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A Study of Elastomeric Fire- and Heat-Resistant Materials Containing Functionally Active Structures

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Abstract

In this paper, we consider the effect of the introduction of functionally active structures of the supramolecular type on the physical and mechanical, thermophysical and heat-resistant characteristics of elastomeric compositions based on ethylene–propylene–diene rubber. The presence of aluminosilicate microspheres, carbon microfiber, and organophosphorus oligomer in the composition of these structures contributes to the manifestation of a synergistic effect, which consists in increasing the heat-shielding properties of the material due to increasing the strength of the coke and enhancing the processes of carbonization of the material. This leads to an increase in the heating time of the unheated sample surface by 8–17% and a decrease in the rate of linear combustion by 6–17% as compared with known analogues. Microspheres allow compensating the negative effect of microfiber on the density and thermal conductivity of the composition.

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REFERENCES

  1. G. E. Zaikov, E. V. Kalugina, and K. Z. Gumargalieva, “Fundamental regularities of thermal oxidation of heat-resistant heterochain polymers,” in Thermal Stability of Engineering Heterochain Thermoresistant Polymers (CRC Press, Boca Ration, Fl, 2004).

  2. Yu. A. Mikhailin, “Special Polymer Composite Materials (Nauchnye Osnovy i Tekhnologii, St. Petersburg, 2008) [in Russian].

    Google Scholar 

  3. Yu. A. Grigor’ev, Yu. M. Evtushenko, and T. A. Rudakova, “Modern compositions for intumescent fire retardant coatings,” Klei, Germetiki, Tekhnol., No. 3, 38–42 (2018).

  4. V. F. Kablov, O. M. Novopol’tseva, N. A. Keibal, V. G. Kochetkov, and V. V. Pudovkin, “Elastomeric compositions containing microspheres modified with an organoelement modifier,” Klei, Germetiki, Tekhnol., No. 12, 16–19 (2017).

  5. J. Markowski, “Cenospheres. An universal construction material,” Przem. Chem. 98 (6), 940–943 (2019). https://doi.org/10.15199/62.2019.6.16

    Article  CAS  Google Scholar 

  6. O. V. Bezzaponnaya and E. V. Golovina, “Effect of mineral fillers on the heat resistance and combustibility of an intumescent fireproofing formulation on silicone base,” Russ. J. Appl. Chem. 91 (1), 96–100 (2018). https://doi.org/10.1134/S1070427218010159

    Article  CAS  Google Scholar 

  7. V. F. Kablov, N. A. Keibal, V. G. Kochetkov, A. O. Motchenko, and Yu. M. Antonov, “Research of the influence of carbon microfiber on the properties of elastomer fire-protective materials,” Russ. J. Appl. Chem. 91, 1160–1164 (2018).

    Article  CAS  Google Scholar 

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Funding

This work was supported by a grant of the President of the Russian Federation for State Support of Young Russian Scientists–Candidates of Science, no. MK-1802.2020.3.

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Correspondence to V. G. Kochetkov.

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Translated by A. Ivanov

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Kablov, V.F., Keibal, N.A., Novopol’tseva, O.M. et al. A Study of Elastomeric Fire- and Heat-Resistant Materials Containing Functionally Active Structures. Polym. Sci. Ser. D 14, 499–503 (2021). https://doi.org/10.1134/S1995421221040067

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  • DOI: https://doi.org/10.1134/S1995421221040067

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