Abstract
The adhesive properties of styrene–isoprene–styrene (SIS) three-block copolymer of different brands modified with isoprene oligomer and Regalite R9100 depending on the adhesive composition and the adhesion-contact-formation temperature were studied. It was shown that oligoisoprene acts as a diluent, while Regalite R9100 modifies the system as a whole by decreasing the glass-transition temperature of the microphase of polystyrene blocks and contributes to the increase in the adhesive ability of the composition.
Similar content being viewed by others
References
A. P. Petrova, A. A. Donskoi, A. E. Chalykh, and A. A. Shcherbina, Adhesives. Sealants: Handbook (Professional, St. Petersburg, 2008) [in Russian].
A. E. Chalykh, A. V. Shapagin, P. Singh, and A. A. Shcherbina, “Factors governing long-term wear of skin-contact adhesives,” in Application of Pressure-Sensitive Products: Handbook of Pressure-Sensitive Adhesives and Products, Ed. by I. Benedek and M. M. Feldstein (CRC Press, Boca Raton, 2009), pp. 6-1–6-24.
M. M. Feldstein, “Molecular nature of pressure-sensitive adhesion,” in Fundamentals of Pressure Sensitivity: Handbook of Pressure-Sensitive Adhesives and Products, Ed. by I. Benedek and M. M. Feldstein (CRC Press, Boca Raton, 2009), pp. 10-1–10-43.
Advances in Pressure Sensitive Adhesive Technology, 3rd ed., Ed. by D. S. Warwick (Satas & Associates, Warwick, RI, 1999).
Technology of Pressure-Sensitive Adhesives and Products: Handbook of Pressure-Sensitive Adhesives and Products, Ed. by I. Benedek and M. M. Feldstein (CRC Press, Boca Raton, 2009).
Developments in Pressure-Sensitive Products, Ed. by I. Benedek (CRC Press, Boca Raton, 2005).
Food and Drug Administration. http://www.fda.gov.
G. V. Motovilin, Gluing: Parallel Dictionary-Handbook (Nauka, St. Petersburg, 2000) [in Russian].
Y. Nakamura, Y. Sakai, K. Imamura, et al., “Effects of the compatibility of a polyacrylic block copolymer/tackifier blend on the phase structure and tack of a pressure-sensitive adhesive,” J. Appl. Polym. Sci. 123 (5), 2883–2893 (2012).
A. A. Shcherbina, “Topology of concentration-gradient transition zones in polymer adhesive compounds,” Polym. Sci., Ser. D 9, 72–82 (2016).
K. Brown, J. C. Hooker, and C. Creton, “Micromechanisms of tack of soft adhesives based on styrenic block copolymers,” Macromol. Mater. Eng. 287 (3), 163–179 (2002).
M. Sasaki, K. Fujita, M. Adachi, et al., “The effect of tackifier on phase structure and peel adhesion of a triblock copolymer pressure-sensitive adhesive,” Int. J. Adhes. Adhes. 28 (7), 372–381 (2008).
A. Ya. Malkin and A. E. Chalykh, Diffusion and Viscosity of Polymers: Measurement Techniques (Khimiya, Moscow, 1979) [in Russian].
A. E. Chalykh, U. V. Nikulova, and A. A. Shcherbina, “Phase equilibria in a polystyrene-poly(butyl acrylate) system,” Polym. Sci., Ser. A 57, 445–451 (2015).
D. K. Owens and R. C. Wendt, “Estimation of the surface free energy of polymers,” J. Appl. Polym. Sci. 13 (8), 1741–1747 (1969).
A. Kinloch, Adhesion and Adhesives: Science and Technology (Springer-Verlag, Dordrecht, 1987; Mir, Moscow, 1991).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Scherbina, A.E. Chalykh, 2017, published in Klei, Germetiki, Tekhnologii, 2017, No. 11, pp. 2–9.
Rights and permissions
About this article
Cite this article
Scherbina, A.A., Chalykh, A.E. Adhesive Compositions Based on Styrene–Isoprene–Styrene Three-Block Copolymer with Different Modifiers. Polym. Sci. Ser. D 11, 140–146 (2018). https://doi.org/10.1134/S1995421218020168
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1995421218020168