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Thermophysical properties of epoxy-polysiloxane composites of cationic polymerization

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Abstract

Epoxy-polysiloxane composites of cationic polymerization were synthesized based on epoxy resin and tetraethoxysilane. The thermophysical properties of the resulting polymers were studied. It was established that, as the filler content increases from 0.5 to 3 wt %, the molecular weight of an intermodal segment increases and the cross-linking density of an epoxy matrix and glass transition point reduce. The resulting polymers have a heterogeneous structure in which the regions of structuring with the corresponding glass transition points are segregated.

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References

  1. L. Grath, R. Parnas, S. King, et al., Lenhart Polymer 49(4), 999–1014 (2008).

    Article  Google Scholar 

  2. S. Lu, H. Zhang, C. Zhao, et al., J. Mater. Sci. 40(5), 1079–1085 (2005).

    Article  CAS  Google Scholar 

  3. L. Matjka, O. Dukh, and J. Kolarik, Polymer 41(4), 1449–1459 (2000).

    Article  Google Scholar 

  4. W. Weng, C. Chang, and H. Chen, Composite Interfaces 11(9), 631–641 (2005).

    Article  CAS  Google Scholar 

  5. L. Matjka, J. Plestil, and K. Dusek, J. Non-Cryst. Solids 226(2), 114–121 (1998).

    Article  Google Scholar 

  6. N. G. Leonova, V. M. Mikhal’chuk, L. A. Savenkova, and V. A. Beloshenko, Vopr. Khim. Khim. Tekhnol., No. 1, 48–53 (2009).

    Google Scholar 

  7. N. G. Leonova, V. M. Mikhal’chuk, and V. A. Beloshenko, Visnik Donetsk. Nats. Univ., Ser. A: Prirodn. Nauki, No. 1, 191–195 (2010).

    Google Scholar 

  8. N. G. Leonova, V. M. Mikhal’chuk, V. I. Rybachenko, et al., Zh. Prikl. Khim. (S.-Peterburg) 84(4), 673–677 (2011).

    Google Scholar 

  9. R. I. Lyga, N. G. Leonova, V. M. Mikhal’chuk, et al., Teor. Eksp. Khim. 47(4), 257–261 (2011).

    Google Scholar 

  10. L. Mat jka, O. Dukh, J. Brus, et al., J. Non-Cryst. Solids 270(1-3), 34–47 (2000).

    Article  Google Scholar 

  11. J. Macan, H. Ivankovic, M. Ivankovic, and H. J. Mencer, J. Appl. Pol. Sci. 92(1), 498–505 (2004).

    Article  CAS  Google Scholar 

  12. W. H. Weng, H. Chen, S. P. Tsai, and J. Ch. Wu, J. Appl. Pol. Sci. 91(1), 532–537 (2004).

    Article  CAS  Google Scholar 

  13. L. R. Treloar, The Physics of Rubber Elasticity, 3rd ed. (Clarendon Press, Oxford, 2005).

    Google Scholar 

  14. V. P. Zakordonskii, Zh. Prikl. Khim. (S.-Peterburg) 68(9), 1532–1537 (1995).

    CAS  Google Scholar 

  15. Yu. N. Paramonov, V. N. Artemov, and M. S. Klebanov, Reactive Oligomers, Polymers, and Materials Based on Them: Collected Papers (NPO Plastik, Moscow, 1977) [in Russian].

    Google Scholar 

  16. E. Cluff, E. Gladding, and R. Pariser, J. Polym. Sci. 45(146), 341–345 (1960).

    Article  CAS  Google Scholar 

  17. Yu. K. Godovsky, Thermal Physics of Polymers (Khimiya, Moscow, 1982) [in Russian].

    Google Scholar 

  18. V. A. Bernshtein and V. M. Egorov, Differentsial’naya skaniruyushchaya kalorimetriya v fizikokhimii polimerov (Differential Scanning Calorimetry in Physics and Chemistry of Polymers), Leningrad: Khimiya, 1990.

    Google Scholar 

  19. Z. Ahmad, M. Ansell, and D. Smedley, IJET-IJEN 10(2), 32–38.

  20. S. V. Zhil’tsova, V. M. Mikhal’chuk, E. M. Petrova, et al., Zh. Prikl. Khim. (S.-Peterburg) 80(3), 479–483 (2007).

    Google Scholar 

  21. L. A. Savenkova, V. M. Mikhal’chuk, V. I. Rybachenko, et al., Vopr. Khim. Khim. Tekhnol., No. 1, 117–121 (2007).

    Google Scholar 

  22. V. I. Irzhak, B. A. Rozenberg, and N. S. Enikolopyan, Reticulated polymers: Synthesis, Structure, and Properties (Nauka, Moscow, 1979) [in Russian].

    Google Scholar 

  23. Yu. S. Zaitsev, Yu. S. Kochergin, M. K. Pakter, and R. V. Kucher, Epoxy Oligomers and Adhesive Compositions (Nauk. Dumka, Kiev, 1990) [in Russian].

    Google Scholar 

  24. Y. Sun, Zh. Zhang, and C. P. Wong, Polymer 46(7), 2297–2305 (2005).

    Article  CAS  Google Scholar 

  25. Y. Sun, Zh. Zhang, K.-S. Moon, and C. P. Wong, J. Polym. Sci. 42(1), 3849–3858.

  26. T. V. Grinevich, S. V. Meshkov, and A. A. Solov’yanov, Vysokomol. Soedin. 37(3), 554–557 (1995).

    CAS  Google Scholar 

  27. A. U. Francis, S. Venkatachalam, M. Kanakavel, et al., Europ. Polym. J. 39(4), 831–841 (2003).

    Article  CAS  Google Scholar 

  28. J. Ostrauskaite, G. Buika, J. V. Grazulevicius, and A. Stanisauskaite, Eur. Polym. J. 36(11), 2499–2504 (2000).

    Article  CAS  Google Scholar 

  29. L. Nielsen, Mechanical Properties of Polymers and Composites, New York: Dekker, 1974.

    Google Scholar 

  30. S. V. Zhil’tsova, V. M. Mikhal’chuk, N. V. Babkina, et al., Pol. Sci. Ser. D 4(3), 12–18 (2011).

    Google Scholar 

  31. L. Mascia and T. Tang, J. Mater. Sci. 8(11), 2417–2421 (1998).

    CAS  Google Scholar 

  32. J. Macan, H. Ivankovic, M. Ivankovic, and H. J. Mencer, J. Appl. Pol. Sci. 92(1), 498–505 (2004).

    Article  CAS  Google Scholar 

  33. M. Yu. Korindyasova, Yu. V. Zherdev, and I. Yu. Sheideman, Plast. Massy, No. 6, 49–51 (1970).

    Google Scholar 

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Authors and Affiliations

  1. Donetsk National University, ul. Universitetskaya 24, Donetsk, 83001, Ukraine

    N. G. Leonova & V. M. Mikhal’chuk

  2. Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Khar’kovskoe sh. 48, Kyiv, 02160, Ukraine

    Y. P. Mamunya, V. V. Davydenko & M. V. Iurzhenko

Authors
  1. N. G. Leonova
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  2. V. M. Mikhal’chuk
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  3. Y. P. Mamunya
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  4. V. V. Davydenko
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  5. M. V. Iurzhenko
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Correspondence to N. G. Leonova.

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Original Russian Text © N.G. Leonova, V.M. Mikhal’chuk, Y.P. Mamunya, V.V. Davydenko, M.V. Iurzhenko, 2013, published in Klei. Germetiki. Tekhnologii, 2013, No. 1, pp. 21–28.

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Leonova, N.G., Mikhal’chuk, V.M., Mamunya, Y.P. et al. Thermophysical properties of epoxy-polysiloxane composites of cationic polymerization. Polym. Sci. Ser. D 6, 210–217 (2013). https://doi.org/10.1134/S1995421213030131

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