Abstract
The growth process of nonspherical nanoparticles on preliminarily synthesized gold-silver seeds in micellar surfactant media is studied in this article. The effect of experimental factors, such as the concentration of initial compounds and formation of intermediate insoluble compounds, on nanoparticle size and geometry in the output sole is investigated. It is concluded that the slow generation of silver ions, causing layer-by-layer directed growth, is a necessary factor of anisotropic nanoparticles formation. The optimized parameters of synthesis enable one to control the geometry of final sols and increase the yield of resulting anisotropic nanoparticles.
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References
M.-C. Daniel and D. Astruc, “Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology,” Chem. Rev. 104(1), 293–346 (2004).
C. Burda, X. Chen, R. Narayanan, and M. A. El-Sayed, “Chemistry and properties of nanocrystals of different shapes,” Chem. Rev. 105(4), 1025–1102 (2005).
Yu. A. Krutyakov, A. A. Kudrinskii, A. Yu. Olenin, and G. V. Lisichkin, “Synthesis and properties of Ag nanoparticles: achievements and trends,” Usp. Khim. 77(3), 242–269 (2008).
A. Yu. Olenin and G. V. Lisichkin, “Manufacturing, dynamic of volume and surface structure of metallic nanoparticles in condensed mediums,” Usp. Khim. 80(7), 635–662 (2011).
B. Wiley, Y. Sun, B. Mayers, and Y. Xia, “Shape-controlled synthesis of metal nanostructures: the case of silver,” Chem. Eur. J. 11(2), 454–463 (2005).
A. Yu. Olenin, Yu. A. Krutyakov, and G. V. Lisichkin, “Formation mechanisms of anisotropic silver nanostructures in polyol synthesis,” Nanotech. Russ. 5(5–6), 421 (2010).
C. J. Murphy, A. M. Gole, S. E. Hunyadi, and C. J. Orendorff, “One-dimensional colloidal gold and silver nanostructures,” Inorg. Chem. 45(19), 7544–7554 (2006).
A. A. Eliseev and A. V. Lukashin, Functional Nanomaterials, Ed. by Yu. D. Tret’yakov (Fizmatlit, Moscow, 2010), p. 247 [in Russian].
P.-Y. Silvert, R. Herrera-Urbina, and K. Tekaia-Elhsissen, “Preparation of colloidal silver dispersions by the polyol process. Part 2. Mechanism of particle formation,” J. Mater. Chem. 7(2), 293–299 (1997).
Y. Wu, P. Jiang, M. Jiang, T.-W. Wang, C.-F. Guo, S.-S. Xie, and Z.-L. Wang, “The shape evolution of gold seeds and goldsilver core-shell nanostructures,” Nanotecnology 20(30) (2009).
G. Park, D. Seo, J. Jung, S. Ryu, and H. Song, “Shape evolution and gram-scale synthesis of gold silver core-shell nanopolyhedrons,” J. Phys. Chem. C 115(19), 9417–9423 (2011).
A. Moores and F. Goettmann, “The plasmon band in noble metal nanoparticles: an introduction to theory and applications,” New J. Chem. 30(8), 1121–1132 (2006).
D. D. Evanoff Jr. and G. Chumanov, “Synthesis and optical properties of silver nanoparticles and arrays,” Chem. Phys. Chem. 6(7), 1221–1231 (2005).
S. Link and M. A. El-Sayed, “Shape and size dependence of radiative, non-radiative and photothermal properties of gold nanocrystals,” Int. Rev. Phys. Chem. 19(3), 409–453 (2000).
M. Rycenga, C. M. Cobley, J. Zeng, W. Li, C. H. Moran, Q. Zhang, D. Qin, and Y. Xia, “Controlling the synthesis and assembly of silver nanostructures for plasmonic applications,” Chem. Rev. 111(6), 3669–3712 (2011).
V. A. Rabinovich and Z. A. Khanin, Concise Chemistry Handbook (Khimiya, Moscow, 1977), p. 125 [in Russian].
C. J. Murphy, T. K. Sau, A. M. Gole, C. J. Orendorff, J. Gao, L. Gou, S. E. Hunyadi, and T. Li, “Anisotropic metal nanoparticles: synthesis, assembly, and optical applications,” J. Phys. Chem. B. 109(29), 13857–13870 (2005).
X. Cui, S. Mao, M. Liu, H. Yuan, and Y. Du, “Mechanism of surfactant micelle formation,” Langmuir 24(19), 10771–10775 (2008).
B. Wiley, T. Herricks, Y. Sun, and Y. Xia, “Polyol synthesis of silver nanoparticles: use of chloride and oxygen to promote the formation of single-crystal, truncated cubes and tetrahedrons,” Nano Lett. 4(9), 1733–1739 (2004).
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Original Russian Text © T.R. Nizamov, I.V. Evstafiev, A.Yu. Olenin, A.V. Knot’ko, G.V. Lisichkin, 2014, published in Rossiiskie Nanotekhnologii, 2014, Vol. 9, Nos. 7–8.
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Nizamov, T.R., Evstafiev, I.V., Olenin, A.Y. et al. Anisotropic growth of silver nanoparticles on preliminarily synthesized seeds. Nanotechnol Russia 9, 391–397 (2014). https://doi.org/10.1134/S1995078014040120
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DOI: https://doi.org/10.1134/S1995078014040120