Skip to main content
Log in

A Study of the Relaxation Processes in an Adhesive Composition Based on Unsaturated Polyketone

  • Published:
Polymer Science, Series D Aims and scope Submit manuscript

Abstract

The temperature–frequency dependence of the complex elastic modulus of an adhesive composition based on unsaturated polyketone was studied by dynamic mechanical analysis. It was shown that, in the temperature range of –100 to +60°C, two relaxation processes occur, which are related to the presence of two polymer networks in an adhesive composition. The regularities of the effect of γ radiation on the temperature dependence of the complex elastic modulus of an adhesive composition were established.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. O. I. Sidorov, O. S. Kukina, D. A. Belyakov, K. A. Dubkov, S. V. Semikolenov, V. N. Parmon, and D. V. Pleshkov, “Fastening composition based on unsaturated polyketone, a new type of reactive oligomers,” Klei, Germetiki, Tekhnol., No. 10, 2–9 (2017).

  2. G. M. Bartenev and S. Ya. Frenkel’, Polymer Physics, Ed. by A. M. El’yashevich (Khimiya, Leningrad, 1990) [in Russian].

    Google Scholar 

  3. ASTM E1640-13: Standard Test Method for Assignment of the Glass Transition Temperature by Dynamic Mechanical Analysis (2013).

  4. K. P. Menard, Dynamic Mechanical Analysis: A Practical Introduction, 2nd ed. (CRC Press, Boca Raton–London–New York–Washington, D.C., 2008).

  5. Thermal Analysis of Polymers: Fundamentals and Applications, Ed. by D. Joseph, R. Menczel, and R. Bruce Prime (John Wiley & Sons, Inc., Hoboken, NJ, 2014).

    Google Scholar 

  6. Yu. M. Milekhin, D. N. Sadovnichii, E. V. Bogdanova, and S. A. Malinin, “Relaxation processes in ballistic solid rocket fuel,” in Proc. Ninth All-Russian Conference Intra-Chamber Processes and Combustion in Solid Fuel Systems and Barrel Systems (ICOC’2017), Moscow, October 10–12, 2017 (Izhevsk, 2017), pp. 180–187.

  7. GOST (State Standard) 34155–2017: Guidelines for Dosimetry when Using the Effects of Radiation on Food and Agricultural Products (ISO/ASTM 51900:2009, NEQ) (2017).

  8. O. I. Sidorov, K. A. Dubkov, S. V. Semikolenov, N. E. Evseev, D. A. Belyakov, O. S. Fursova, V. N. Parmon, and D. V. Pleshakov, “A study of the properties of unsaturated polyketone as a representative of new-type reactive oligomers for the development of an adhesive composition on its basis,” Polym. Sci., Ser. D 11 (2), 215–224 (2018).

  9. A. P. Meleshevich, Radiation Chemistry of Epoxy Compounds (Nauk. dumka, Kiev, 1989) [in Russian].

Download references

ACKNOWLEDGMENTS

The fabrication of a UPK sample was supported by the Russian Foundation for Basic Research, project no. 17-03-00706.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yu. M. Milekhin.

Additional information

Translated by E. Petrova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Milekhin, Y.M., Sadovnichii, D.N., Sidorov, O.I. et al. A Study of the Relaxation Processes in an Adhesive Composition Based on Unsaturated Polyketone. Polym. Sci. Ser. D 12, 116–120 (2019). https://doi.org/10.1134/S199542121902014X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S199542121902014X

Keywords:

Navigation