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3D Structures Based on Reduced Graphite Oxide and Gold Nanoparticles and Their Sorption Properties

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Abstract

The preparation of hydro- and aerogels based on reduced graphite oxide and gold nanoparticles obtained by the method of Turkevich is described. According to the transmission electron microscopy data, gold nanoparticles have a spherical shape and an average size of 16‒18 nm. Sorption of methylene blue dye from water solutions was used to characterize the obtained 3D structures. The sorption properties of hydro- and aerogels were compared; it was shown that aerogels sorb the dye more efficiently (>80%) than a composite based on hydrogel (~50%). The formed porous 3D structure of the aerogel efficiently sorbs the molecules of the dye, while the gold nanoparticles facilitate its destruction under the visible light. Sorption by aerogels of pure graphite oxide is most efficient at room temperature, in a neutral medium, and in the absence of additional reducing agents. Introduction of gold nanoparticles to aerogels led to an increase of the maximal sorption by 15%.

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REFERENCES

  1. A. K. Geim and K. S. Novoselov, “The rise of graphene,” Nat. Mater. 6, 183 (2007).

    Article  CAS  Google Scholar 

  2. A. Lerf, H. He, M. Forster, and J. Klinowski, “Structure of graphite oxide revisited,” J. Phys. Chem. B 102, 4477 (1998).

    Article  CAS  Google Scholar 

  3. Yanwu Zhu, Shanthi Murali, Weiwei Cai, et al., “Graphene and graphene oxide: synthesis, properties, and applications,” Adv. Mater. 22, 3906 (2010).

    Article  CAS  Google Scholar 

  4. H. Gao and H. Duan, “2D and 3D graphene materials: preparation and bioelectrochemical applications,” Biosens. Bioelectron. 65, 404 (2015).

    Article  CAS  Google Scholar 

  5. B. C. Brodie, “On the athomic weight of graphite,” Phil. Trans. R. Soc. London 149, 249 (1859).

    Article  Google Scholar 

  6. W. S. Hammers and R. E. Offeman, “Preparation of graphitic oxide,” J. Am. Chem. Soc. 80, 1339 (1958).

    Article  Google Scholar 

  7. D. C. Marcano, D. V. Kosynkin, J. M. Berlin, et al., “Improved synthesis of graphene oxide,” ACS Nano 4, 4806 (2010).

    Article  CAS  Google Scholar 

  8. I. Kondratowicz, K. Zelechowska, M. Nadolska, et al., “Comprehensive study on graphene hydrogels and aerogels synthesis and their ability of gold nanoparticles adsorption,” Colloids Surf. A 528, 65 (2017).

    Article  CAS  Google Scholar 

  9. W. Chen and L. Yan, “In situ self-assembly of mild chemical reduction graphene for three-dimensional architectures,” Nanoscale 3, 3132 (2011).

    Article  CAS  Google Scholar 

  10. Xuan Lu, Xiaoli Liu, Ting Shen, et al., “Convenient fabrication of graphene/gold nanoparticle aerogel as direct electrode for H2O2 sensing,” Mater. Lett. 207, 49 (2017).

    Article  CAS  Google Scholar 

  11. H. Gao and H. Duan, “2D and 3D graphene materials: Preparation and bioelectrochemical applications,” Biosens. Bioelectron., No. 65, 404 (2015).

  12. Qiangqiang Zhang, Yu Wang, Baoqiang Zhang, et al., “3D superelastic graphene aerogel-nanosheet hybrid hierarchical nanostructures as high-performance supercapacitor electrodes,” Carbon, No. 127, 449 (2018).

    Article  CAS  Google Scholar 

  13. Dong  Ma,  Jiantao Lin,  Yuyun Chen,  Wei Xue, Li-Ming Zhang, “In situ gelation and sustained release of an antitumor drug by graphene oxide nanosheets,” Carbon 50, 3001 (2012).

  14. E. Jokara, S. Shahrokhiana, A. Iraji zada, et al., “An efficient two-step approach for improvement of graphene aerogel characteristics in preparation of supercapacitor electrodes,” J. Energy Storage, No. 17, 465 (2018).

    Article  Google Scholar 

  15. Xin Wang, Chengxing Lu, Huifen Peng, et al., “Efficiently dense hierarchical graphene based aerogel electrode for supercapacitors,” J. Power Sources, No. 324, 188 (2016).

    Article  CAS  Google Scholar 

  16. Zh. Sun, W. Fan, and T. Liu, “Graphene/graphene nanoribbon aerogels as tunable three-dimensional framework for efficient hydrogen evolution reaction,” Electrochim. Acta, No. 250, 91 (2017).

    CAS  Google Scholar 

  17. Zh. Yang, G. Xing, P. Hou, and D. Han, “Amino acid-mediated n-doped graphene aerogels and its electrochemical properties,” Mater. Sci. Eng. B, No. 228, 198 (2018).

  18. Xuan Lu, Xiaoli Liu, Ting Shen, et al., “Convenient fabrication of graphene/gold nanoparticle aerogel as direct electrode for H2O2 sensing,” Mater. Lett., No. 207, 49 (2018).

  19. R. Pocklanova, A. K. Rathi, M. B. Gawande, et al., “Gold nanoparticle-decorated graphene oxide: synthesis andapplication in oxidation reactions under benign conditions,” J. Mol. Catal. A: Chem. 424, 121 (2016).

    Article  CAS  Google Scholar 

  20. Xiaoli Liu, Ting Shen, Zhiyong Zhao et al., “Graphene/gold nanoparticle aerogel electrode for electrochemical sensing of hydrogen peroxide,” Mater. Lett. 229, 368 (2018).

    Article  CAS  Google Scholar 

  21. J. Xie, X. Yang, and X. Xu, “Wet chemical method for synthesizing 3D graphene/gold nanocomposite: catalytic reduction of methylene blue,” Phys. E (Amsterdam, Neth.) 88, 201 (2017).

  22. Yu. V. Ioni, V. V. Voronov, A. V. Naumkin, E. Yu. Buslaeva, A. V. Egorov, S. V. Savilov, and S. P. Gubin, “Platinum, palladium, and rhodium nanoparticles on the surface of graphene flakes,” Russ. J. Inorg. Chem. 60, 709 (2015).

    Article  CAS  Google Scholar 

  23. Yu. Ioni, E. Buslaeva, and S. Gubin, “Synthesis of graphene with noble metals nanoparticles on its surface,” Mater. Today: Proc. 3, 209 (2016).

    Google Scholar 

  24. Fang Ren, Zhen Li, Wen-Zhen Tan, et al., “Facile preparation of 3D regenerated cellulose/graphene oxide composite aerogel with high-efficiency adsorption towards methylene blue,” J. Colloid Interface Sci. 532, 58 (2018).

    Article  CAS  Google Scholar 

  25. J. Turkevich, P. C. Stevenson, and J. Hillier, “A study of the nucleation and growth processes in the synthesis of colloidal gold,” J. Am. Chem. Soc., 55 (1951).

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Funding

This study was supported by the Russian Foundation for Basic Research, project nos. 19-03-00556, 18-29-19120.

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Correspondence to E. A. Eremina.

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Translated by V. Kudrinskaya

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Eremina, E.A., Dobrovolskii, A., Lemesh, I.A. et al. 3D Structures Based on Reduced Graphite Oxide and Gold Nanoparticles and Their Sorption Properties. Nanotechnol Russia 14, 427–434 (2019). https://doi.org/10.1134/S1995078019050045

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  • DOI: https://doi.org/10.1134/S1995078019050045

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