Skip to main content
Log in

Characteristics of Hybrid Mixtures of Boron Polyoxide and Copolymer of Ethylene with Vinyl Acetate

  • Published:
Polymer Science, Series D Aims and scope Submit manuscript

Abstract

Using the extrusion method, composites based on the melts of boron polyoxide oligomer and block-copolymers of ethylene and vinyl acetate with various structures have been prepared. Visible-light-transparent specimens of the mixtures have been prepared. Measurements of thermomechanical and mechanical properties of the composites have shown the compatibility of the polymers. An increase in the flow rate of the melts of the mixtures in the extruder channel when using boron polyoxide oligomer as a second component of the mixtures has been determined. The hydrolytic stability of the composites under atmospheric conditions has been measured.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.

Similar content being viewed by others

REFERENCES

  1. A. Yu. Shaulov and A. A. Berlin, “Inorganic plyoxide thermoplastics: Their hybrids and blends,” in Additives in Polymers. Analysis and Applications, Ed. by A. A. Berlin, S. Z. Rogovina, and G. E. Zaikov (2015).

    Google Scholar 

  2. V. M. Lalayan, E. V. Stegno, A. V. Nikitin, A. A. Samoi-lenko, A. V. Grachev, I. I. Khazanov, A. Yu. Shaulov, V. M. Kopylov, and A. A. Berlin, “A hybrid resin based on organoelement and inorganic oligomers,” Polym. Sci., Ser. B 57 (1), 23–26 (2015).

    Article  CAS  Google Scholar 

  3. V. M. Lalayan, E. V. Stegno, A. V. Grachev, L. N. Ignat’eva, V. K. Goncharuk, A. Yu. Shaulov, Al. Al. Berlin, and V. M. Buznik, “Composite materials based on fluoropolymers and oxyfluoride glasses,” Dokl. Chem. 468 (2), 187–190 (2016).

    Article  CAS  Google Scholar 

  4. A. Yu. Shaulov, I. I. Aliev, A. Yu. Lyumpanova, T. S. Zarkhina, I. I. Barashkova, A. M. Vasserman, and Al. Al. Berlin, “On the structure of composites based on mixtures of boron polyoxides with polyethylene,” Dokl. Phys. Chem. 413 (1), 63–65 (2007).

    Article  CAS  Google Scholar 

  5. A. E. Chalykh, V. K. Gerasimov, A. D. Aliev, A. Yu. Lyumpanova, A. Yu. Shaulov, and Al. Al. Berlin, “Solubility, diffusion, and phase structure of hybrid polyolefin-boric acid composites,” Dokl. Chem. 423 (1), 286–289 (2008).

    Article  CAS  Google Scholar 

  6. E. V. Stegno, V. M. Lalayan, A. V. Grachev, L. V. Vladimirov, N. G. Berezkina, A. Yu. Shaulov, S. A. Patlazhan, and A. A. Berlin, “Orientation effects in hybrid-polymer mixtures,” Polym. Sci., Ser. D 11 (2), 209–214 (2018).

    CAS  Google Scholar 

  7. B. Rimez, H. Rahier, G. Van Assche, T. Artoos, M. Biesemans, and B. Van Mele, “The thermal degradation of poly(vinyl acetate) and poly(ethylene-covinyl acetate), Part I: Experimental study of degradation mechanism,” Polym. Degrad. Stab. 93, 800–810 (2008).

    Article  CAS  Google Scholar 

  8. B. Rimez, H. Rahier, G. Van Assche, T. Artoos, and B. Van Mele, “The thermal degradation of poly(vinyl acetate) and poly(ethylene-co-vinyl acetate), Part II: Modelling the degradation kinetics,” Polym. Degrad. Stab. 93, 1222–1230 (2008).

    Article  CAS  Google Scholar 

  9. B. B. Troitskii, G. A. Razuvaev, L. V. Khokhlova, and G. N. Bortnikov, “On the mechanism of the thermal degradation of polyvinyl acetate,” J. Polym. Sci.: Symp., No. 42, 1363–1375 (1973).

  10. J. L. Parsons, “Vibrational spectra of orthorhombic metaboric acid,” J. Chem. Phys. 33 (4), 1860–1866 (1960).

    Article  CAS  Google Scholar 

  11. P. L. Hanst and V. H. Early, “Infrared spectrum and molecular structure of B2O3,” J. Chem. Phys. 42, 1097 (1965).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. V. Stegno.

Additional information

Translated by A. Muravev

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Stegno, E.V., Lalayan, V.M., Grachev, A.V. et al. Characteristics of Hybrid Mixtures of Boron Polyoxide and Copolymer of Ethylene with Vinyl Acetate. Polym. Sci. Ser. D 11, 426–430 (2018). https://doi.org/10.1134/S1995421218040238

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1995421218040238

Keywords:

Navigation