Abstract
Kinetic characteristics of reactions occurring in the alkylation of phenol with straight-chain alkenes (C9, C16) over the Amberlyst 15 Dry, Amberlyst 35 Dry, Amberlyst 36 Dry, Amberlyst 70, Amberlyst DT, Tulsion 66 MP, Lewatit K2640, Lewatit K 2431, and Relite EXC8D sulfonic acid cation-exchange resins have been determined experimentally. The activities of these catalysts in different types of reactions have been compared. The rate constants of all reactions decrease on passing from 1-nonene to straight-chain hexadecene. In the alkylations of phenol with straight-chain alkenes, the ortho-alkylphenol/para-alkylphenol ratio is practically equal to the statistical ratio for all of the resins examined in their operation range.
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Original Russian Text © T.N. Nesterova, D.A. Chernyshov, V.A. Shakun, N.Yu. Krymkin, A.V. Tarasov, I.O. Voronin, N.V. Bilenchenko, 2015, published in Kataliz v Promyshlennosti.
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Nesterova, T.N., Chernyshov, D.A., Shakun, V.A. et al. Sulfonic acid cation-exchange resins in the synthesis of straight-chain alkylphenols. Catal. Ind. 8, 16–22 (2016). https://doi.org/10.1134/S2070050416010086
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DOI: https://doi.org/10.1134/S2070050416010086