Abstract
With the purpose of obtaining new thermosensitive polymers, the phase transition temperatures of aqueous solutions of the N,N-dimethylaminoethylmethacrylate homopolymers and its copolymers with N,N-butylacrylamide, dodecylacrylate, dodecylmethacrylate, N-(3-dimethylaminopropyl)methacrylamide, and acrylic acid have been investigated. It is shown that the lower critical solution temperatures of polymers depend on the concentration of polymer and on the type of comonomer.
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References
RF Patent No. 2434894 (November 27, 2011).
RF Patent No. 2416433 (April 20, 2011).
EU Patent No. 0326276 A3 (September 4, 1991).
O. Schepelina and I. Zharov, Langmuir 24 ((24)), 14188–14194 (2008).
M. Kamperman, C. B. W. Garcia, P. Du, et al., J. Am. Chem. Soc. 126, 14708–14709 (2004).
P. Cotanda, D. B. Wright, M. Tyler, and R. K. O’Reilly, J. Polym. Sci. Part A: Polym. Chem. 51 3333–3338 (2013).
S. H. Yuk, S. H. Cho, and S. H. Lee, Macromolecules 30, 6856–6859 (1997).
X. J. Loh, J. Appl. Polym. Sci. (2012). DOI: 10.1002/APP.3753
S. G. Roy, K. Bauri, S. Pal, et al., Polym. Int. (2012). DOI: 10.1002/pi.4335
C. Zhang and M. Maric, Polymers, No. 3, 1398–1422 (2011). DOI: 10.3390/polym3031398
D. Kuckling, A. Doering, F. Krahl, and K.-F. Arndt, Polym. Sci. Comprehensive Reference 8 377–442. DOI: 10.1016/B9780444533494.00214-4
G. Georglev, E. Kamenska, G. Kareyannldla, et al., Polym. Bull. 17, 169–174 (1987).
V. Butun, S. P. Armes, and N. C. Billingham, Polymer 42, 5993–6008 (2001).
E. Uchida, Y. Uyama, and Y. Ikada, Langmuir 10, 1193–1198 (1994).
F. A. Plamper, M. Ruppel, A. Schmalz, et al., Macromolecules 40, 8361–8366 (2007).
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Original Russian Text © D.M. Kamorin, K.V. Shirshin, O.A. Kazantsev, A.P. Sivokhin, 2014, published in Klei. Germetiki. Tekhnologii, 2014, No. 9, pp. 27–30.
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Kamorin, D.M., Shirshin, K.V., Kazantsev, O.A. et al. Studies of concentration dependences of phase transition temperatures of amine-containing (meth)acrylic copolymers in aqueous solutions. Polym. Sci. Ser. D 8, 171–174 (2015). https://doi.org/10.1134/S1995421215020094
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DOI: https://doi.org/10.1134/S1995421215020094