Skip to main content

Direct Synthesis of Al-B-SBA-15 and Its Application in Preparing of Bifunctional Platinum Catalyst for Hydrogenation of Tetralin

Abstract

In this work, the mesoporous material Al-B-SBA-15 has been obtained by direct synthesis method with Si : B : Al ratio of 10 : 0.5 : 0.5. Wetness impregnation (WI) method was used to load platinum on Al-B-SBA-15. The prepared support and catalyst were characterized by nitrogen adsorption–desorption measurement (BET), XRD, TEM, and TPD-NH3 to investigate the influence of boron and aluminium on characteristics of the catalyst. The activity of the bifunctional catalyst was tested for hydrogenation of tetralin at 180–220°C, hydrogen pressure of 1.5–2.5 MPa for 3 h.

This is a preview of subscription content, access via your institution.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

REFERENCES

  1. Cao, Z., Xu, X., Qi, Y., Lu, S., and Qi, B., Pet. Sci. Technol., 2004, vol. 22, no. 5–6, pp. 617–629.

  2. Valles, V.A., Ledesma, B.C., Rivoira, L.P., Cussa, J., Anunziata, O.A., and Beltramone, A.R., Catal. Today, 2016, vol. 271, pp. 140–148.

    Article  CAS  Google Scholar 

  3. Chan. J.-C. and Tan, C.-S., Energy Fuels, 2006, vol. 20, no. 2, pp. 771–777.

  4. Sato, K., Iwata, Y., Miki, Y., and Shimada, H., J. Catal., 1999, vol. 186, no. 1, pp. 45–56.

    Article  CAS  Google Scholar 

  5. Lee, J., Choi, Y., Shin, J., and Lee, J.K., Catal. Today, 2016, vol. 265, pp. 144–153.

    Article  CAS  Google Scholar 

  6. Calemma, V., Giardino, R., and Ferrari, M., Fuel Process. Technol., 2010, vol. 91, no. 7, pp. 770–776.

    Article  CAS  Google Scholar 

  7. Vallés, V.A., Ledesma, B.C., Pecchi, G.A., Anunziata, O.A., and Beltramone, A.R., Catal. Today, 2017, vol. 282, part 2, pp. 111–122.

    Article  CAS  Google Scholar 

  8. Williams, M.F., Fonfé, B., Woltz, C., Jentys, A., van Veen, J.A.R., and Lercher, J.A., J. Catal., 2007, vol. 251, no. 2, pp. 497–506.

    Article  CAS  Google Scholar 

  9. Dokjampa, S., Rirksomboon, T., Osuwan, S., Jongpatiwut, S., and Resasco, D.E., Catal. Today, 2007, vol. 123, nos. 1–4, pp. 218–223.

  10. Zhao, D., Huo, Q., Feng, J., Chmelka, B.F., and Stucky, G.D., J. Am. Chem. Soc., 1998, vol. 120, no. 24, pp. 6024–6036.

    Article  CAS  Google Scholar 

  11. Zhao, D., Feng, J., Huo, Q., Melosh, N., Fredrickson, G.H., Chmelka, B.F., and Stucky, G.D., Science, 1998, vol. 279, no. 5350, pp. 548–552.

    Article  CAS  Google Scholar 

  12. Gallo, J.M.R., Bisio, C., Gatti, G., Marchese, L., and Pastore, H.O., Langmuir, 2010, vol. 26, no. 8, pp. 5791–5800.

    Article  CAS  PubMed  Google Scholar 

  13. Vallés, V.A., Bottazzi, G.S.B., Martínez, M.L., Costa, M.B.G., Anunziata, O.A., and Beltramone, A.R., Ind. Eng. Chem. Res., 2012, vol. 51, no. 21, pp. 7185–7195.

    Article  CAS  Google Scholar 

  14. Eswaramoorthi, I. and Dalai, A.K., Microporous Mesoporous Mater., 2006, vol. 93, nos. 1–3, pp. 1–11.

  15. Van Grieken, R., Escola, J.M., Moreno, J., and Rodríguez, R., Chem. Eng. J., 2009, vol. 155, nos. 1–2, pp. 442–450.

  16. Huyen, P.T., Krivec, M., Kočevar, M., Bucur, I.C., Rizescu, C., and Parvulescu, V.I., ChemCatChem, 2016, vol. 8, no. 6, pp. 1146–1156.

    Article  CAS  Google Scholar 

  17. Huyen, P.T., Nam Le, T.H., Vinh, T.Q., Martínez, C., and Parvulescu, V.I., Catal. Today, 2018, vol. 306, pp. 121–127.

    Article  CAS  Google Scholar 

  18. Yu, W., Tang, Y., Mo, L., Chen, P., Lou, H., and Zheng, X., Catal. Commun., 2011, vol. 13, no. 1, pp. 35–39.

    Article  CAS  Google Scholar 

  19. Yaripour, F., Shariatinia, Z., Sahebdelfar, S., and Irandoukht, A., Microporous Mesoporous Mater., 2015, vol. 203, pp. 41–53.

    Article  CAS  Google Scholar 

  20. Ferraz, S.G.A., Zotin, F.M.Z., Araujo, L.R.R., and Zotin, J.L., Appl. Catal., A, 2010, vol. 384, nos. 1–2, pp. 51–57.

  21. Jongpatiwut, S., Li, Z., Resasco, D.E., Alvarez, W.E., Sughrue, E.L., and Dodwell, G.W., Appl. Catal., A, 2004, vol. 262, no. 2, pp. 241–253.

Download references

ACKNOWLEDGMENTS

This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under grant no. 104.05-2014.21.

Funding

The article is published in the original.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Pham Thanh Huyen.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Ngo Thi Thanh Hien, Kien, P.T., Vu, N.A. et al. Direct Synthesis of Al-B-SBA-15 and Its Application in Preparing of Bifunctional Platinum Catalyst for Hydrogenation of Tetralin. Catal. Ind. 11, 59–64 (2019). https://doi.org/10.1134/S2070050419010069

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070050419010069

Keywords:

  • mesoporous materials
  • Al-B-SBA-15
  • boron
  • aluminium
  • bifunctional platinum catalyst
  • tetralin hydrogenation