Skip to main content

Analysis of the structure of polymer-inorganic nanoparticles in solutions

Abstract

A methodical approach to analyzing the structure of hybrid polymer-inorganic particles with covalent bonding between the components has been suggested. Its effectiveness has been demonstrated on the example of modified poly(methyl methacrylate) containing covalently bonded zirconium dioxide nanocrystals. The methodological approach is based on the application of viscometry, dynamic light scattering, and absorption spectroscopy for a comparative study of the unmodified polymer and its analogue containing a low weight fraction (about a few hundredths) of hybrid particles. The methodology allows a quantitative estimation of the weight of the polymer component covalently bonded to the inorganic nanoparticle to obtain a fully soluble composite material.

This is a preview of subscription content, access via your institution.

References

  1. N. A. Shabanova, Chemistry and Technology of Nanodispersed Systems (Akademkniga, Moscow, 2006) [in Russian].

    Google Scholar 

  2. S. Pavlidou and C. D. Papaspyrides, Progr. Polym. Sci. 33(12), 1119–1198 (2008).

    Article  Google Scholar 

  3. Polymer Nanocomposites, Ed. by Yu. Mai Yiu-Wing and Zhong Zhen (Woodhead Publ., 2006).

    Google Scholar 

  4. V. E. Yudin and V. M. Svetlichnyi, Zh. Obshch. Khim. 53, 75 (2010).

    Google Scholar 

  5. S. M. Khaled, R. Sui, A. Paul, P. A. Charpentier, and A. S. Rizkalla, Langmuir 23, 3988–3995 (2007).

    Article  Google Scholar 

  6. P. Obreja, D. Cristea, V. S. Teodorescu, A. Dinescu, A. C. Obreja, F. Comanescu, and R. Rebigan, J. Optoelectron. Adv. Mater. 12(10), 2007–2013 (2010).

    Google Scholar 

  7. A. N. Bugrov, E. N. Vlasova, M. V. Mokeev, E. N. Popova, E. M. Ivankova, O. V. Al’myasheva, and V. M. Svetlichnyi, Polym. Sci. Ser. B Polym. Phys. 54(10), 486 (2012).

    Article  Google Scholar 

  8. V. N. Tsvetkov, V. E. Eskin, and S. Ya. Frenkel’, Structure of Macromolecules in Solution (Nauka, Moscow, 1964) [in Russian].

    Google Scholar 

  9. B. J. Berne and R. Pecora, Dynamic Light Scattering (Courier Dover Publ., New York, 2000).

    Google Scholar 

  10. M. K. Mishra and Y. Yagci, Handbook of Vinyl Polymers: Radical Polymerization, Progress, and Technology (Taylor&Francis, Boca Raton, 2009).

    Google Scholar 

  11. Y. Hu, Sh. Zhou, and L. Wu, Polymer 50(11), 3609–3616 (2009).

    Article  Google Scholar 

  12. T. Otsuka and Y. Chujo, Polym. J. 42(1), 56–65 (2010).

    Article  Google Scholar 

  13. S. Shokoohi, A. Arefazar, and R. Khorsokhavar, J. Reinf. Plast. Comp. 27, 473–479 (2008).

    Article  Google Scholar 

  14. A. S. Bugrov, “Polymeric-inorganic composites based on carbon- and heterochain polymers modified by ZrO2 nanoparticles”, Candidate’s Dissertation in Chemical Sciences (St. Petersburg, 2013).

    Google Scholar 

  15. O. V. Pozhidaeva, E. N. Korytkova, D. P. Romanov, and V. V. Gusarov, “The way to synthesize zirconium dioxide crystals in hydrothermal mediums of different chemical composition,” Zh. Obshch. Khim. 72(6), 910–914 (2002).

    Google Scholar 

  16. http://photocor.com/dynals/

  17. S. N. Chinai, J. D. Matlack, A. L. Resnick, and R. J. Samuels, J. Polym. Sci. 17, 391–401 (1955); J. Brandrup, E. H. Immergut, E. A.Grulke, A. Abe, and D. R. Bloch, Polymer Handbook, 4th ed. (John Wiley&Sons, 2005).

    Article  Google Scholar 

  18. A. A. Mercurieva, T. M. Birshtein, and V. M. Amoskov, “Theory of liquid-crystalline ordering in polymer Brushes,” Macromol. Sym. 252(1), 90–100 (2007).

    Article  Google Scholar 

  19. S. Okabe, S. Sugihara, S. Aoshima, and M. Shibayama, Macromolecules 36(11), 4099 (2003).

    Article  Google Scholar 

  20. M. Shibayama, T. Karino, and S. Okabe, Polymer 47(18), 6446 (2006).

    Article  Google Scholar 

  21. C. Wu, M. Siddiq, and K. F. Woo, Macromolecules 28(14), 4914 (1995).

    Article  Google Scholar 

  22. Y. Zhang, C. Wu, Q. Fang, and Y.-X. Zhang, Macromolecules 29(7), 2494 (1996).

    Article  Google Scholar 

  23. C. Wu, S. Bo, M. Siddiq, G. Yang, and T. Chen, Macromolecules 29(9), 3157 (1996).

    Article  Google Scholar 

  24. E. A. Litmanovich and E. M. Ivleva, Polym. Sci., Ser. A. Polym. Phys. 52(6), 671 (2010).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. P. Yevlampieva.

Additional information

Original Russian Text © N.P. Yevlampieva, M.Yu. Antipov, E.I. Ryumtsev, 2014, published in Rossiiskie Nanotekhnologii, 2014, Vol. 9, Nos. 5–6.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Yevlampieva, N.P., Antipov, M.Y. & Ryumtsev, E.I. Analysis of the structure of polymer-inorganic nanoparticles in solutions. Nanotechnol Russia 9, 261–268 (2014). https://doi.org/10.1134/S1995078014030033

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1995078014030033

Keywords

  • PMMA
  • Dynamic Light Scattering
  • Hybrid Particle
  • Translational Diffusion Coefficient
  • Dynamic Light Scattering Data