Abstract
It is shown that anionic indoheptamethine cyanine dyes of different structures form mixed metalcomplex J-aggregates in aqueous solutions under the action of multiply charged inorganic cations. By measuring the photoconductivity of layers from mixed metal-complex J-aggregates, it has been found that the photoresponse of nanoscale photoconverters for the IR region of the spectrum increases significantly in comparison with the indices for the J-aggregate of the individual dye. It is concluded that the formation of new highly organized structures by the self-assemblage of J-aggregates of several dyes can be considered a promising nanotechnology method for the production of organic semiconductors with improved photo properties.
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References
B. I. Shapiro, “Molecular assemblies of polymethine dyes,” Russ. Chem. Rev. 75, 433–456 (2006).
B. I. Shapiro, “Block building of polymethine dye aggregates,” Nanotechnol. Russ. 3, 139–150 (2008).
B. I. Shapiro, E. A. Satalkina, and A. D. Nekrasov, “Matrix synthesis of multilayer aggregates of polymethine dyes,” Nanotechnol. Russ. 9, 356–362 (2014).
B. I. Shapiro, E. V. Manulik, and V. V. Prokhorov, “Multilayer J-aggregates of cyanine dyes,” Nanotechnol. Russ. 11, 265–272 (2016).
B. I. Shapiro and E. V. Manulik, “Multichromic J-aggregates of cyanine dyes for visible and IR range of spectrum,” Nanotechnol. Russ. 11, 273–279 (2016).
V. I. Avdeeva and B. I. Shapiro, “J-aggregation of cyanine dyes in gelatin solutions and matrices,” Dokl. Phys. Chem. 389, 77–79 (2003).
L. V. Rozhkova and B. I. Shapiro, “Spectral sensitization with mixed J-aggregates in the infrared region of the spectrum,” Zh. Nauch. Prikl. Fotogr. 48 (1), 58–66 (2003).
B. I. Shapiro, L. V. Chirkova, A. I. Tolmachev, Yu. L. Slominskii, and V. A. Kuz’min, “Formation of mixed J-aggregates of cyanine dyes stimulated by Eu+3 cations,” High Energy Chem. 44, 418–422 (2010).
M. Kawasaki and S. Aoyama, “High efficiency photocurrent generation by two-dimensional mixed J-aggregates of cyanine dyes,” Chem. Commun., No. 4, 988–989 (2004).
M. Kawasaki, S. Aoyama, and E. Kozawa, “Enhanced intra-aggregate charge separation from binary excitons in mixed J-aggregates of cyanine dyes,” J. Phys. Chem. B 110, 24480–24485 (2006).
B. I. Shapiro and E. V. Manulik, “Synthesis of mixed J-aggregates based on polymethine dyes of different structure,” Nanotechnol. Russ. 12, 9–18 (2017).
A. K. Chibisov, H. Gorner, and T. D. Slavnova, “Kinetics of salt-induced J-aggregation of an anionic thiacarbocyanine dye in aqueous solution,” Chem. Phys. Lett. 390, 240–245 (2004).
T. D. Slavnova, A. K. Chibisov, and H. Gorner, “Kinetics of salt-induced J-aggregation of cyanine dyes,” J. Phys. Chem. A 109, 4758–4765 (2005).
B. I. Shapiro, E. A. Belonozhkina, O. A. Tyapina, and V. A. Kuz’min, “cis-, trans-Aggregates of thiatrimethine cyanine dyes,” Nanotechnol. Russ. 4, 38–44 (2009).
A. D. Nekrasov and B. I. Shapiro, “Effect of multiply charged paramagnetic metal cations on J-aggregation of thiacyanine dyes,” High Energy Chem. 45, 133–139 (2011).
A. K. Chibisov, T. D. Slavnova, and H. Görner, “Selfassembly of polymethine dye molecules in solutions: kinetic aspects of aggregation,” Nanotechnol. Russ. 3, 19 (2008).
D. A. Voznyak and A. K. Chibisov, “Kinetic models of J-aggregation of polymethine dyes,” Nanotechnol. Russ. 3, 543 (2008).
M. V. Proskurnina, T. A. Podrugina, V. A. Kuz’min, T. D. Nekipelova, and N. S. Zefirov, Fluorophores with an Indolenin Scaffold and Their Use for Biomedical Purposes (Gilem, Ufa, 2016) [in Russian].
B. I. Shapiro, E. V. Manulik, and A. D. Nekrasov, “J-aggregates of indoheptamethin cyanine dye,” Nanotechnol. Russ. 13 (3–4), 103–108 (2018).
N. A. Davidenko, A. A. Ishchenko, V. A. Pavlov, V. A. Pivtorak, and N. G. Chuprinova, “Photoconductivity of poly-n-epoxypropylcarbazole films doped with polymethine dyes of varying degrees of ionicity,” Zh. Nauch. Prikl. Fotogr. 46, 53–59 (2001).
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Original Russian Text © B.I. Shapiro, E.V. Manulik, A.D. Nekrasov, 2018, published in Rossiiskie Nanotekhnologii, 2018, Vol. 13, Nos. 3–4.
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Shapiro, B.I., Manulik, E.V. & Nekrasov, A.D. Nanoscale Photoconverters for the IR Region of the Spectrum Based on Mixed J-Aggregates of Indolenine Dyes. Nanotechnol Russia 13, 134–140 (2018). https://doi.org/10.1134/S1995078018020131
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DOI: https://doi.org/10.1134/S1995078018020131