Abstract
The effect of the ruthenium promotion of Fischer–Tropsch (FT) cobalt–alumina catalysts on the temperature of catalyst activation reduction and catalytic properties in the FT process is studied. The addition of 0.2–1 wt % of ruthenium reduces the temperature of reduction activation from 500 to 330–350°C while preserving the catalytic activity and selectivity toward C5+ products in FT synthesis. FT ruthenium-promoted Co–Al catalysts are more selective toward higher hydrocarbons; the experimental value of parameter αASF of the distribution of paraffinic products for ruthenium-promoted catalysts is 0.93–0.94, allowing us to estimate the selectivity toward C20+ synthetic waxes to be 48 wt %, and the selectivity toward C35+ waxes to be 23 wt %. Ruthenium-promoted catalysts also exhibit high selectivity toward olefins.
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Lisitsyn, A.S., Golovin, A.V., Kuznetsov, V.L., and Yermakov, Yu.I., C1 Mol. Chem., 1984, no. 1, pp. 115–135.
Khassin, A.A., Yur’eva, T.M., and Parmon, V.N., Dokl. Phys. Chem., 1999, vol. 367, nos. 1–3, pp. 213–216.
Satterfield, C.N., Huff, G.A., Stenger, H.G., Carter, J.L., and Madon, R.J., Ind. Eng. Chem. Fundam., 1985, vol. 24, no. 3, pp. 450–454.
Tavasoli, A., Pour, A.N., and Ahangari, M.G., J. Nat. Gas Chem., 2010, vol. 19, no. 6, pp. 653–659.
Savost’yanov, A.P., Narochnyi, G.B., Yakovenko, R.E., Bakun, V.G., and Zemlyakov, N.D., Catal. Ind., 2014, vol. 6, no. 4, pp. 292–297.
Ermolaev, I.S., Ermolaev, V.S., and Mordkovich, V.Z., Theor. Found. Chem. Eng., 2013, vol. 47, no. 2, pp. 153–158.
Sineva, L.V., Mordkovich, V.Z., Ermolaev, V.S., Ermolaev, I.S., Mitberg, E.B., and Solomonik, I.G., Katal. Prom-sti, 2012, no. 6, pp. 13–22.
Lamprecht, D., Nel, R., and Leckel, D., Energy Fuels, 2010, vol. 24, no. 3, pp. 1479–1486.
Simentsova, I.I., Khassin, A.A., Minyukova, T.P., Davydova, L.P., Shmakov, A.N., Bulavchenko, O.A., Cherepanova, S.V., Kustova, G.N., and Yurieva, T.M. Kinet. Catal., 2012, vol. 53, no. 4, pp. 497–503.
Khassin, A.A., Simentsova, I.I., Shmakov, A.N., Shtertser, N.V., Bulavchenko, O.A., and Cherepanova, S.V., Appl. Catal., A, 2016, vol. 514, pp. 114–125.
RF Patent 2538088, Byull. Izobret., 2015, no. 1.
Simentsova, I.I., Khasin, A.A., Shtertser, N.V., Davydova, L.P., Minyukova, T.P., and Yur’eva, T.M., Katal. Prom-sti, 2016, no. 2, pp. 17–22.
Khassin, A.A., Anufrienko, V.F., Ikorskii, V.N., Plyasova, L.M., Kustova, G.N., Larina, T.V., Molina, I.Yu., and Parmon, V.N., Phys. Chem. Chem. Phys., 2002, vol. 4, no. 17, pp. 4236–4243.
Tsubaki, N., Sun, S., and Fujimoto, K., J. Catal., 2001, vol. 199, no. 2, pp. 236–246.
Ma, W., Jacobs, G., Keogh, R.A., Bukur, D.B., and Davis, B.H., Appl. Catal., A, 2012, vols. 437–438, pp. 1–9.
Jacobs, G., Das, T.K., Zhang, Y., Li, J., Racoillet, G., and Davis, B.H., Appl. Catal., A, 2002, vol. 233, nos. 1–2, pp. 263–281.
Song, S.-H., Lee, S.-B., Bae, J.W., Sai Prasad, P.S., and Jun, K.-W., Catal. Commun., 2008, vol. 9, no. 13, pp. 2282–2286.
Kogelbauer, A., Goodwin, J.G., and Oukaci, R., J. Catal., 1996, vol. 160, no. 1, pp. 125–133.
Park, J.-Y., Lee, Y.-J., Karandikar, P.R., Jun, K.-W., Bae, J.W., and Ha, K.-S., J. Mol. Catal. A: Chem., 2011, vol. 344, nos. 1–2, pp. 153–160.
Parnian, M.J., Najafabadi, A.T., Mortazavi, Y., Khodadadi, A.A., and Nazzari, I., Appl. Surf. Sci., 2014, vol. 313, pp. 183–195.
Cook, K.M., Poudyal, S., Miller, J., Bartholomew, C.H., and Hecker, W.C., Appl. Catal., A, 2012, vol. 449, pp. 69–80.
Hermans, L.A.M. and Geus, J.W., Stud. Surf. Sci. Catal., 1979, vol. 3, pp. 113–130.
Bezemer, G.L., Radstake, P.B., Koot, V., van Dillen, A.J., Geus, J.W., and De Jong, K.P., J. Catal., 2006, vol. 237, no. 2, pp. 291–302.
Eschemann, T.O., Bitter, J.H., and De Jong, K.P., Catal. Today, 2014, vol. 228, pp. 89–95.
Emel'yanov, V.A., Formation and conversion of ruthenium nitrozo complexes in chloride, nitrite, nitrate, and ammonia solutions, Doctoral (Chem.) Dissertation, Novosibirsk Nikolaev Inst. Inorg. Chem., 2013.
Iglesia, E., Reyes, S.C., and Madon, R.J., J. Catal., 1991, vol. 129, no. 1, pp. 238–256.
Iglesia, E., Appl. Catal., A, 1997, vol. 161, nos. 1–2, pp. 59–78.
Zhan, X.D. and Davis, B.H., Pet. Sci. Technol., 2000, vol. 18, nos. 9–10, pp. 1037–1053.
Derevich, I.V., Ermolaev, V.S., Zol’nikova, N.V., and Mordkovich, V.Z., Theor. Found. Chem. Eng., 2013, vol. 47, no. 3, pp. 191–200.
Chickos, J.S. and Hanshaw, W., J. Chem. Eng. Data, 2004, vol. 49, no. 1, pp. 77–85.
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Original Russian Text © O.A. Kungurova, N.V. Shtertser, G.K. Chermashentseva, I.I. Simentsova, A.A. Khassin, 2016, published in Kataliz v Promyshlennosti.
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Kungurova, O.A., Shtertser, N.V., Chermashentseva, G.K. et al. Ruthenium promoted cobalt–alumina catalysts for the synthesis of high-molecular-weight solid hydrocarbons from CO and hydrogen. Catal. Ind. 9, 23–30 (2017). https://doi.org/10.1134/S2070050417010081
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DOI: https://doi.org/10.1134/S2070050417010081