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Upconversion Nanoparticles: Synthesis, Photoluminescence Properties, and Applications

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Abstract

In the late 1990s, the unique possibilities application of inorganic nanocrystals with anti-Stokes photoluminescence were demonstrated. In a fairly short period, a significant breakthrough has been achieved in this field due to the development of new and modification of existing methods for the synthesis of these nanomaterials, and the expansion of understanding of the photophysical processes occurring in nanocrystals. The interest from the scientific community is due to the exceptional luminescence properties of upconversion nanomaterials, which can convert photons of the near-infrared spectrum to radiation in the visible and UV ranges. This multiquantum process takes place under low-intensity excitation, which largely determines the use of this class of nanomaterials in high-tech fields, including biotechnology, photochemistry, medicine, solar energy, nanosensorics, etc. The goals of this review are to consider the mechanisms of anti-Stokes luminescence, to analyze the synthesis methods, and to demonstrate the applications of fluoride upconversion nanomaterials, in which they have formed a stable scientific and technological niche.

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Funding

This work was supported by the Russian Foundation for Basic Research (project no. 19-02-00877 in terms of analysis of methods for the synthesis of nanoparticles, project no. 18-29-20064 in terms of analysis of synthesis methods and properties of hybrid nanostructures) and the RF Ministry of Science and Higher Education in the framework of the state assignment of the Federal Research Center “Crystallography and Photonics” of the Russian Academy of Sciences in terms of the analysis of the photophysics of the upconversion process.

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Authors and Affiliations

  1. Federal Scientific Research Center “Crystallography and Photonics”, Russian Academy of Sciences, 119333, Moscow, Russia

    D. N. Karimov, P. A. Demina, A. V. Koshelev, V. V. Rocheva, A. V. Sokovikov, A. N. Generalova, E. V. Khaydukov, M. V. Koval’chuk & V. Ya. Panchenko

  2. Shemyakin and Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, 117997, Moscow, Russia

    P. A. Demina, A. N. Generalova & V. P. Zubov

  3. National Research Center “Kurchatov Institute”, 123182, Moscow, Russia

    E. V. Khaydukov, M. V. Koval’chuk & V. Ya. Panchenko

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  1. D. N. Karimov
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Karimov, D.N., Demina, P.A., Koshelev, A.V. et al. Upconversion Nanoparticles: Synthesis, Photoluminescence Properties, and Applications. Nanotechnol Russia 15, 655–678 (2020). https://doi.org/10.1134/S1995078020060117

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