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A Study of the Properties of Unsaturated Polyketone as a Representative of New-Type Reactive Oligomers for the Development of an Adhesive Composition on Its Basis

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Abstract

The properties of unsaturated polyketone, which is a representative of new-type reactive oligomers, were studied. It was shown that unsaturated polyketone is compatible with a polar plasticizer (dibutyl phthalate), to some extent compatible with a nonpolar plasticizer (transformer oil), and can be cured by dinitrile oxide and EKh-1 quinol ester. An adhesive composition based on unsaturated polyketone cured by quinol ester and epoxy-containing components was developed. It was established that the adhesive composition based on unsaturated polyketone limitedly swells in transformer oil and has two glass-transition temperatures. The adhesive composition based on unsaturated polyketone provides bonding of a high-filled polymer composition with a rigid multilayered substrate.

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Authors and Affiliations

  1. Soyuz Federal Center for Dual-Use Technologies, Dzerzhinskyi, Moscow oblast, 140090, Russia

    O. I. Sidorov, N. E. Evseev, D. A. Belyakov & O. S. Fursova

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    K. A. Dubkov, S. V. Semikolenov & V. N. Parmon

  3. Mendeleev University of Chemical Technology of Russia, Moscow, 125047, Russia

    D. V. Pleshakov

Authors
  1. O. I. Sidorov
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  2. K. A. Dubkov
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  3. S. V. Semikolenov
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  4. N. E. Evseev
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  5. D. A. Belyakov
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  6. O. S. Fursova
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  7. V. N. Parmon
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  8. D. V. Pleshakov
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Correspondence to O. I. Sidorov.

Additional information

Original Russian Text © O.I. Sidorov, K.A. Dubkov, S.V. Semikolenov, N.E. Evseev, D.A. Belyakov, O.S. Fursova, V.N. Parmon, D.V. Pleshakov, 2018, published in Vse Materialy, 2018, No. 1, pp. 14–23.

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Sidorov, O.I., Dubkov, K.A., Semikolenov, S.V. et al. A Study of the Properties of Unsaturated Polyketone as a Representative of New-Type Reactive Oligomers for the Development of an Adhesive Composition on Its Basis. Polym. Sci. Ser. D 11, 215–224 (2018). https://doi.org/10.1134/S199542121802017X

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  • DOI: https://doi.org/10.1134/S199542121802017X

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