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Polymerization of propylene in liquid monomer using state-of-the-art high-performance titanium-magnesium catalysts

Abstract

A comparative study of propylene polymerization in liquid monomer is performed under laboratory conditions using the IK-8-21 Ti-Mg catalyst designed at the Boreskov Institute of Catalysis and imported industrial catalysts (conditionally labeled TMC-1, -2, and -3). The activity and stereospecificity of the catalysts are estimated along with properties of the resulting polypropylene (granular composition and physicomechanical characteristics). It is shown that the IK-8-21 catalyst is not inferior to imported counterparts in terms of catalytic properties in the synthesis of polypropylene. The polypropylene powder formed on IK-8-21 is homogeneous and has good morphology. The physicomechanical characteristics of polypropylene synthesized on the domestic IK-8-21 catalyst are similar to those for polypropylene prepared with the imported TMK-1 catalyst.

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Correspondence to I. I. Salakhov.

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Original Russian Text © I.I. Salakhov, A.Z. Batyrshin, S.A. Sergeev, G.D. Bukatov, A.A. Barabanov, A.G. Sakhabutdinov, V.A. Zakharov, Kh.Kh. Gilmanov, 2014, published in Kataliz v Promyshlennosti.

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Salakhov, I.I., Batyrshin, A.Z., Sergeev, S.A. et al. Polymerization of propylene in liquid monomer using state-of-the-art high-performance titanium-magnesium catalysts. Catal. Ind. 6, 198–201 (2014). https://doi.org/10.1134/S2070050414030106

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  • DOI: https://doi.org/10.1134/S2070050414030106

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