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Structure and properties of ultrathin poly-(3-hydroxybutirate) fibers modified by silicon and titanium dioxide particles

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Abstract

The influence of small concentrations of nanoscale silicon and titanium dioxide particles on the structure, physicomechanical and sorption properties, thermal destruction resistance, and thermal and photo oxidant destruction of unwoven ultrathin fibrous materials that are prepared via electrostatic solution spinning is studied. It is established that nanoscale particles favor the formation of thinner fibers with improved physical and mechanical parameters; good resistance to thermal, thermo- and photo oxidant destruction; and positive dynamics of mesenchymal stem cells.

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References

  1. A. Greiner and J. H. Wendorff, Adv. Polym. Sci., 107–171 (2008).

    Google Scholar 

  2. Y. Filatov, A. Budyka, and V. Kirichenko, Electrospinning of Micro- and Nanofibers: Fundamentals in Separation and Filtration Processes (Begell House Inc, New York, 2007).

    Google Scholar 

  3. A. Kulkarni, V. A. Bambole, and P. A. Mahanwar, Polymer-Plastics Technol. Engin., No. (5), 427–441 (2010).

    Article  Google Scholar 

  4. Yu. N. Filatov, Electrospinning of Fibrous Materials (ESF process) (Neft’ i Gaz, Moscow, 1997) [in Russian].

    Google Scholar 

  5. A. P. Bonartsev, S. G. Yakovlev, E. V. Filatova, G. M. Soboleva, T. K. Makhina, G. A. Bonartseva, K. V. Shaitan, V. O. Popov, and M. P. Kirpichnikov, Biochemistry (Moscow) Suppl. Ser. B: Biomed. Chem., No. (1), 42–47 (2012).

    Article  Google Scholar 

  6. A. P. Bonartsev, A. L. Iordanskii, G. A. Bonartseva, and G. E. Zaikov, J. Balkan Tribol. Assoc. 14 (3), 359–395 (2008).

    CAS  Google Scholar 

  7. I. I. Zharkova, A. P. Bonartsev, A. P. Boskhomdzhiev, Yu. M. Efremov, D. V. Bagrov, T. K. Makhina, V. L. Myshkina, E. A. Ivanov, V. V. Voinova, S. G. Yakovlev, A. L. Zernov, E. V. Filatova, N. V. Andreeva, G. A. Bonartseva, and K. V. Shaitan, Biomed. Khim. 58 (5), 579–591 (2012).

    Article  CAS  Google Scholar 

  8. Yu. N. Pankova, A. N. Shchegolikhin, A. L. Iordanskii, A. L. Zhulkina, A. A. Olkhov, and G. E. Zaikov, “The characterization of novel biodegradable blends based on polyhydroxybutyrate: the role of water transport,” J. Mol. Liquids 156 (1), 65–69 (2010).

    Article  CAS  Google Scholar 

  9. A. A. Ol’khov, A. L. Iordanskii, S. V. Vlasov, R. Yu. Kosenko, Yu. S. Simonova, and G. E. Zaikov, “Matrices of furatsilina controlled release based on films made of polyhydroxybutyrate modified with shungite,” Entsikl. Inzhenera-Khimika, No. 7, 17–21 (2012).

    Google Scholar 

  10. A. P. Boskhomdzhiev, A. P. Bonartsev, T. K. Makhina, V. L. Myshkina, E. A. Ivanov, D. V. Bagrov, E. V. Filatova, A. L. Iordanski, and G. A. Bonartseva, Biochemistry (Moscow) Suppl. Ser. B: Biomed. Chem. 4 (2), 177–183 (2010).

    Article  Google Scholar 

  11. A. P. Bonartsev, A. P. Boskhomodgiev, A. L. Iordanskii, G. A. Bonartseva, A. V. Rebrov, T. K. Makhina, V. L. Myshkina, S. A. Yakovlev, E. A. Filatova, E. A. Ivanov, D. V. Bagrov, and G. E. Zaikov, Mol. Crystals Liquid Crystals 556 (1), 288–300 (2012).

    Article  CAS  Google Scholar 

  12. A. P. Bonartsev, A. P. Boskhomodgiev, V. V. Voinova, T. K. Makhina, V. L. Myshkina, S. A. Yakovlev, I. I. Zharkova, A. L. Zernov, E. A. Filatova, D. V. Bagrov, A. V. Rebrov, G. A. Bonartseva, and A. L. Iordanskii, Chem. Chem. Technol. 6 (4), 385–392 (2012).

    CAS  Google Scholar 

  13. A. P. Bonartsev, A. L. Iordanskii, G. A. Bonartseva, and G. E. Zaikov, J. Balkan Tribol. Assoc. 14 (3), 359–395 (2008).

    CAS  Google Scholar 

  14. O. V. Staroverova, A. M. Shushkevich, G. M. Kuz’micheva, A. A. Ol’khov, V. V. Voinova, I. I. Zharkova, K. V. Shaitan, E. D. Sklyanchuk, and V. V. Gur’ev, Tekhnol. Zhivykh Sist. 10 (8), 74–79 (2013).

    CAS  Google Scholar 

  15. O. V. Staroverova, A. A. Ol’khov, G. M. Kuz’micheva, E. N. Domoroshchina, S. V. Vlasov, and Yu. N. Filatov, “Ultrathin fibers based on biopolymer polyhydroxybutyrate (PHB) modified with nanoscale modifications of titanium dioxide,” Vestnik MITKhT 6 (6), 120–127 (2011).

    CAS  Google Scholar 

  16. A. A. Olkhov, O. V. Staroverova, G. M. Kuzmicheva, E. N. Domoroshina, Yu. N. Filatov, I. Yu. Filatov, S. V. Vlasov, A. L. Iordanskii, L. S. Shibryaeva, Yu. V. Tertishnaya, G. A. Bonartseva, A. P. Bonartsev, and G. E. Zaikov, “Nanofibrous materials on the basis of biopolymer—polyhydroxybutyrate,” in Nanostructured Polymers and Nanochemistry: Research Progress, Ed. by A. K. Haghi, S. Kubica, and G. E. Zaikov, (IMPIB, Institute for Engineering of Polymer Materials and Dyes, Torun, Poland, 2012), pp. 25–36.

    Google Scholar 

  17. A. A. Ishchenko, S. G. Dorofeev, N. N. Kononov, and A. A. Ol’khov, RF Patent No. 2411613, Method for obtaining nanocrystalline silicon with a bright stable photoluminescence, Bull. No. 4 (February 10, 2011)

    Google Scholar 

  18. A. A. Ishchenko, V. N. Bagratashvili, N. N. Kononov, S. G. Dorofeev, and A. A. Ol’khov, RF Patent No. 2491227, Method for obtaining biodegradable nanosilicon particles for in vivo application, Bull. No. 24 (August 27, 2013).

    Google Scholar 

  19. S. G. Dorofeev, A. O. Rybaltovskii, A. A. Ishchenko, A. A. Krutikova, A. A. Ol’khov, N. N. Kononov, V. N. Bagratashvili, and N. V. Minaev, “Laser-induced effects in the Raman spectra of nanocrystalline silicon,” Ross. Nanotekhnol. 7 (7), 96–101 (2012).

    Google Scholar 

  20. G. M. Kuz’micheva, E. V. Savinkina, L. N. Obolenskaya, et al., Kristallografiya 55 (5), 913–917 (2010).

    Google Scholar 

  21. A. A. Ol’khov, V. B. Ivanov, S. V. Vlasov, and A. L. Iordanskii, “Climatic aging of composite films based on LDPE and polyhydroxybutyrate (PHB),” Plast. Massy, No. 6, 19 (1998).

    Google Scholar 

  22. S. G. Karpova, A. L. Iordanskii, S. N. Chvalun, M. A. Shcherbina, S. M. Lomakin, N. G. Shilkina, S. Z. Rogovina, V. S. Markin, A. A. Popov, and A. A. Berlin, Dokl. Akad. Nauk 446 (5), 1–4 (2012).

    Google Scholar 

  23. A Practical Course in Plastic Processing Technology, Ed. by V. M. Vinogradov and G. S. Golovkin (Khimiya, Moscow, 1980) [in Russian].

  24. A. I. Gusev, Nanomaterials, Nanostructures, Nanotechnology, 2nd ed. (FIZMATLIT, Moscow, 2009) [in Russian].

    Google Scholar 

  25. A. A. Ol’khov, O. V. Staroverova, Yu. N. Filatov, G. M. Kuz’micheva, A. L. Iordanskii, O. V. Stoyanov, G. E. Zaikov, and L. A. Zenitova, “Nanofibrous polyhydroxybutyrate-based biomaterials,” Vestnik Kazan. Tekhnol. Univ. 16 (8), 157–161 (2013).

    Google Scholar 

  26. G. C. Rutledge and S. V. Fridrikh, Adv. Drug Delivery Rev., No. 14, 1384–1391 (2007).

    Article  Google Scholar 

  27. M. L. Di Lorenzo, M. Gazzano, and M. C. Righetti, Macromolecules, 5684–5691 (2012).

    Google Scholar 

  28. A. A. Ishchenko, G. V. Fetisov, and L. A. Aslanov, Nanosilicon: Properties, Production, Application, and Methods of Research and Monitoring (Fizmatlit, Moscow, 2011) [in Russian].

    Google Scholar 

  29. A. A. Ishchenko and A. A. Ol’khov, RF Patent No. 2429189, Polymeric nanocomposite for protection against UV (September 20, 2011).

    Google Scholar 

  30. A. A. Ol’khov, D. Dzh. L’yao, G. V. Fetisov, M. A. Gol’dshtrakh, N. N. Kononov, A. A. Krutikova, P. A. Storozhenko, and A. A. Ishchenko, “Nanocom-posite films with UV-barrier properties based on polyethylene with ultrafine silicon,” Plast. Massy, No. 9, 40–46 (2010).

    Google Scholar 

  31. A. A. Ishchenko, G. V. Fetisov, and L. A. Aslanov, Nanosilicon: Properties, Production, Application, and Methods of Research and Monitoring (FIZMATLIT, Moscow, 2011) [in Russian].

    Google Scholar 

  32. A. A. Popov, N. Ya. Rapoport, and G. E. Zaikov, Oxidation of Oriented and Strained Polymers (Khimiya, Moscow, 1987) [in Russian].

    Google Scholar 

  33. A. P. Boskhomdzhiev, A. P. Bonartsev, E. A. Ivanov, T. K. Makhina, V. L. Myshkina, D. V. Bagrov, E. V. Filatova, G. A. Bonartseva, and A. L. Iordanskii, Int. Polym. Sci. Technol., No. 11, 25–30 (2010).

    Google Scholar 

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Correspondence to A. A. Olkhov.

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Original Russian Text © A.A. Olkhov, O.V. Staroverova, A.P. Bonartsev, I.I. Zharkova, E.D. Sklyanchuk, A.L. Iordanskii, S.Z. Rogovina, A.A. Berlin, A.A. Ishchenko, 2014, published in Vse Materialy. Entsiklopedicheskii Spravochnik, 2014, No. 12, pp. 2–13.

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Olkhov, A.A., Staroverova, O.V., Bonartsev, A.P. et al. Structure and properties of ultrathin poly-(3-hydroxybutirate) fibers modified by silicon and titanium dioxide particles. Polym. Sci. Ser. D 8, 100–109 (2015). https://doi.org/10.1134/S1995421215020124

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  • DOI: https://doi.org/10.1134/S1995421215020124

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