Abstract
Temperature dependences of the dynamic shearing modulus of oak timber Quercus robur subjected to hydrolysis were obtained by dynamic mechanical analysis. A decrease of the timber dynamic shearing modulus and considerable reduction of the glass-transition temperature of its amorphous components complex with an increase of the hydrolysis hardness level were revealed. Suppositions about the nature of the found effects were made.
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J. K. Kurian, G. R. Nair, A. Hussain, and V. Raghavan, “Feedstocks, logistics and pre-treatment processes for sustainable lignocellulosic biorefineries: A comprehensive review renewable and sustainable,” En. Rev., No. 25, 205 (2013).
A. T. Teleshev, M. P. Koroteev, G. Z. Kaziev, E. E. Nifantiev, O. P. Kronova, and G. V. Malysheva, “A new technology of wood cavitation,” Polym. Sci., Ser. D 5 (3), 219–220 (2012).
C. Asada, C. Sasaki, Y. Uto, J. Sakafuji, and Y. Nakamura, “Effect of steam explosion pretreatment with ultra-high temperature and pressure on effective utilization of softwood biomass,” Biochem. Eng. J., No. 60, 25 (2012).
Z. Yu, B. Zhang, F. Yu, G. Xu, and A. Song, “A real explosion: The requirement of steam explosion pretreatment,” Bioresour. Technol., No. 121, 335 (2012).
D. Fengel and G. Wegener, Wood: Chemistry, Ultrastructure, Reactions (Verlag Kessel, 2003).
B. N. Kuznetsov, A. A. Efremov, G. A. Slashchinin, E. D. Korniets, and L. K. Balakireva, “Catalytic conversion of aspen wood in a stream of superheated steam in the presence of sulfuric acid cobalt, iron and aluminum sulfates,” Khim. Drev., No. 5, 51 (1990).
V. M. Nikitin, Theoretical Foundations of Delignification (Lesnaya Prom-st, Moscow, 1981) [in Russian].
V. T. Erofeev, O. V. Startsev, V. D. Antoshkin, S. S. Gudozhnikov, E. G. Samol’kina, I. V. Boldina, and A. Yu. Makhon’kov, “Assessment of changes in timber strength in wet conditions,” Fundam. Issled., No. 9 (2014).
O. V. Startsev, A. S. Frolov, A. Yu. Makhon’kov, V. T. Erofeev, S. S. Gudozhnikov, and A. S. Krotov, “Parameter estimation of moisture transfer of polymer composites based on wood in the pre-drying stage,” Fundam. Issled., No. 5 (2014).
O. V. Startsev, A. Yu. Makhon’kov, M. V. Molokov, V. T. Erofeev, and S. S. Gudozhnikov, “The study of molecular mobility and the glass transition temperature of polymer composites based on wood by dynamic mechanical spectroscopy,” Fundam. Issled., Nos. 5–6, 1177 (2014).
E. A. Shakhzadyan, Yu. P. Kvachev, and V. S. Papkov, “Temperature transitions in the wood and its components,” Vysokomol. Soedin., Ser. A. 34 (9), 3 (1992).
E. A. Shakhzadyan, Yu. P. Kvachev, and V. S. Papkov, “Dynamic mechanical properties of some wood species,” Vysokomol. Soedin., Ser. A 36 (8), 1298 (1994).
Yu. G. Skurydin, Candidate’s Dissertation in Engineering (Barnaul, 2000).
E. M. Skurydina, Candidate’s Dissertation in Engineering (Barnaul, 2006).
O. V. Startsev, B. N. Salin, Y. G. Skuridin, R. M. Utemesov, and A. D. Nasonov, “Physical properties and molecular mobility of new wood composite plastic Thermobalite,” Wood Sci. Technol. 33, 73 (1999).
R. P. Overend and E. Chornet, “Fractionation of lignocellulosies by steam-aqueous pretreatments,” Philos. Trans. Roy. Soc. London A321 (1561), 523 (1987).
D. V. Filistovich, O. V. Startsev, and A. Ya. Suranov, “Automated installation for dynamic mechanical analysis,” Prib. Tekh. Eksp. 46 (4), 163 (2003).
O. V. Startsev, E. N. Kablov, and A. Yu. Makhon’kov, “Patterns of α-transfer in epoxy bonding of composite materials according to dynamic mechanical analysis,” Vestn. Mosk. Gos. Tekh. Univ. im. N. E. Baumana, Spets. Vyp. Perspekt. Konstr. Mater. Tekhnol., 104–113 (2011).
D. V. Filistovich, O. V. Startsev, A. A. Kuznetsov, A. S. Krotov, L. I. Anikhovskaya, L. A. Dement’eva, “Effect of moisture on the anisotropy of the dynamic shear modulus of glass-reinforced plastics,” Dokl. Phys. 48 (6), 306 (2003).
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Original Russian Text © O.V. Startsev, Yu.G. Skurydin, E.M. Skurydina, L.T. Startseva, M.V. Molokov, 2016, published in Vse Materialy. Entsiklopedicheskii Spravochnik, 2016, No. 2, pp. 15–21.
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Startsev, O.V., Skurydin, Y.G., Skurydina, E.M. et al. The influence of barometric hydrolysis on the glass-transition temperature of oak timber. Polym. Sci. Ser. D 9, 346–350 (2016). https://doi.org/10.1134/S1995421216030230
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DOI: https://doi.org/10.1134/S1995421216030230