Skip to main content
Log in

An Epoxy-Siloxane Composite with Enhanced Deformation Heat Resistance and Improved Deformation and Strength Characteristics

  • Published:
Polymer Science, Series D Aims and scope Submit manuscript

Abstract

The curing of an epoxy-triphenol resin (ETP) using an amine curing agent in the presence of a polyorganosyloxane modifier is studied. It is shown that mixing of ETP with a modifier favors the formation of a completely compatible system, which, however, undergoes phase separation upon the curing. It has been established that curing of the epoxy-siloxane composite results in a denser mesh-structure buildup, while the cured samples exhibit higher deformation and strength characteristics and deformation heat resistance.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. N. Rusanova, S. Yu. Sof’ina, and O. V. Stoyanov, “Influence of organosilicon modifiers on structural characteristics and operational properties of polymers,” Vestn. Kazan. Tekhnol. Univ., No. 5, 85–89 (2008).

    Google Scholar 

  2. J. J. Chruściel and E. Leśniak, “Modification of epoxy resins with functional silanes, polysiloxanes, silsesquioxanes, silica and silicates,” Progr. Polym. Sci. 41, 67–121 (2015).

    Article  Google Scholar 

  3. F. Piscitelli, M. Lavorgna, and G. G. Buonocore, “Peculiarities in the structure—properties relationship of epoxy-silica hybrids with highly organic siloxane domains,” Polymer 63, 222–229 (2015).

    Article  CAS  Google Scholar 

  4. S. Najafi-Shoa, H. Roghani-Mamaqani, M. Salami-Kalajahi, et al., “Incorporation of epoxy resin and carbon nanotube into silica/siloxane network for improving thermal properties,” J. Mater. Sci. 51 (19), 9057–9073 (2016). doi 10.1007/s10853-016-0158-3

    Article  CAS  Google Scholar 

  5. WO 2005078012A2 Switzerland, “Fire retardant compositions using siloxanes” (2005).

    Google Scholar 

  6. RF Patent No. 2209218, “The heat-resistant epoxy-silicone matrix for creating layered composite materials based on glass, carbon, boron and organic fibers” (2003).

    Google Scholar 

  7. N. G. Leonova, V. M. Mikhal’chuk, and E. P. Mamunya, “Thermophysical properties of epoxy-polysiloxane composites of cationic polymerization,” Entsikl. Inzh.-Khim., No. 12, 38–45 (2012).

    Google Scholar 

  8. I. Díaz, B. Chico, and D. de la Fuente, “Corrosion resistance of new epoxy–siloxane hybrid coatings. A laboratory study,” Progr. Org. Coat., No. 69, 278–286 (2010).

    Article  Google Scholar 

  9. T. A. Akopova, Yu. V. Olikhova, and V. S. Osipchik, “A thermoanalytical study of curing of epoxy-amine binders modified with epoxy-containing silsesquioxane,” Polym. Sci., Ser. D 8 (2), pp. 133–137 (2015).

    Article  CAS  Google Scholar 

  10. L. Kh. Nguen, Yu. V. Olikhova, and A. I. Kochetkov, “Features of epoxy phenol resin curing by aromatic amines,” Usp. Khim. Khim. Tekhnol. 29 (10), 35–37 (2015).

    Google Scholar 

  11. S. A. Vshivkov, S. N. Paznikova, E. V. Rusinova, and S. A. Evtyukhov, “Study of phase equilibrium by refractometry and determination of the second virial coefficients of the polymer–fire retardant system,” Pozharovzryvobezopasnost’ 16 (4), 34–36 (2007).

    Google Scholar 

  12. I. V. Chudnov, “Investigation of the properties of polymer binders by thermoanalytical methods,” Entsikl. Inzh.-Khim., No. 4, 30–35 (2013).

    Google Scholar 

  13. A. A. Gavrilov, P. I. Kos, and A. V. Chertovich, “Modeling of phase behavior and mechanical properties of ideal interpenetrating networks,” Vysokomol. Soedin., Ser. A 58 (6), 595–603 (2016).

    Google Scholar 

  14. Yu. S. Lipatov, T. T. Alekseeva, V. F. Rosovitskii, and N. V. Babkina, “Influence of the kinetics of the formation of interpenetrating polymer networks on their microphase separation,” Vysokomol. Soedin. 35 (6), 652–657 (1993).

    CAS  Google Scholar 

  15. US Patent 4250074A, Interpenetrating polymer network comprising epoxy polymer and polysiloxane (1981).

    Google Scholar 

  16. R. G. Jones, W. Ando, and Ju. Chojnowski, Silicon-Containing Polymers: The Science and Technology of Their Synthesis and Applications (Springer Science & Business Media, 2013).

    Google Scholar 

  17. D. F. Bergstrom, G. T. Burns, and G. T. Decker, “Insitu phase separation of an amine-terminated siloxane in epoxy matrices,” MRS Online Proc. Libr. doi 10.1557/proc-274-31

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yu. V. Olikhova.

Additional information

Original Russian Text © Yu.V. Olikhova, Nguen Le Khoang, N.V. Kostromina, V.M. Aristov, V.S. Osipchik, 2017, published in Klei, Germetiki, Tekhnologii, 2017, No. 7, pp. 7–11.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Olikhova, Y.V., Le Khoang, N., Kostromina, N.V. et al. An Epoxy-Siloxane Composite with Enhanced Deformation Heat Resistance and Improved Deformation and Strength Characteristics. Polym. Sci. Ser. D 11, 6–10 (2018). https://doi.org/10.1134/S199542121801015X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S199542121801015X

Keywords

Navigation