., and Parmon, V.N., Chem. Eng. J., 2015, vol. 273, pp. 130–137. https://doi.org/10.1016/j.cej.2015.03.036

    Article  CAS  Google Scholar 

  8. Lytkina, A.A., Zhilyaeva, N.A., Ermilova, M.M., Orekhova, N.V., and Yaroslavtsev, A.B., Int. J. Hydrogen Energy, 2015, vol. 40, no. 31, pp. 9677–9684. https://doi.org/10.1016/j.ijhydene.2015.05.094

    Article  CAS  Google Scholar 

  9. Lytkina, A.A., Orekhova, N.V., Ermilova, M.M., Petriev, I.S., Baryshev, M.G., and Yaroslavtsev, A.B., Membr. Membr. Tekhnol., 2017, vol. 7, no. 6, pp. 398–407.

    Google Scholar 

  10. Gribovskiy, A.G., Makarshin, L.L., Andreev, D.V., Klenov, O.P., and Parmon, V.N., Chem. Eng. J., 2013, vol. 231, pp. 497–501. https://doi.org/10.1016/j.cej.2013.07.068

    Article  CAS  Google Scholar 

  11. Chen, W.-H. and Shen, Ch.-T., Energy, 2016, vol. 106, pp. 1–12. https://doi.org/10.1016/j.energy.2016.03.030

    Article  CAS  Google Scholar 

  12. Wan, A. and Yeh, C.T., Catal. Today, 2007, vol. 129, nos. 3–4, pp. 293–296. https://doi.org/10.1016/j.cattod.2006.12.009

  13. Chi, H., Andolina, C.M., Li, J., Curnan, M.T., Saidi, W.A., Zhou, G., Yang, J.C., and Veser, G., Appl. Catal., A, 2018, vol. 556, pp. 64–72. https://doi.org/10.1016/j.apcata.2018.02.028

  14. Cheng, W.-H., Acc. Chem. Res., 1999, vol. 32, no. 8, pp. 685–691. https://doi.org/10.1021/ar980088+

    Article  CAS  Google Scholar 

  15. Brown, J.C. and Gulari, E., Catal. Commun., 2004, vol. 5, no. 8. pp. 431–436. https://doi.org/10.1016/j.catcom.2004.05.008

    Article  CAS  Google Scholar 

  16. Iwasa, N. and Takezawa, N., Top. Catal., 2003, vol. 22, nos. 3–4, pp. 215–224. https://doi.org/10.1023/A:1023571819211

  17. Avgouropoulos, G., Papavasiliou, J., and Ioannides, T., Chem. Eng. J., 2009, vol. 154, nos. 1–3, pp. 274–280. https://doi.org/10.1016/j.cej.2009.03.019

  18. Badmaev, S.D., Akhmetov, N.O., Belyaev, V.D., Kulikov, A.V., Pechenkin, A.A., Potemkin, D.I., Konishcheva, M.V., Rogozhnikov, V.N., Snytnikov, P.V., and Sobyanin, V.A., Int. J. Hydrogen Energy, 2020, vol. 45, no. 49, pp. 26188–26196. https://doi.org/10.1016/j.ijhydene.2020.01.101

    Article  CAS  Google Scholar 

  19. Badmaev, S.D., Akhmetov, N.O., and Sobyanin, V.A., Int. J. Hydrogen Energy, 2021, vol. 46, no. 72, pp. 35877–35885. https://doi.org/10.1016/j.ijhydene.2021.01.229

    Article  CAS  Google Scholar 

  20. Arutyunov, V.S., Strekova, L.N., Savchenko, V.I., Sedov, I.V., Nikitin, A.V., Eliseev, O.L., Kryuchkov, M.V., and Lapidus, A.L., Pet. Chem., 2019, vol. 59, no. 4, pp. 370–379. https://doi.org/10.1134/S0965544119040029

    Article  CAS  Google Scholar 

  21. Gorlova, A.M, Karmadonova, I.E., Derevshchikov, V.S., Rogozhnikov, V.N., Snytnikov, P.V., and Potemkin, D.I., Catal. Ind., 2022, vol. 14, no. 4, pp. 349–356. https://doi.org/10.1134/S2070050422040031

    Article  Google Scholar 

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Funding

This work was supported by the Russian Science Foundation (project no. 17-79-30071).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    S. D. Badmaev, V. D. Belyaev, D. I. Potemkin, P. V. Snytnikov & V. A. Sobyanin

  2. Institute of Solid State Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    V. V. Kharton

Authors
  1. S. D. Badmaev
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  2. V. D. Belyaev
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  3. D. I. Potemkin
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  4. P. V. Snytnikov
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  5. V. A. Sobyanin
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  6. V. V. Kharton
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Correspondence to S. D. Badmaev.

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Badmaev, S.D., Belyaev, V.D., Potemkin, D.I. et al. Methanol Decomposition to Synthesis Gas over Supported Platinum-Containing Catalysts. Catal. Ind. 15, 367–373 (2023). https://doi.org/10.1134/S2070050423040037

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  • DOI: https://doi.org/10.1134/S2070050423040037

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